全文获取类型
收费全文 | 51634篇 |
免费 | 5024篇 |
国内免费 | 2891篇 |
专业分类
电工技术 | 3376篇 |
技术理论 | 3篇 |
综合类 | 3681篇 |
化学工业 | 7971篇 |
金属工艺 | 3430篇 |
机械仪表 | 3396篇 |
建筑科学 | 4379篇 |
矿业工程 | 1491篇 |
能源动力 | 1388篇 |
轻工业 | 3979篇 |
水利工程 | 1002篇 |
石油天然气 | 2670篇 |
武器工业 | 543篇 |
无线电 | 6268篇 |
一般工业技术 | 5938篇 |
冶金工业 | 2001篇 |
原子能技术 | 606篇 |
自动化技术 | 7427篇 |
出版年
2024年 | 97篇 |
2023年 | 861篇 |
2022年 | 1525篇 |
2021年 | 2322篇 |
2020年 | 1783篇 |
2019年 | 1378篇 |
2018年 | 1564篇 |
2017年 | 1666篇 |
2016年 | 1515篇 |
2015年 | 2151篇 |
2014年 | 2631篇 |
2013年 | 3089篇 |
2012年 | 3705篇 |
2011年 | 3839篇 |
2010年 | 3569篇 |
2009年 | 3338篇 |
2008年 | 3150篇 |
2007年 | 3168篇 |
2006年 | 2937篇 |
2005年 | 2561篇 |
2004年 | 1771篇 |
2003年 | 1442篇 |
2002年 | 1433篇 |
2001年 | 1162篇 |
2000年 | 1220篇 |
1999年 | 1146篇 |
1998年 | 842篇 |
1997年 | 737篇 |
1996年 | 666篇 |
1995年 | 530篇 |
1994年 | 435篇 |
1993年 | 323篇 |
1992年 | 270篇 |
1991年 | 170篇 |
1990年 | 129篇 |
1989年 | 126篇 |
1988年 | 91篇 |
1987年 | 52篇 |
1986年 | 43篇 |
1985年 | 22篇 |
1984年 | 23篇 |
1983年 | 12篇 |
1982年 | 14篇 |
1981年 | 11篇 |
1980年 | 10篇 |
1979年 | 5篇 |
1978年 | 3篇 |
1969年 | 1篇 |
1959年 | 8篇 |
1951年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Yunyan Liu Ning Jiang Yao Liu Dawei Cui Chang-Feng Yu Huiqiang Liu Zhao Li 《Ceramics International》2021,47(16):22416-22423
Pulsed laser deposition (PLD) was used to prepare tungsten trioxide (WO3) films on ITO substrates with a varying laser power density of 4.0–5.5 W/cm2. XPS indicated that when the laser power density decreased, the peak positions of the W 4f and O 1s orbits shifted slightly to low energy due to the difference in oxygen vacancies. As the laser power density decreased, W6+ gradually replaced the lattice position of O2?, increasing oxygen vacancies in the lattice. The transmittance modulated values (ΔT) were over 44% at 830 nm, indicating strong absorption by the WO3 thin films in the near-infrared ray. The switching time of the WO3 thin films between bleached states and coloured states decreased as the laser power density increased due to the amorphous structure, morphology, and lower oxygen deficiency at a high power density. The high ΔT and very fast switching time of tb (1.09 s) and tc (6.01 s) demonstrated the excellent electrochromic (EC) properties of the WO3 films prepared by PLD. 相似文献
2.
Chenhui Ding Marion Breunig Jana Timm Roland Marschall Jürgen Senker Seema Agarwal 《Advanced functional materials》2021,31(49):2106507
Covalent organic frameworks (COFs) show advantageous characteristics, such as an ordered pore structure and a large surface area for gas storage and separation, energy storage, catalysis, and molecular separation. However, COFs usually exist as difficult-to-process powders, and preparing continuous, robust, flexible, foldable, and rollable COF membranes is still a challenge. Herein, such COF membranes with fiber morphology for the first time prepared via a newly introduced template-assisted framework process are reported. This method uses electrospun porous polymer membranes as a sacrificial large dimension template for making self-standing COF membranes. The porous COF fiber membranes, besides having high crystallinity, also show a large surface area (1153 m2 g−1), good mechanical stability, excellent thermal stability, and flexibility. This study opens up the possibility of preparation of large dimension COF membranes and their derivatives in a simple way and hence shows promise in technical applications in separation, catalysis, and energy in the future. 相似文献
3.
