火麻仁油微乳凝胶面膜的制备及初步评价

目的:制备火麻仁油微乳凝胶补水面膜并对其理化性质、保湿性和抗氧化活性进行评价.方法:通过伪三元相图确定火麻仁油微乳最佳处方,采用单因素及正交试验优化火麻仁油微乳凝胶处方,载入保湿活性物质制得火麻仁油微乳凝胶面膜并对其质量、稳定性、保湿性和抗氧化活性进行评价.结果:火麻仁油微乳最佳处方:火麻仁油0.2％、PEG-20氢化蓖麻油0.53％、1,3丙二醇0.27％.火麻仁油微乳凝胶最佳处方为卡波姆-940含量1％,丙三醇含量5％,稀释倍数30倍.制得的微乳凝胶澄清透明、涂展性较好、易清洗、不油腻;平均粒径为(30.91±0.31)nm,PDI为0.299±0.017,电位为(-3.54±0.43)mV;黏度为494725.15 mPa·s;pH值为5.50±0.01;保湿效果优于市售某凝胶面膜;火麻仁油微乳凝胶面膜对DPPH自由基清除率高于火麻仁油毛油,质量浓度为6 mg·mL-1时可达62.39％,IC50为3.71 mg·mL-1.结论:火麻仁油微乳凝胶面膜安全、稳定,制备工艺简单,对皮肤具有良好的补水和抗氧化效果,具备开发和推广的价值.     

Surface Modification of Co3O4 Nanosheets to Promote Peroxymonosulfate Activation for Degradation of Atrazine

Catalysis Letters - This study proposed a new facile route to rational creating oxygen-vacancy (Vo)-rich surface of Co3O4 nanosheets by acetic acid leaching. The acid leached Co3O4 nanosheets was...     

GC-MS法测定缬草残渣中的化学组分

分别使用95％乙醇和四氯化碳作为提取溶剂,在78℃左右,对已提取过挥发油的缬草残渣中化学成分进行提取,借用气相色谱-质谱联用方法(GC-MS)对提取浸膏中化学组分进行分析.结果显示:以乙醇作为提取溶剂条件下,共鉴定出38中化学组分,数据出峰相对总质量分数为81.7％;以四氯化碳为提取溶剂条件下,共鉴定出44种化学组分,数据出峰相对总质量分数为84.4％.     

Mechanical properties of biomimetic ceramic with Bouligand architecture

Biomimetic Bouligand architecture is constructed in the ceramic to improve its toughness. Firstly, unidirectional carbon fiber-reinforced ZrB₂-SiC ceramic films are achieved through a vacuum-assisted filtration method using graphene oxide. Then, ceramic films are helically assembled at a fixed angle of 30° in the graphite die based on the fiber orientation. Finally, the spark plasma sintering method was utilized to densify helical assembly carbon fiber/ceramic films. By constructing Bouligand structure, high fracture toughness (7.4 MPa·m^0.5) and work of fracture (∼1055 J/m²) are achieved in ZrB₂-based ceramic. The toughening mechanisms mainly are crack deflection, twisting and branching, carbon fiber pulling out, and bridging.     

Bio-Based,Self-Crosslinkable Eucommia ulmoides Gum/Silica Hybrids with Body Temperature Triggering Shape Memory Capability

At present, the synthesis of body temperature triggering shape memory polymers usually requires elaborate structural design, which limits their wide application. Herein, starting from bio-based Eucommia ulmoides gum (EUG), a series of EUG/silica hybrids (ESHs) are prepared through a facile one-pot process, in which EUG is epoxied and then self-crosslinked with SiO₂ by epoxy ring-open reaction. Varying the amount of H₂O₂, the shape memory transition temperature (T_trans) of ESHs is adjusted to 47.4–36.6 ℃, which is close to human body temperature (37 ℃). Among them, ESH-17 exhibited the best body temperature triggering shape memory ability (T_trans = 36.6 ℃), which can restore the permanent shape within 60 s at 37 ℃ with a shape fixity ratio of 99% and shape recovery ratio near 100%. In addition, the shape memory mechanism is discussed and shows some application scenarios of ESHs. The as-produced materials can be used as smart biomaterials such as self-tightening sutures, self-sealing root canal filling materials, and so on.     

Fine-diameter Si–B–C–N ceramic fibers enabled by polyborosilazanes with N–methyl pendant group

Given the superior thermal stability and electromagnetic features, continuous Si–B–(C)–N ceramic fibers have displayed great potential to fulfill the increasing demand for the high-temperature structural and functional materials. Manufacture of such ceramic fibers depends heavily upon the design of processable polymer precursors. Herein, a class of polyborosilazanes (PBSZs) with high spinnability were created through a facile one-pot synthesis. The trade-off between spinnability and ceramic yield of PBSZs was overcome by using heptamethyldisilazane and hexamethyldisilazane as the co-condensing agents to polymerize silicon and boron chloride monomers. The optimal PBSZs can fabricate continuous Si–B–C–N fibers with homogeneous diameter of 7.9 ± 0.5 μm and high ceramic yield of 80 wt%. Experimental characterization and quantum chemical computation revealed the mechanistic pictures of the impact of pendant groups on the polycondensation, melt spinning, and pyrolyzing process. These insights improve our understanding of spinnable pre-ceramic polymers for exploiting high-performance nitride ceramic fibers.     

软化+微滤膜工艺处理填埋场渗滤液的中试研究

以阜阳市某生活垃圾填埋场渗滤液为研究对象,针对渗滤液高硬度、低碱度的特点,考查软化+微滤膜中试工艺对填埋场总硬度的处理效能,分析微滤膜运行参数对膜通量和产水流量的影响.中试结果表明:软化+微滤膜工艺可有效去除水源中钙镁离子污染问题,控制软化装置的反应池pH在11.5,总硬度(以CaCO3计)的去除率在94％以上,出水总硬度(以CaCO3计)稳定<100 mg/L.软化微滤工艺对渗滤液中COD的平均去除率为16.2％.单支微滤膜正常运行,反洗频率30 min时,可将膜通量恢复至初始通量的90％以上.由中试可知,微滤膜具有良好的抗污染性能,在进膜污泥浓度为4.97 g/L及以上时,初始膜通量仍能保持较高值.