Influence of iron on phase and magnetic property of the LaFe_（11.6）Si_（1.4） compound

The phase relation, microstructure, Curie temperatures, hysteresis, and magnetocaloric effects of LaFex*11.6Si1.4 (x=0.96, 0.98, 1.0, and 1.02) compounds prepared by arc-melting and then annealed at 1423 K (1.5 h)+1523 K (4.5 h) were investigated. The main phase was NaZn13-type phase, the impurity phases included a small amount of α-Fe and LaFeSi phase in four samples. The crystal cell parameters of 1:13 phase increased from 1.1433(5) to 1.1454(4) nm with x increasing from 0.96 to 1.02, respectively. All samples kept the typical first-order magnetic transition. The increase of Fe strengthened IEM behavior, and led to the remarkable enhancement of MCE effect and negative slopes in Arrott plots around TC. The maximum ΔSM (T, H) under a low magnetic field (0-2 T) was 15.3, 16.8, 17.9, and 24.7 J/kg K with increasing of Fe content from x=0.96 to 1.02, respectively.     

Microstructures, mechanical properties and compressive creep behaviors of as-cast Mg-5%Sn-（0-1 .0）%Pb alloys

The microstructures, tensile properties and compressive creep behaviors of Mg-5%Sn-(0–1.0)%Pb (mass fraction) alloys were studied. The microstructures of the Mg-Sn-Pb alloys consist of dendritic α-Mg and Mg₂Sn phase. The addition of Pb can refine the size of Mg₂Sn phase and grain size, reduce the amount of Mg₂Sn phase at grain or inter-dendrite boundaries and change the distribution of Mg₂Sn phase. Pb exists in the Mg₂Sn phase or dissolves in α-Mg matrix. The mechanical properties of the tested alloys at room temperature are improved with the addition of Pb. When the Pb content is over 0.5%, the mechanical properties are decreased gradually. The Mg-5%Sn-0.5%Pb shows the best ultimate tensile strength and elongation, 174 MPa and 14.3%, respectively. However, the compressive creep resistance of the Mg-Sn-Pb alloys is much lower than that of the Mg-Sn binary alloy at 175 °C with applied load of 55 MPa, which means that Pb has negative effects on the compressive creep resistance of the as-cast Mg-Sn alloys.     

高温短时退火LaFe_(13-x)Si_x合金的组织结构

采用XRD、SEM及EDS等手段研究了LaFe13-xSix(x=1.43,1.56,2.4)合金铸态及高温短时退火后的结构与显微组织,并通过振动样品磁强计研究了退火态合金的磁性能.结果表明:铸态LaFe11.57Si1.43和LaFe11.44Si1.56含有大量的α-Fe和LaFeSi相,显微组织呈典型的树枝晶状,LaFe11.44Si1.56还含有较多具有NaZn13型结构的相.铸态LaFe10.6Si2.4可直接得到具有NaZn13型结构的主相,组织呈胞状.在1350 ℃退火0.5 h并随炉冷却后,除含有少量α-Fe及LaFeSi杂相外,LaFe11.57Si1.43和LaFe11.44Si1.56主要以具有NaZn13型结构的相为主,其组织呈等轴晶状.磁性测量结果表明:随Si含量的增加,合金居里温度逐渐升高.     

Compressive creep behavior of Mg-Sn binary alloy

Mg-Sn based alloy is one of the potential alloys for application at elevated temperature.The compressive creep behavior of ageing-treated Mg-xSn(x=3%,5%) alloys was investigated at the temperatures of 423 and 473 K and the stresses from 25 MPa to 35 MPa.When the tin content varies,the ageing-treated Mg-xSn alloys show quite different creep resistance,which are mainly attributed to the size and distribution of Mg_2Sn phases in the ageing-treated Mg-xSn alloys.The calculated value of stress exponent, n=6.3...     

GdsSi1．975Ge1.975T0，05（T=Ni，Fe，Cr，Mn，Co）合金的结构及磁热效应

研究了GdsSi1．975Ge1.975T0，05（为Ni，Fe，Cr，Mn，Co）合金的结构及磁热效应。XRD结果显示：当T元素的原子序数为偶数时，合金形成了单一的Gd5Si2Ge2单斜结构；而当原子序数为奇数时，则为Gd5Si2Ge2单斜结构和正交结构的混合相。在拥有单一相的合金中均发现了巨磁热效应，然而在具有混合相的合金中由于未能发生一级结构相变而导致了低的磁熵变。此外，GdsSi1.975Ge1．975Cr0.05合金的磁制冷量达到了112J／kg，相对于Gd5Si2Ge2合金提高了50％。     