Xueru Chen Yin Zhang Dashui Yuan Wu Huang Jing Ding Hui Wan Wei-Lin Dai Guofeng Guan 《材料科学技术学报》2021,71(12):211-220
Porous g-C3N4 nanosheets (PCN) were prepared by the nickel-assisted one-step thermal polymerization method.Hydrogen (H2) which was produced by the reaction between nickel (Ni) foam and ammonia (NH3) defined the structure and properties of PCN.During the formation of PCN,the participation of H2 not only enhanced the spacing between layers but also boosted the specific surface area that more active sites were exposed.Additionally,H2 promoted pores formation in the nanosheets,which was beneficial to the transfer of photons through lamellar structure and improved the absorption efficiency of visible light.Remarkably,the obtained PCN possessed better Cr(Ⅵ) photocatalytic reduction efficiency than pure g-C3N4.The reaction rate constant (k) of PCN (0.013 min-1) was approximately twice that of bare g-C3N4 (0.007 min-1).Furthermore,the effects of original pH and concentration of Cr(Ⅵ)-containing solution on removal efficiency of Cr(Ⅵ) were explored.A possible photocatalytic mechanism was proposed based on the experiments of radical scavengers and photoelectrochemical characterizations. 相似文献
4.
Recently, the successful synthesis of wafer-scale single-crystal graphene, hexagonal boron nitride (hBN), and MoS2 on transition metal surfaces with step edges boosted the research interests in synthesizing wafer-scale 2D single crystals on high-index substrate surfaces. Here, using hBN growth on high-index Cu surfaces as an example, a systematic theoretical study to understand the epitaxial growth of 2D materials on various high-index surfaces is performed. It is revealed that hBN orientation on a high-index surface is highly dependent on the alignment of the step edges of the surface as well as the surface roughness. On an ideal high-index surface, well-aligned hBN islands can be easily achieved, whereas curved step edges on a rough surface can lead to the alignment of hBN along with different directions. This study shows that high-index surfaces with a large step density are robust for templating the epitaxial growth of 2D single crystals due to their large tolerance for surface roughness and provides a general guideline for the epitaxial growth of various 2D single crystals. 相似文献
5.
Wire arc additive manufacturing(WAAM)has been investigated to deposit large-scale metal parts due to its high deposition efficiency and low material cost.However,in the process of automatically manufacturing the high-quality metal parts by WAAM,several problems about the heat build-up,the deposit-path optimization,and the stability of the process parameters need to be well addressed.To overcome these issues,a new WAAM method based on the double electrode micro plasma arc welding(DE-MPAW)was designed.The circuit principles of different metal-transfer models in the DE-MPAW deposition process were analyzed theoretically.The effects between the parameters,wire feed rate and torch stand-off distance,in the process of WAAM were investigated experimentally.In addition,a real-time DE-MPAW control system was developed to optimize and stabilize the deposition process by self-adaptively changing the wire feed rate and torch stand-off distance.Finally,a series of tests were performed to evaluate the con-trol system's performance.The results show that the capability against interferences in the process of WAAM has been enhanced by this self-adaptive adjustment system.Further,the deposition paths about the metal part's layer heights in WAAM are simplified.Finally,the appearance of the WAAM-deposited metal layers is also improved with the use of the control system. 相似文献
6.
柔性夹钳因具有微/纳精密操作能力, 常应用于微操作系统中, 但因抓爪无法提供恒定输出力或恒力范围小, 容易造成操作对象的损伤或脱落。根据放大模块与常力模块串联的结构形式, 设计了一种具有常力特性的柔性夹钳。基于伪刚体法, 建立放大模块中桥式机构与杠杆机构的刚度和放大率数学模型, 通过对倾斜导向梁进行分析, 得到常力模块的力-位移关系式, 计算出恒定输出力为42.5 N, 输出范围为370 μm。最后, 结合不同柔顺梁的结构参数, 运用MATLAB仿真探究了各关键参数对常力特性的影响。研究结果可为常力柔性夹钳的构型设计和分析提供一定的理论支撑。 相似文献
7.
