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1.
Hydrogen peroxide (H2O2) has been listed as one of the 100 most important chemicals in the world. However, huge amount of residual H2O2 is hard to timely decomposed into O2 and H2O under acidic condition, easily resulting in explosion hazard. Here, we reported a core–shell structure catalyst, that is graphene with Co N structure encapsulated Co nanoparticles. Co N graphene shell serves as the active site for the H2O2 decomposition, and Co core further enhance this decomposition. Benefiting from it, the H2O2 decomposition were close to 100% after 6 cycles without pH adjustment, which increased 6 orders of magnitude compared with no catalyst. At the same time, the O2 generation reached 99.67% in 2 h with little metal leaching, and ·OH has been greatly inhibited to only 0.08%. This work can cleanly remove H2O2 with little deep oxidation and protect the process of H2O2 utilization to achieve a safer world.  相似文献   
2.
采用系统动力学(SD)方法建立城市内涝灾害应急管理SD模型。在确定模型变量权重的基础上,通过构建模型方程式并绘制内涝灾害因果回路图和存量流量图实现对事件动态模拟仿真和敏感性分析。将构建的SD模型用于西安市一场典型内涝灾害事件的仿真分析,结果表明:随着时间增长,通过模拟仿真增加对技术因素、社会因素、管理因素和自然因素的管控,城市内涝灾害应急管理效果趋于变好;SD模型中不同变量对城市内涝灾害应急管理影响存在差异,需要不断完善应急预案,加强城市排水管网建设,提高应急决策时效性。  相似文献   
3.
《Journal of dairy science》2022,105(5):4314-4323
We tested the hypothesis that the size of a beef cattle population destined for use on dairy females is smaller under optimum-contribution selection (OCS) than under truncation selection (TRS) at the same genetic gain (ΔG) and the same rate of inbreeding (ΔF). We used stochastic simulation to estimate true ΔG realized at a 0.005 ΔF in breeding schemes with OCS or TRS. The schemes for the beef cattle population also differed in the number of purebred offspring per dam and the total number of purebred offspring per generation. Dams of the next generation were exclusively selected among the one-year-old heifers. All dams were donors for embryo transfer and produced a maximum of 5 or 10 offspring. The total number of purebred offspring per generation was: 400, 800, 1,600 or 4,000 calves, and it was used as a measure of population size. Rate of inbreeding was predicted and controlled using pedigree relationships. Each OCS (TRS) scheme was simulated for 10 discrete generations and replicated 100 (200) times. The OCS scheme and the TRS scheme with a maximum of 10 offspring per dam required approximately 783 and 1,257 purebred offspring per generation to realize a true ΔG of €14 and a ΔF of 0.005 per generation. Schemes with a maximum of 5 offspring per dam required more purebred offspring per generation to realize a similar true ΔG and a similar ΔF. Our results show that OCS and multiple ovulation and embryo transfer act on selection intensity through different mechanisms to achieve fewer selection candidates and fewer selected sires and dams than under TRS at the same ΔG and a fixed ΔF. Therefore, we advocate the use of a breeding scheme with OCS and multiple ovulation and embryo transfer for beef cattle destined for use on dairy females because it is favorable both from an economic perspective and a carbon footprint perspective.  相似文献   
4.
为实现核医学广泛关注的新型医用放射性同位素177Lu的国产规模化,利用中国绵阳反应堆(CMRR)进行无载体(n.c.a.)177Lu的制备工艺研究。在常规的镧系树脂分离纯化177Lu的流程中加入可以吸附洗脱液中金属离子的DGA树脂柱,并通过特殊的流路连接方式,实现淋洗镧系树脂柱洗脱液的“在线”循环。示踪实验和三次生产流程验证表明,第一级分离的废液量降低>86%。质检分析表明,循环淋洗技术制备的无载体177Lu产品符合质量要求。研究表明,该技术显著降低了镧系树脂分离无载体177Lu中的放射性酸废液总量,可用于规模化生产工艺。  相似文献   
5.
邵宇  晏婷 《包装工程》2022,43(10):378-385
目的 以现代设计的角度解析粉彩团花纹饰,探索其传承创新的可能性。在相关研究的基础上,丰富并启发传统纹饰研究,促进传统纹饰在当代设计中的多元融合,给当下设计提供传承与创新理论支持。方法 研究“一带一路”的传统文化艺术源头,以景德镇粉彩纹饰为切入点,用现代设计的法则解析粉彩团花纹饰的形成。对馆藏的典型粉彩团花纹饰举例说明,分析其纹饰在艺术性、功能性及思想性上的独特之处,为传统纹饰在当代设计的创新做出一些有意义的探索。结论 “一带一路”背景下研究中国传统纹饰艺术不仅有历史考古与文化收集的价值,也有审美的价值。通过设计角度的解构和分析粉彩团花纹饰的基本特征、文化意义、艺术审美和传承载体等,有利于进一步解读“一带一路”源头的中国传统文化艺术内涵,促进传统元素在当代艺术中的创意传承与创新发展。  相似文献   
6.
《Ceramics International》2022,48(5):6322-6337