铸态Mg—xSn-2La合金的组织与性能

采用光学金相显微镜、SEM、EDS、XRD分析以及拉伸试验等试验手段,研究了Mg-xSn-2La(x=2.34、4.68、7.02、9.36)合金铸态下的组织和性能.结果表明,当Sn含量为2.34%时,合金主要由α-Mg和Mg-La-Sn稀土相组成;随着Sn含量增加,Mg2Sn数量增多,Mg-La-Sn稀土相逐渐粗化,细小的颗粒状稀土相减少,棒状稀土相增加,并且逐渐由晶界向枝晶间界分布,合金的抗拉强度与伸长率明显提高.Mg-7.02Sn-2La合金具有最高的抗拉强度(151 MPa),而Mg-4.68Sn2La具有最高的伸长率(12.7%),但是过多的Sn反而会导致合金力学性能下降.     

Gd5Si1.975Ge1.975T0.05(T=Ni,Fe,Cr,Mn,Co)合金的结构及磁热效应

研究了Gd5Si1.975Ge1.975T0.05(T为Ni、Mn、Cr、Co、Fe)合金的结构及磁热效应.XRD结果显示:当T元素的原子序数为偶数时,合金形成了单一的Gd5Si2Ge2单斜结构;而当原子序数为奇数时,则为Gd5Si2Ge2单斜结构和正交结构的混合相.在拥有单一相的合金中均发现了巨磁热效应,然而在具有混合相的合金中由于未能发生一级结构相变而导致了低的磁熵变.此外,Gd5Si1.975Ge1.975Cr0.05合金的磁制冷量达到了112 J/kg,相对于Gd5Si2Ge2合金提高了50%.     

Sn合金化对Gd5Si2Ge2磁致冷材料结构和性能的影响

以商业纯Gd为原料,采用非自耗电弧炉氩气保护下熔炼了Gd5Si2Ge2-xSnx(x=0.2,0.5,1)和Gd5Si2-yGe2Sny(y=0.1,0.2,0.5)系列合金,研究Sn合金化对Gd5Si2Ge2晶体结构和磁热性能的影响.粉末XRD结果表明Sn代Ge样品具有正交Gd5Si4型结构;Sn少量代Si(y=0.1,0.2)的样品具有单斜Gd5Si2Ge2型结构;Gd5Si1.5Ge2Sn0.5则为单斜和正交的混合结构.用超导量子磁强计(SQUID)测定了样品的M-T和不同温度的M-H曲线,结果表明Gd5Si2Ge2-xSnx(x=0.2,0.5,1)不具有巨磁热效应;Gd5Si1 9Ge2Sn01合金的最大磁熵变达15.3 J/kg·K(0 T～5 T),具有巨磁热效应.     

Effect of Aluminum Coating on Corrosion and Heat Transfer Performance of Magnetic Refrigerant Gadolinium

The surface of gadolinium was covered with a layer of Al film(10-15 μm) by hot-press.Corrosion resistance, thermal conductivity and diffusivity of the composites were studied. As a result,temperature and pressure are the main factors that influence the combination of Gd and Al, and the effect of pressure is especially obvious. When the pressure exceeds 700 MPa, the binding force reaches 9 MPa. After coating, corrosion resistance of the composites is significantly improved, Corrosion rate is significantly reduced and mass loss reduced to one-tenth of pure Gd after 15 days. The current density decreases by an order of magnitude and corrosion potential increases by 0.3 V. The thermal conductivity of the composites is 11.12 W·m~(-1)·K~(-1). Due to good thermal diffusion coefficient of aluminum, the magnetic work piece coated with Al film might show better heat transfer performance.     

Di对Mg-10Al合金显微组织与力学性能的影响

研究了Di加入量为1％～3％（质量分数，下同）[Nd—Pr混合稀土金属，w（Nd）：w（Pr）=3：1]的Mg-10Al合金的显微组织和力学性能。通过显微组织分析发现Di加入Mg-10Al合金后，析出了块状的Al2（Nd，Pr）相及杆状的Al11（Nd，Pr）3相，合金组织得到细化。Di的加入使铸态的Mg-10Al合金的力学性能提高，在Di的加入量为2％时，块状的Al2（Nd，Pr）相占主导地位，合金的抗拉强度和伸长率都达到峰值。在Di的加入量达到3％时，杆状的Al11（Nd，Pr），相增加，抗拉强度、尤其是伸长率有所降低。