为了解决机器人辅助在线检测系统示教过程中效率低、人为干预多的问题,针对孔类特征,提出一种通过处理光刀图像获取机器人位姿纠正参数的方法。在该方法中,纠偏过程按照将图像光刀线调整为水平方向、将被测特征调整至图像中央、根据不同特征调整最优扫描方向3个步骤进行。根据光刀图像可以求出测量坐标系与被测特征的位姿关系,并得到该位姿与理想测量位姿的偏差。经过坐标变换即可得到在机器人基坐标系下的调整参数。另外,可利用电脑控制机器人运动,从而实现了纠偏过程的自动化。实验结果表明,该方法可将初始的示教位姿修正为理想位姿,且比传统方式效率更高。 相似文献
8.
Nengbing Long Yanqing Fu Tianxiang Xu Dashuang Ding Shaoqian Zhang Shengzhi Sun Shiliang Kang Tiefeng Xu Shixun Dai Qiuhua Nie Changgui Lin 《Journal of the European Ceramic Society》2021,41(8):4584-4589
The confinement of CsPbX3 (X = Cl, Br, and I) perovskite nanocrystals (NCs) in a stabilized inorganic glass matrix is a new strategy for improving their long-term stability and promoting their applications in the optoelectronic field. Here, in situ nanocrystallization strategy is developed to precipitate CsPbBr3?xIx NCs with arbitrary I/Br ratio among an elaborately designed GeS2–Sb2S3-based chalcogenide glass matrix. Spherical CsPbBr3?xIx NCs are homogeneously distributed in the glass matrix after thermal treatment. The photoluminescence (PL) spectra show that the emission peaks of CsPbBr3?xIx NCs can be tuned from 570 nm to 722 nm with the replacement of Br by I. The fs transient absorption (TA) spectra reveal that there exists some structural defects in the NCs, leading to short PL decay life. This work would shed light on confining CsPbX3 NCs into glassy matrices, facilitating their future applications in photoelectronic fields. 相似文献
9.
Ruizhi Hu Chen Dai Chunmei Wang Jie Lin Hui Hu Zhifang Li Han Lin Li Ding Yu Chen Bo Zhang 《Advanced functional materials》2021,31(25):2101660
As an anticancer drugs, arsenic trioxide (ATO) has been certified to efficiently treat refractory acute promyelocytic leukemia (APL). Unfortunately it suffers from limited therapeutic potency for solid tumors due to its in vivo restricted administration dose and rapid renal clearance. Herein, distinct 2D arsenic-phosphorus (AsP) nanosheets are engineered by adopting an alloy strategy followed by exfoliation, which can confine toxic arsenic into AsP crystals, thus significantly improving the biosafety and biocompatibility of arsenic-based chemotherapeutic drugs. Of particular note, the high light absorption and strong photothermal-conversion efficiency (37.6%) in the second near infrared biowindow (NIR-II) of AsP nanosheets not only endow them with desirable contrast-enhanced photoacoustic imaging properties, but also achieve efficient local tumor hyperthermia, which further synergistically triggers the in-situ transformation from low toxic/nontoxic AsP crystals into highly toxic arsenic species, exerting a strong arsenic-mediated antineoplastic effect. Both in vitro and in vivo data verify the synergy between photonic therapy in NIR-II and enhanced chemotherapy as enabled by AsP nanosheets, paving the way for efficient nanomedicine-enabled arsenic-based chemotherapeutic tumor treatment. 相似文献
10.
A novel CdS/CaFe2O4 (CS/CFO) heterogeneous p-n junction was created by thermal deposition of CaFe2O4 nanoparticles on CdS rods. The CS/CFO hetero-structured photocatalysts exhibited increasingly efficient visible light harvesting compared to the bare CdS. The CS/CFO composites also presented higher photocurrent and slower decay of photoluminescence, suggesting a better separation of the photo-generated electrons and holes. The photocatalytic H2 evolution quantity on the optimized CS/CFO composite from water in the presence of ethanol was up to 2200 μmol after 3-h visible light illumination, which is more than twice that of the pristine CdS. The chemical interaction between CdS and CaFe2O4 was confirmed by the shifts in the XPS peaks, which made it possible for the charge carriers to transfer across the p-n junction interface. This research highlights the importance of forming an interfacial p-n heterojunction between two semiconductors for efficient charge separation and improved photocatalytic performance. 相似文献