To optimize the corrosion, bioactivity, and biocompatibility behaviors of plasma electrolytic oxidation (PEO) coatings on titanium substrates, the effects of five process variables including frequency, current density, duty cycle, treatment time, and electrolyte Ca/P ratio were evaluated. In our systematic study, a Taguchi design of experimental based on an L16 orthogonal array was used. For this, the coatings characteristics such as the surface roughness, wettability, rutile to anatase and Ca/P ratios, and corrosion polarization resistance were investigated. After determining the optimum process variables for each response, the apatite forming ability in SBF (bioactivity behavior) and MG63 cell attachment and flattening (biocompatibility behavior) for two groups of coatings were examined. The first group was optimized based on the maximum corrosion polarization resistance and the variables were set as the frequency of 2000 Hz, the current density of 5 A/dm2, the duty cycle of 30%, the treatment time of 5 min, and the Ca/P ratio of 0.65 at. % in the electrolyte. For the second group, the maximum surface roughness, greatest Ca/P ratio, and highest wettability as well as the minimum rutile to anatase ratio in coatings, could be obtained when the variables were set as the frequency of 10 Hz, the current density of 12.5 A/dm2, the duty cycle of 50%, the treatment time of 12.5 min, and the Ca/P ratio of 1.70 at. % in the electrolyte. The results showed that while both groups of coatings indicated a significant apatite forming ability and can serve as bioactive coatings, a proper attachment and flattening of cells and consequently, the favorable biocompatibility properties were seen only in the first group.  相似文献   
7.
对 10kV 开关站噪音特性进行了测试,在此基础上从声学理论出发设计了分形声学噪声屏障,对具有良好低频隔声性能的三阶隔声屏障进行了仿真分析,通过试验测量了噪声屏障对各频段噪声的衰减效果,验证了此声学超材料的降噪有效性;并且提出了一种结合超材料声屏障的有源噪声控制方法,来补偿声屏障边缘附近的绕射声波以进一步提升降噪性能.最后,设计搭建了一套结合超材料声屏障的噪声实验系统,并进行了试验验证.  相似文献   
8.
Crude wax extracted from rice bran oil (RBO) is used to improve the oleogel properties and oxidative stability of RBO. The effect of crude rice bran wax (CrBW) on the formation characteristics and oxidative stability of oleogels is discussed. The results show that oleogels can be formed with 7.0 wt% CrBW at 20 °C. As the concentration of CrBW increases from 7.0 to 11.0 wt%, the hardness and solid fat content (SFC) of the oleogels increase significantly, and the oleogels are primarily β' crystals. Moreover, oleogel crystals formed with 5 and 7 wt% CrBW are flocculent; when the amount included is 9%, the oleogel crystals are transformed into long dendrites, and the density rises. After 90 days of storage at 20 °C, the peroxide value of oleogels formed with 9.0 wt% CrBW slowly rises from 3.21 to 6.52 mmol kg−1. Practical Applications: Oleogels prepared here by CrBW and RBO are an innovative structural lipid without trans fats. Useful information on the rich fats and nutrients in CrBW is provided, which reduces the production cost and improves the industrial production capacity.  相似文献   
9.
主要介绍换热器200余年的发展历程,对不同结构换热器的产生及典型应用进行综述。重点阐述管壳式换热器、板式换热器、微结构换热器和印刷电路板换热器四种不同结构的换热器,及其为了实现强化传热所开展的相关几何参数优化和结构改进的发展工作。分析现有换热器结构设计中存在的问题与限制,总结换热器结构更新的具体建议和发展趋势。  相似文献   
10.
Purpose: Metformin hydrochloride (MF) repurposing as adjuvant anticancer therapy for colorectal cancer (CRC) proved effective. Several studies attempted to develop MF-loaded nanoparticles (NPs), however the entrapment efficiency (EE%) was poor. Thus, the present study aimed at the facile development of a new series of chitosan (CS)-based semi-interpenetrating network (semi-IPN) NPs incorporating Pluronic® nanomicelles as nanocarriers for enhanced entrapment and sustained release of MF for efficient treatment of CRC.

Methods: The NPs were prepared by ionic gelation and subsequently characterized using FTIR, DSC, TEM, and DLS. A full factorial design was also adopted to study the effect of various formulation variables on EE%, particle size, and zeta-potential of NPs.

Results: NPs had a spherical shape and a mean particle size ranging between 135 and 220?nm. FTIR and DSC studies results were indicative of successful ionic gelation with the drug being dispersed in its amorphous form within CS-Pluronic® matrix. Maximum EE% reaching 57.00?±?12.90% was achieved using Pluronic®-123 based NPs. NPs exhibited a sustained release profile over 48?h. The MF-loaded NPs sensitized RKO CRC cells relative to drug alone.

Conclusion: The reported results highlighted the novel utility of the developed NPs in the arena of colon cancer treatment.  相似文献   
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