全文获取类型
收费全文 | 24167篇 |
免费 | 1915篇 |
国内免费 | 862篇 |
专业分类
电工技术 | 1184篇 |
技术理论 | 5篇 |
综合类 | 1398篇 |
化学工业 | 4095篇 |
金属工艺 | 1606篇 |
机械仪表 | 1479篇 |
建筑科学 | 1823篇 |
矿业工程 | 694篇 |
能源动力 | 787篇 |
轻工业 | 1662篇 |
水利工程 | 399篇 |
石油天然气 | 1596篇 |
武器工业 | 193篇 |
无线电 | 2478篇 |
一般工业技术 | 3025篇 |
冶金工业 | 1342篇 |
原子能技术 | 272篇 |
自动化技术 | 2906篇 |
出版年
2024年 | 13篇 |
2023年 | 451篇 |
2022年 | 568篇 |
2021年 | 955篇 |
2020年 | 818篇 |
2019年 | 661篇 |
2018年 | 774篇 |
2017年 | 782篇 |
2016年 | 604篇 |
2015年 | 899篇 |
2014年 | 1135篇 |
2013年 | 1591篇 |
2012年 | 1571篇 |
2011年 | 1685篇 |
2010年 | 1458篇 |
2009年 | 1400篇 |
2008年 | 1364篇 |
2007年 | 1294篇 |
2006年 | 1359篇 |
2005年 | 1188篇 |
2004年 | 732篇 |
2003年 | 656篇 |
2002年 | 588篇 |
2001年 | 477篇 |
2000年 | 539篇 |
1999年 | 634篇 |
1998年 | 535篇 |
1997年 | 400篇 |
1996年 | 393篇 |
1995年 | 329篇 |
1994年 | 270篇 |
1993年 | 185篇 |
1992年 | 142篇 |
1991年 | 105篇 |
1990年 | 85篇 |
1989年 | 45篇 |
1988年 | 62篇 |
1987年 | 38篇 |
1986年 | 23篇 |
1985年 | 28篇 |
1984年 | 22篇 |
1983年 | 15篇 |
1982年 | 11篇 |
1981年 | 7篇 |
1980年 | 11篇 |
1979年 | 9篇 |
1978年 | 4篇 |
1974年 | 3篇 |
1959年 | 2篇 |
1958年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 16 毫秒
1.
为改善攀钢含钛高炉渣大量堆放造成的环境问题以及减少有价资源浪费,通过研究水淬含钛高炉渣的化学成分、矿物物相组成、热重等特性,以-140目水淬含钛高炉渣为原料,采用加热方式研究其矿物物相的结晶行为,结果表明:水淬渣与空冷渣的化学成分基本相同,但矿物物相组成随颗粒粒径变化有较大的差异;矿物物相的结晶主要发生在680℃以上,随着温度的升高结晶顺序为尖晶石、钙钛矿、透辉石;水淬渣的微观形貌也随着加热温度的升高由具有尖锐棱角的碎屑颗粒逐渐变得圆润,颗粒表面覆盖有粒径为0.5~2.0μm的片状晶体。 相似文献
2.
运用天然气水合物含油气系统理论,对天然气形成、分解这一复杂动态物理化学过程的研究进展进行了论述,分析了天然气水合物含油气系统的研究进展、存在问题和发展趋势,得到以下结论:大多数天然气水合物气源与生物降解密切相关;影响天然气水合物温度-压力临界曲线的主要因素为天然气、孔隙水的组分,地温梯度和冻土厚度不改变天然气水合物温度-压力临界曲线;天然气水合物含油气系统关键时刻的静态要素和动态过程以及两者之间的耦合关系在天然气水合物含油气系统中起重要作用。天然气水合物含油气系统研究不仅为天然气水合物成藏过程提供了理论依据,也为天然气水合物的勘探开发提供技术支持。 相似文献
3.
Polyhedral oligomeric silsesquioxane (POSS) as an organic–inorganic hybrid at a molecular level, has excellent mechanical properties, thermodynamic properties, dielectric properties and so on. In recent decades, POSS has been extensively used in modification of various polymers to prepare nanocomposites with enhanced comprehensive performances. Biomass materials such as chitosan, cellulose, silk protein, collagen fibers and gelatin have excellent biocompatibility and biodegradability, which have been widely used in the fields such as biomedical, innovative environmental protection and so on. However, deficiencies including insufficient mechanical properties and rapid rate of biodegradation hampered their application. This paper briefly introduced the principal methods to synthesize POSS nanoparticles, and then focused on technologies for preparing biomass-based composites utilizing diverse functional POSSs. Finally, put forward the prospects of POSS modification technology and its future application direction. This article will have a positive guiding role for the further research and development of biomass/POSS nanocomposites. 相似文献
4.
