Silver nanocluster formation in silicate glass by single step ion-exchange

We report the formation of silver nanoclusters of average size ∼ 1.1 nm in a single step ion-exchanged silica glass. Silver clusters are formed in a glass during ion-exchange by fine-tuning the ion-exchange parameters such as salt composition, temperature and time. Such nanocluster formation during ion-exchange preserves the waveguiding properties of the ion-exchanged surface of the glass making them suitable for nonlinear waveguide device fabrication.     

Alekseevskii-Tate revisited:An extension to the modified hydrodynamic theory of long rod penetration

The modified hydrodynamic theory of long rod penetration into semi-infinite targets was established independently by Alek-seevskii and Tate over forty years ago and since then many investigators contributed much to the development of the high speed penetration mechanics.However,in all the models proposed so far,the target resistance Rt is not well defined and usually determined by adjusting it until the predicted depth of penetration comes to an agreement with experimental data.In this paper,assumptions are...     

Evolutionary circuit design for fast FPGA-based classification of network application protocols

The evolutionary design can produce fast and efficient implementations of digital circuits. It is shown in this paper how evolved circuits, optimized for the latency and area, can increase the throughput of a manually designed classifier of application protocols. The classifier is intended for high speed networks operating at 100 Gbps. Because a very low latency is the main design constraint, the classifier is constructed as a combinational circuit in a field programmable gate array (FPGA). The classification is performed using the first packet carrying the application payload. The improvements in latency (and area) obtained by Cartesian genetic programming are validated using a professional FPGA design tool. The quality of classification is evaluated by means of real network data. All results are compared with commonly used classifiers based on regular expressions describing application protocols.     

In-situ synthesis of TiO2 nanostructures on Ti foil for enhanced and stable photocatalytic performance

TiO_2 nanostructures with strong interfacial adhesion and diverse morphologies have been in-situ grown on Ti foil substrate through a multiple-step method based on conventional plasma electrolytic oxidation(PEO) technology, hydrothermal reaction and ion exchange process. The PEO process is critical to the formation of TiO_2 seeding layer for the nucleation of Na_2Ti_3O_7 and H_2Ti_3O_7 mediates that are strongly attached to the Ti foil. An ion exchange reaction can finally lead to the formation of H_2Ti_3O_7 nanostructures with diverse morphologies and the calcination process can turn the H_2Ti_3O_7 nanostructures into TiO_2 nanostructures with enhanced crystallinity. The morphology of the TiO_2 nanostructures including nanoparticles(NP), nanowhiskers(NWK), nanowires(NW) and nanosheets(NS) can be easily tailored by controlling the NaOH concentration and reaction time during hydrothermal process. The morphology, composition and optical properties of TiO_2 photocatalysts were analyzed using scanning electron microscope(SEM), X-ray diffraction(XRD), photoluminescence(PL) spectroscopy and UV–vis absorption spectrum. Photocatalytic tests indicate that the TiO_2 nanosheets calcined at 500?C show good crystallization and the best capability of decomposing organic pollutants. The decoration of Ag cocatalyst can further improve the photocatalytic performance of the TiO_2 nanosheets as a result of the enhanced charger separation efficiency. Cyclic photocatalytic test using TiO_2 nanostructures grown on Ti foil substrate demonstrates the superior stability in the photodegradation of organic pollutant, suggesting the promising potential of in-situ growth technology for industrial application.     

Unique role of non-mercapto groups in thiol-pinning-mediated Ag growth on Au nanoparticles

Owing to the strong affinity of thiols to Au and Ag, they are often employed to modify the surfaces of nanoparticles (NPs). Recently, these strong ligand-interface interactions have been employed to control NP growth, and this technique has emerged as a unique modulation strategy for creating unconventional plasmonic hybrid nanostructures. In these systems, the roles of the non-mercapto components of the thiol molecules and their structures are still unknown. Therefore, we herein present our investigation into this phenomenon. Primary amino (–NH₂) groups in thiols are found to play a key role in regulating growth kinetics, i.e., in accelerating Ag deposition on Au NPs. The–NH₂ groups are thought to bring Ag ions to the particle surface by coordinating to them, and thereby assist their reduction. The effect of molecular structure is non-trivial and thus provides the possibility of selective thiol detection. Based on the dependence of kinetic modulation on the non-mercapto components and molecular structures of molecules, we demonstrate the highly sensitive and specific detection of cysteine (limit of detection: 6 nM) in a mixture of 19 natural amino acids based on Ag growth on Au nanospheres. In addition, based on this modulation effect, we reveal the entrapping of chiral thiols within the growth layer through their plasmonic circular dichroism (PCD) responses. We believe that thiol-based growth regulation has great potential for creating plasmonic nanostructures with novel functionalities.

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Several multi-criteria programming methods for classification

In this paper, we propose a general optimization-based model for classification. Then we show that some well-known optimization-based methods for classification, which were developed by Shi et al. [Data mining in credit card portfolio management: a multiple criteria decision making approac. In: Koksalan M, Zionts S, editors. Multiple criteria decision making in the new millennium. Berlin: Springer; 2001. p. 427–36] and Freed and Glover [A linear programming approach to the discriminant problem. Decision Sciences 1981; 12: 68–79; Simple but powerful goal programming models for discriminant problems. European Journal of Operational Research 1981; 7: 44–60], are special cases of our model. Moreover, three new models, MCQP (multi-criteria indefinite quadratic programming), MCCQP (multi-criteria concave quadratic programming) and MCVQP (multi-criteria convex programming), are developed based on the general model. We also propose algorithms for MCQP and MCCQP, respectively. Then we apply these models to three real-life problems: credit card accounts, VIP mail-box and social endowment insurance classification. Extensive experiments are done to compare the efficiency of these methods.     

Collision and intersection detection of two ruled surfaces using bracket method

Collision and intersection detection of surfaces is an important problem in computer graphics and robotic engineering. A key idea of our paper is to use the bracket method to derive the necessary and sufficient conditions for the collision of two ruled surfaces. Then the numerical intersection curve can be characterized. The cases for two bounded ruled surfaces are also discussed.     

Photochromism in composite and hybrid materials based on transition-metal oxides and polyoxometalates

Photochromic materials are attractive and promising for applications in many fields. One subject in this area is to prepare and study the photochromism in composite or hybrid materials based on transition-metal oxides or polyoxometalates. Their properties not depend only on the chemical nature of each component, but also on the interface and synergy between them. Since the charge transfer plays a key role in the photochromism of these materials, it is very important to increase the charge (electrons, holes, and protons) interactions between the two components in either composites or hybrids. To realize this, one big challenge is to optimize the two components on a molecular or nanometer scale, which is closely relevant to the constituents, sample history (pre-treatment, preparation, and post-treatment), environment (humidity, presence of reducible or oxidizible matters, light-irradiation wavelength, intensity, time, etc.). Based on these, many novel composite or hybrid materials with improved photochromism, visible-light coloration, reversible photochromism, multicolor photochromism or, possibly, fast photoresponse, have been prepared during the last two decades or three. This may underscore the opportunity of using these composite and hybrid materials as the photonic applications. In present paper, we summarize thoroughly all the recent progress in these subjects.     

Design study of APS-U-type hybrid-MBA lattice for mid-energy DLSR

In recent years,a new generation of storage ring-based light sources,known as diffraction-limited storage rings(DLSRs),whose emittance approaches the diffractio...