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《International Journal of Hydrogen Energy》2022,47(18):10137-10155
In this work, hydrate based separation technique was combined with membrane separation and amine-absorption separation technologies to design hybrid processes for separation of CO2/H2 mixture. Hybrid processes are designed in the presence of different types of hydrate promoters. The conceptual processes have been developed using Aspen HYSYS. Proposed processes were simulated at different flow rates for the feed stream. A comprehensive cost model was developed for economic analysis of novel processes proposed in this study. Based on the results from process simulation and equipment sizing, the amount of total energy consumption, fixed cost, variable cost, and total cost were calculated per unit weight of captured CO2 for various flow rates of feed stream and in the presence of different hydrate promoters. Results showed that combination of hydrate formation separation technique with membrane separation technology results in a CO2 capture process with lowest energy consumption and total cost per unit weight of captured CO2. As split fraction and heat of hydrate formation increases, the share of hydrate formation section in total energy consumption increases. When TBAB is applied as hydrate promoter, due to its higher hydrate separation efficiency, more amount of CO2 is captured in hydrate formation section and consequently the total cost for process decreases considerably. Hybrid hydrate-membrane process in the presence of TBAB as hydrate promoter with 29.47 US$/ton CO2 total cost is the best scheme for hybrid hydrate CO2 capture process. Total cost for this process is lower than total cost for single MDEA-based absorption process as the mature technology for CO2 capture. 相似文献
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针对高帧频、全局曝光和光谱平坦等成像应用需求,设计了一款高光谱成像用CMOS图像传感器。其光敏元采用PN型光电二极管,读出电路采用5T像素结构。采用列读出电路以及高速多通道模拟信号并行读出的设计方案来获得低像素固定图像噪声(FPN)和非均匀性抑制。芯片采用ASMC 0.35μm三层金属两层多晶硅标准CMOS工艺流片,为了抑制光电二极管的光谱干涉效应,后续进行了光谱平坦化VAE特殊工艺,并对器件的光电性能进行了测试评估。电路测试结果符合理论设计预期,成像效果良好,像素具备积分可调和全局快门功能,最终实现的像素规模为512×256,像元尺寸为30μm×30μm,最大满阱电子为400 ke^(-),FPN小于0.2%,动态范围为72 dB,帧频为450 f/s,相邻10 nm波段范围内量子效率相差小于10%,可满足高光谱成像系统对CMOS成像器件的要求。 相似文献
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《International Journal of Hydrogen Energy》2022,47(73):31202-31222
Dark fermentation of sugarcane vinasse can be used as a “cleaning” step to remove sulfate prior to methanogenesis because sulfidogenic conditions can be successfully established in parallel with biohydrogen production. Using a 22 central composite rotational design (CCRD) and response surface methodology (RSM), this study assessed the impacts of bicarbonate and sulfate availability on the establishment of sulfidogenesis in the thermophilic (55 °C) fermentation of vinasse in batch reactors, equally assessing the impacts on biohydrogen evolution. CCRD-RSM results indicated the favoring of biohydrogen production at the lowest sulfate and bicarbonate concentrations, whilst the opposite was observed for sulfidogenesis. Glycerol, lactate, and hydrogen were the preferential electron donors utilized by sulfate-reducing bacteria (SRB), whilst ethanol was markedly consumed only at high sulfate concentrations. SRB were inhibited by sodium when dosing excess NaHCO3 and Na2SO4. Complementary tests revealed maximum biohydrogen production (2.40 mmol) out of the CCRD, at pH exceeding 7.5 with no interference of sulfidogenesis. Non-efficient biohydrogen production was observed at low pH (<5.0; ~1.90 mmol) because the uptake of lactate was inhibited. Meanwhile, homoacetogenesis was established under intermediate pH range (5.5–6.5), as revealed by the accumulation of acetate (up to 2.5 g L?1). 16S rRNA gene amplicon sequencing further revealed the genera Thermoanaerobacterium/Pseudoclostridium, Desulfotomaculum/Desulfohalotomaculum and Sporomusaceae/Moorella as the main biohydrogen-producing, sulfate-removing and biohydrogen-consuming (homoacetogens) microbial groups, respectively. Hence, using a single inoculum source, vinasse may provide a butyrate-rich (along with biohydrogen-rich biogas) or a sulfate-free and acetate-rich fermented effluent, depending mainly on proper pH control. 相似文献
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《International Journal of Hydrogen Energy》2022,47(12):8145-8154