以银耳为原料, 采用超声波辅助热水浸提法提取银耳多糖, 以多糖提取率为指标, 以超声波功率、提取料液比、提取温度和提取时间为影响因素, 设计单因素试验, 并通过正交试验得到较佳提取工艺。通过用TRPV1(Transient Receptor Potential Vanilloid1)试剂盒检测了小胶质细胞TRPV1的释放水平, 与脂多糖(Lipopolysaccharide, LPS)对照组相比, 不同质量浓度的银耳多糖组(62.5, 250, 1000 μg/mL)均能不同程度地抑制TRPV1的释放量。说明了银耳多糖对于BV2小胶质细胞炎症具有良好的抑制作用。 相似文献
5.
Zhipei Gao Yongli Du Xiehuang Sheng Jingkang Shen 《International journal of molecular sciences》2021,22(7)
Estrogen-related receptor α (ERRα), which is overexpressed in a variety of cancers has been considered as an effective target for anticancer therapy. ERRα inverse agonists have been proven to effectively inhibit the migration and invasion of cancer cells. As few crystalline complexes have been reported, molecular dynamics (MD) simulations were carried out in this study to deepen the understanding of the interaction mechanism between inverse agonists and ERRα. The binding free energy was analyzed by the MM-GBSA method. The results show that the total binding free energy was positively correlated with the biological activity of an inverse agonist. The interaction of the inverse agonist with the hydrophobic interlayer composed of Phe328 and Phe495 had an important impact on the biological activity of inverse agonists, which was confirmed by the decomposition of energy on residues. As Glu331 flipped and formed a hydrogen bond with Arg372 in the MD simulation process, the formation of hydrogen bond interaction with Glu331 was not a necessary condition for the compound to act as an inverse agonist. These rules provide guidance for the design of new inverse agonists. 相似文献
6.
Xihan Fu Shuang Wang Zheng Liu Yaofa Luo Xiaosheng Du Haibo Wang Mi Zhou Xu Cheng Zongliang Du 《大分子材料与工程》2021,306(1):2000504
In recent years, highly efficient oil/water separation materials have brought much attention. It requests superhydrophobic surfaces with a rapid and facile separation process, excellent durability, and large-scale fabrication. Herein, a facile vapor-liquid sol-gel, and free radical polymerization reaction method to prepare the durable and robust superhydrophobic cotton fabric is proposed. Moreover, the fabric can be used for highly efficient and various oil/water separation. It is prepared via a simple two-step process, including a vapor-liquid sol-gel process to deposit with thiols particles, and then followed a free radical polymerization reaction to graft 2,2,3,4,4,4-hexafluorobutyl methacrylate. Scanning electron microscopy and Fourier transform infrared spectrometry prove that the rough structures are generated from the hydrolysis condensation reaction between tetraethyl orthosilicate and 3-mercaptopropyltriethoxysilane. As a result, the synthetic chemical composition provided by the natural fabric and silica nanoparticles synergistically construct a superhydrophobic surface with water contact angles and shedding angle of 158° and 9°, respectively. Additionally, the treated fabric exhibits excellent chemical resistance and self-cleaning ability. Remarkably, the fabric still retains superhydrophobic and excellent mechanical robustness after 30 cycles of various oil/water separation. In summary, the resultant fabrics with excellent chemical resistance, remarkable mechanical robustness, and versatile separation abilities have potential applications in various oil/water separations. 相似文献
7.
8.
9.
采用第一性原理计算方法研究了H原子在立方TiC 晶格中的结构稳定性及扩散行为。结果表明:H原子在TiC晶格中的最稳定位点位于Ti/C六面体中靠近C原子的C-H(C-HS)位置,H被C原子捕获而形成C—H键,键长1.15 Å(1 Å=0.1 nm),零点修正(ZPE)后形成能为1.58 eV;其次是Ti/C六面体中心位置(CS),H 原子主要与Ti原子成键,ZPE修正后的形成能为1.75 eV。采用CI-NEB方法计算预测了TiC晶格中H间隙原子的最优扩散路径,即先在Ti/C六面体内沿(110)晶面进行“跳跃”扩散,扩散势垒为0.47 eV;然后以C原子为中心,沿(100)晶面进行两次“旋转”扩散穿越Ti/C原子面,扩散势垒为0.28 eV。 相似文献
10.