水热法制备Sr_2FeNiO_6催化剂及其催化性能研究

采用水热法制备双钙钛矿催化剂Sr_2FeNiO_6,考察不同浓度KOH溶液(4 mol·L~(-1)、6 mol·L~(-1)、8 mol·L~(-1)、10 mol·L~(-1)、12 mol·L~(-1)、14 mol·L~(-1))对催化剂性能的影响,利用X射线衍射、比表面积测定、程序升温还原和扫描电镜等对样品进行性能表征,并以催化甲烷燃烧为目标,考察催化剂催化性能。结果表明,矿化剂KOH浓度对样品性能影响较大,当浓度为10 mol·L~(-1)时,起燃温度最低,T_(10%)为430℃;浓度为8 mol·L~(-1)时,样品比表面积最大,为19.0 m~2·g~(-1),完全燃烧温度最低,T_(90%)为610℃。     

白酒中风味物质分析研究进展

白酒是我国传统而又独具特色的蒸馏酒，也是世界六大蒸馏酒之一。白酒中含有多种风味化合物，包括酯类、醇类、酮类、醛类、酸类、萜烯类、含硫化合物等，这些风味物质虽然含量很低，但风味物质的组成及含量对白酒口感和香味的贡献很大，是形成不同酒类风格的重要因素。该文主要对近年来白酒中风味物质种类、风味物质分析前处理技术、风味物质测定方法及功能性风味成分相关研究进行了综述，以期为白酒中风味物质分析与鉴定提供一定的参考。     

Electron–hole recombination dynamics in carbon nanodots

Since their discovery, carbon nanodots (C-dots) have attracted great interest due to their strong photoluminescence (PL). Yet a full understanding of the mechanisms for PL from C-dots is still under debate. In this work, we analyzed the evolution of the time-resolved PL spectra of C-dots using picosecond time-resolved spectroscopy to explore the carrier dynamics in C-dots. Our results suggest two different pathways of electron–hole radiative recombination, each with distinct relaxation time scales: a relaxation of carriers from carbogenic core onto the surface states with a slow decay (>14 ns) and direct radiative recombination of carriers on the surface states with a fast decay (∼1.3 ns). The slow decay at short-wavelength emissions is dominant due to the effective relaxation from the carbogenic core onto the surface states, while the fast decay is dominant at long-wavelength emissions. An explanation for the excitation-dependent and independent PL properties of C-dots is also presented here using this carrier dynamic model.     

Simulation of police shooting stability training based on FPGA and sensors

Stability training refers to the practice, while the surface is unstable and activation stabilizer muscles of the trunk and goals, which may ignore other forms of exercise. For stability, the train network control system is caused by network latency and packet drop out of school. The current study aimed to analyze the accuracy of necessary shooting skills and check the balanced posture, stability, and rifle shooting performance bracelets. There is no burden on the body in different performance groups. No. Equivalent continuous-time model, proposed account. The train network control system model uses Romanov theory, some new analytical techniques to get in, and less conservative results. It will be completed. The effectiveness of the proposed method of numerical display. The proposed training in the correct use of architecture to shape muscle memory training interns position signal trainee lead to incorrect behavior. Students warned that the recent shooting would be suspended after the retry using the selected function when needed for phase detection of unnecessary or excessive exercise pistol. Combined with real-time biofeedback applications, it can lead to accelerated learning, training the number of shots that poverty can be reduced, thereby saving time and costs.     

蓝莓红豆复合饮料的研究

以蓝莓和红豆为主要原料研制复合果蔬饮料,利用单因素和正交试验,通过感官评价和沉降率优化饮料风味配方和稳定性。采用感官评分对色泽、滋味、气味、组织状态进行评价,得到最佳配方为:蓝莓汁20%、红豆汁15%、蔗糖6%、柠檬酸0.1%。通过离心沉降速率和感官评价指标研究稳定剂对饮料的稳定效果,得到稳定性配方为羧甲基纤维素钠0.05%、黄原胶0.05%、海藻酸钠0.1%。对蓝莓红豆复合饮料的杀菌条件进行初步探索,在70℃杀菌30 min条件下,微生物检测指标和理化指标均符合国家标准。     