High-quality p-type semiconducting Co3O4 with mixed morphology of nanoparticles/nanorods are synthesized using a hydrothermal route for high response and selective hydrogen sulphide (H2S) sensor application. XRD and Raman studies revealed the crystal structure and molecular bonding for obtained Co3O4, respectively. The nanoparticles/nanorods-like structures were confirmed for Co3O4 using FESEM and TEM analysis. The EDS and XPS spectra analysis were carried out for elemental composition and chemical atomic states of Co3O4. The Co3O4 sensor is investigated for gas sensing properties in dynamic conditions. The sensor exhibited the highest selectivity towards H2S among various hydrogen-contained gases at 225 °C. The sensor revealed a high response of 357% and 44% for 100 and 10 ppm H2S gas concentrations, respectively. The Co3O4 sensor exhibited a systematic dynamic resistance response for 100–10 ppm range H2S gas. The excellent dynamic resistance repeatability of the sensor was shown towards 25 ppm H2S gas. The response of Co3O4 sensor was investigated at different operating temperatures and H2S concentrations. The sensor stability and H2S sensing mechanism for the Co3O4 sensor have been reported. Highly uniform and mixed nanostructures of Co3O4 can be the potential sensor material for real-time high-performance H2S sensor application. 相似文献
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《International Journal of Hydrogen Energy》2022,47(81):34504-34532
This paper focuses on thermal destratification and pressurisation inside thermally stratified storage tanks by continuous gas bubbling. The primary purpose of doing these studies is to better understand the effect of bubble dynamics on thermal destratification and quantify the extent of destratification. The volume of fluid and interface compression method of OpenFOAM CFD code is utilised for the present analysis. Different values of inlet gas velocities (Vg), orifice diameters (do), and arrangement of the orifices in triangular and square fashion with different pitches (p/do) are considered. In addition, the effect of gravitational forces (g/ge) on thermal destratification is also reported. For all these cases, the effectiveness of thermal destratification is quantified in terms of a newly defined parameter, the destratification index (Id). For Vg = 1 m/s, the Id value is maximum compared to lower Vg values. It is seen that when the gas velocity increased from 0.3 m/s to 1.0 m/s, the average effectiveness in thermal destratification (Idavg) and pressure at the ullage increased by 44.38% and by 64.81%, respectively. The Idavg and pressure at ullage increased by 96.29% and 14.91%, respectively, when the g/ge ratio changed from 0.3 to 3. Compared to the triangular arrangement with p/do = 10, the calculated Idavg increased by 30.67% when gas inlets were arranged with a square pitch of 10. For p/do = 4, 6 and 8, the increments in Idavg are of the order of 12.86%, 19.43% and 21.92%, respectively, for gas inlets arranged in a square fashion as compared to the triangular arrangement. It is found that continuous bubbling with gas inlets arranged in square pitch p/do = 10 gives higher effectiveness in thermal destratification. Thus, by these studies, one can develop a thermal destratification mechanism with continuous bubbling for optimum performance. Also, these studies give an overall idea of sparger design for getting the correct gas flow rate for thermal destratification within the cryogenic liquid storage tanks. 相似文献
9.
《International Journal of Hydrogen Energy》2022,47(37):16375-16397
Many attempts have been made to improve mass transfer by reducing the size of reactors. However, such reduction will fairly quickly reach practical limitations and numerous difficulties still remain. Catalytic washcoat shape and properties may be critical design factors, but the mechanisms for their effects on mass transfer characteristics are still not fully understood. To effectively eliminate problems associated with mass transport phenomena in microstructured steam-methanol reformers, the effects of washcoat shape and properties were investigated in various situations by performing computational fluid dynamics simulations. The dependence of the solution on mass transfer characteristics was reduced to a small number of dimensionless parameters. A dimensionless mass transfer analysis was carried out in terms of the Sherwood, Schmidt, and pore Reynolds numbers. The results indicated that the rate of mass transfer is predominantly controlled by washcoat properties, and porosity and effective thermal conductivity are fundamentally important. The rate of the reforming reaction is typically controlled by kinetics at a temperature of 480 K and limited by mass transfer at a temperature of 580 K. The shape of washcoats affects the overall mass transfer characteristics, depending on the structural and thermal properties of washcoats. The shape effect is limited by heat transfer. A three-fold increase in effectiveness factor can be achieved by increasing the effective thermal conductivity of the washcoat. Design recommendations were finally made to improve transport characteristics for the systems. 相似文献
10.
通过试验得出了C105混凝土100 mm×100 mm×100 mm立方体非标准试件抗压强度换算系数以及C105混凝土的标准方差和强度变异系数。采用理论计算,得到了棱柱体抗压强度与立方体抗压强度的比值αc1,并与试验实测平均值进行了比较,验证了理论计算方法的可行性。此外,通过对比分析,探讨了直接外延法和引用公式法两种C105混凝土设计参数计算方法的正确性,研究结果可为C105管桩混凝土的设计和应用提供参考。 相似文献