A novel combination of precursor pyrolysis assisted sintering and rapid sintering for construction of multi-composition coatings to improve ablation resistance of SiOC ceramic modified carbon fiber needled felt preform composites

A double-layer coating composed of MoSi₂–SiO₂–SiC/ZrB₂–MoSi₂–SiC was designed and successfully constructed by a novel combination of precursor pyrolysis assisted sintering and rapid sintering to improve the ablation resistance of SiOC ceramic modified carbon fiber needled felt preform composites (CSs). The ZrB₂–MoSi₂–SiC inner layer coating was in relatively uniform distribution in the zone of 0–3 mm from the surface of CSs through the slurry/precursor infiltration in vacuum and SiOC precursor pyrolysis assisted sintering, which played a predominant role in improving oxidation and ablation resistance and maintaining the morphology of CSs. The MoSi₂–SiO₂–SiC outer layer coating was prepared by the spray and rapid sintering to further protect CSs from high-temperature oxidation. The ablation resistance of CSs coated with double-layer coating was evaluated by an oxygen-acetylene ablation test under the temperature of 1600–1800 °C with different ablation time of 1000 and 1500 s. The results revealed that the mass recession rates increased with the rise of ablation temperature and extension of ablation time, ranging from 0.47 g/(m²·s) to 0.98 g/(m²·s) at 1600–1800 °C for 1000 s and from 0.72 g/(m²·s) to 0.86 g/(m²·s) for 1000–1500 s at 1700 °C, while the linear recession rates showed negative values at 1700 °C due to the formation of oxides, such as SiO₂ and ZrO₂. The ablation mechanism of the double-layer coating was analyzed and found that a SiO₂–ZrO₂–Mo_4.8Si₃C_0.6 oxidation protection barrier would be formed during the ablation process to prevent the oxygen diffusion into the interior CSs, and this study provided a novel and effective way to fabricate high-temperature oxidation protective and ablation resistant coating.     

The investigation of gold/zirconia as a photocatalyst for the direct synthesis of imines from alcohols and aniline

Au/ZrO₂ nanoparticles have been widely used as photocatalysts in various organic syntheses because of their localized surface plasmon resonance (LSPR) effects. In our work, Au/ZrO₂ has been synthesized by a solution method and it was used as a heterogeneous catalyst in the synthesis of imines from alcohols and aniline with irradiation by visible light. The reaction occurred in two steps: step 1 was the aerobic oxidation of the alcohols and step 2 was the nucleophilic addition of aniline. Dimethyl sulfoxide (DMSO) was used as a solvent in the reaction. The selectivity in the synthesis of imines over 3 wt% Au/ZrO₂ (with mean particle size of 5 nm) was high (over 90%) with irradiation by visible light at room temperature, and an obvious difference in the conversion was observed between the reactions with light irradiation and those without light. The intensity and wavelength of the light strongly affected the reaction. The Au/ZrO₂ could be used at least 5 times. A reaction mechanism was proposed based on the experimental results. The results indicate that the reaction of alcohols and aniline using Au/ZrO₂ as the photocatalyst can proceed under mild conditions. Furthermore, this process is environmentally friendly and green.     

木质鸡胸肉生肉品质表征及检测方法研究

目的探索木质肉(woody/wooden breast,WB)生肉品质特性差异及客观检测方法。方法对不同木质鸡胸肉等级样本的重量、挤压力(CF Probe、CF TA-25)进行检测,同时在剪切实验中以剪切力(MORSF)、剪切做功(MORSE)及剪切峰值个数(PC-MORS)作为生肉质构分析指标。结果重量、CF Probe、CF TA-25、MORSF、MORSE、PC-MORS随着WB等级的递增而显著增大,2种硬度检测探头均可用于鸡胸肉的硬度检测。PC-MORS在MORSF和MORSE的基础上可有效区分WB等级,同时可显示鸡胸肉肌肉内部的层状结构信息。各测量指标之间存在不同程度的相关性,其中重量、CF Probe、MORSE、PC-MORS与WB等级之间存在极显著相关。建立的BP神经网络模型区分正常肉和木质肉的总体识别率达90.6%。结论本研究确定了木质鸡胸肉生肉硬度检测方法、质构分析的特征参数,并研究其木质化等级判定模型,研究结果可为后续木质鸡胸肉在线检测分级装置的研发提供一定的理论支撑。