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海水中存在的硫酸根离子传输至混凝土内部将导致其腐蚀破坏。针对矿粉掺量0~65%的C40引气混凝土进行海洋潮汐区、大气区和水下区腐蚀1~2a,测试其水溶和酸溶硫酸根离子浓度分布;分析水泥净浆中的腐蚀产物类型及含量。试验结果表明:海洋不同腐蚀区带混凝土中硫酸根离子传输量及传输深度排序为:潮汐区水下区大气区。混凝土中反应硫酸根离子与总硫酸根离子的关系服从线性函数分布,反应量占总硫酸根离子量的90%以上,反应的硫酸根离子量随腐蚀龄期增加而增加。海洋潮汐区和水下区生成的腐蚀产物量高于大气区,主要是钙矾石和石膏;海洋大气区暴露混凝土的腐蚀产物为钙矾石。对于P.I.52.5水泥制备的C40混凝土而言,掺加65%的矿粉有助于提升混凝土抗海洋硫酸根离子侵蚀能力。 相似文献
3.
The hydration properties of cement-GGBS-fly ash blended binder and cement-GGBS-steel slag blended binder were compared. The experimental results show that the hydration rate of cement-GGBS- steel slag blended binder is higher than that of cement-GGBS-fly ash blended binder within 28 days, but lower than the latter after 28 days. The hydration of cement-GGBS-steel slag blended binder tends to produce more Ca(OH)2 than the hydration of cement-GGBS-fly ash blended binder, especially at late ages. Cement-GGBS- steel slag mortar exhibits higher strength than cement-GGBS-fly ash mortar within 28 days, but at late ages, it exhibits similar compressive strength with eement-GGBS-fly ash mortar and even slightly lower bending strength than cement-GGBS-fly ash mortar. Cement-GGBS-steel slag paste has finer early pore structure but coarser late pore structure than cement-GGBS-fly ash paste. Cement-GGBS-steel slag paste can get satisfied late pore structure and cement-GGBS-steel slag mortar can get satisfied late strength as compared with pure cement paste and pure cement mortar, respectively. 相似文献
4.
为了研究骨料与水泥石界面区(ITZ)的组成及结构对混凝土抗硫酸盐腐蚀性能的影响,利用紫外分光光度计绘制了硫酸钠溶液浸泡混凝土试样的SO2-4浸入浓度/深度曲线,并辅以扫描电镜(SEM)和电子探针能谱(EDS)等对ITZ进行观测;同时利用XRD定量分析研究了混凝土本体相和界面相的水化产物富集的差异.结果表明:Ca(OH)2、钙矾石(AFt)等晶体富集于硫酸钠溶液浸泡后试样的ITZ,引起AFt二次结晶型的硫酸盐腐蚀破坏.在适量石膏的激发下,掺入超细矿粉(GGBS)可阻止AFt转变成单硫型水化硫铝酸钙(AFm),减少AFt二次结晶的生成,明显提高抗硫酸盐侵蚀能力,试样的同深度硫酸根浓度最低,抗硫酸盐侵蚀性能最好. 相似文献
5.
This article presents the first spectroscopic data describing the processes responsible for the temporary blue-green coloration that forms during the hydration of various materials containing Ground Granulated Blast-furnace Slag (GGBS) under anoxic conditions. UV-visible-near infrared Diffuse Reflectance (DR) spectra demonstrate a striking similarity of the coloring center forming during the curing of a broad range of GGBS-bearing materials (pure GGBS with different compositions, mix Portland cement/GGBS (30/70), concrete and mortar). All spectra are similar to those of polysulfide complexes contained in the interlayer spacing of a synthetic green-colored hydrated calcium aluminate phase (AFm). This “greening effect” demonstrates a progressive oxidation of sulfide-based compounds initially contained in these materials during curing of GGBS bearing materials. 相似文献
6.
In this paper, the effects of high temperature exposure of recycled aggregate concretes in terms of residual strengths, capillary water absorption capacity and pore size distribution are discussed. Two mineral admixtures, fly ash (FA) and ground granulated blast furnace (GGBS) were used in the experiment to partially replace ordinary Portland cement for concrete production. The water to cementitious materials ratio was maintained at 0.50 for all the concrete mixes. The replacement levels of natural aggregates by recycled aggregates were at 0%, 50% and 100%. The concretes were exposed separately to 300 °C, 500 °C and 800 °C, and the compressive and splitting tensile strength, capillary water coefficient, porosity and pore size distribution were determined before and after the exposure to the high temperatures. The results show that the concretes made with recycled aggregates suffered less deteriorations in mechanical and durability properties than the concrete made with natural aggregates after the high temperature exposures. 相似文献
7.
矿渣对阿利特-硫铝酸钡钙水泥水化硬化过程的影响 总被引:1,自引:0,他引:1
通过对水泥力学性能、水化速率和水泥硬化浆体孔结构的测定,结合XRD、SEM分析,研究了矿渣对阿利特-硫铝酸钡钙水泥水化硬化过程的影响。研究结果表明:掺入矿渣后,水泥的早期强度下降幅度较大,但后期强度下降幅度较小。在试验掺量范围内,当矿渣掺量为20%时,该水泥各龄期抗压强度下降幅度最小,其后期抗压强度接近纯熟料水泥;加入矿渣后,水泥水化热明显降低,矿渣在受到碱激发与硫铝酸盐双重激发作用下发生二次水化反应,使水泥水化速率有一定增加而出现第三个放热峰;矿渣二次水化反应有效地改善了硬化水泥浆体的孔结构,使水泥后期强度逐渐增加。 相似文献
8.
矿渣混凝土硫酸盐腐蚀研究 总被引:2,自引:0,他引:2
研究了矿渣混凝土在5%Na2SO4溶液中浸烘循环,其相对动弹性模量、幅值及抗压强度演化规律.试验结果表明:混凝土相对动弹性模量先下降,后上升,再保持稳定,最后下降直至破坏;其幅值在前100次保持稳定,后下降直至破坏.混凝土抗硫酸盐腐蚀能力随矿渣掺量的增加而增加.相比于普通混凝土,随矿渣掺量增加,混凝土抗压强度损失率下降了28%~62%.混凝土在硫酸盐溶液中浸烘循环,其腐蚀产物为钙矾石和石膏.膨胀性腐蚀产物导致了混凝土浆集界面区和浆体区开裂,并最终导致混凝土破坏. 相似文献
9.
通过试验研究,探讨了不同强度等级的矿渣混凝土和普通混凝土在7 d,28 d,90 d,180d,365 d 龄期的抗压强度,研究了矿渣混凝土的抗冻融耐久性.试验表明,强度等级、养护条件、矿渣掺量等因素对矿渣混凝土的强度、抗冻融耐久性有着显著的影响;矿渣混凝土的抗冻融耐久性明显优于同等级的普通混凝土;矿渣掺量愈大,矿渣混凝土的抗冻融耐久性愈差 相似文献
10.
The influence of concrete mixes and commonly used mineral additions and their effects on the near surface performance of vertically cast concrete against controlled permeable formwork (CPF) are the focus of this study. Three grades of concrete (C25, C30 and C45) and mineral additives including GGBS and PFA have been tested for surface performance in situ with CPF. The various loadings were chosen to represent the minimum and maximum levels seen in standard industry practice. The range of tests used to characterise the near surface performance include subjective assessment of surface quality, surface hardness and surface tensile strength. Permeability studies of the liners after casting indicate that no excessive embedding of fine particles occurred irrespective of constituents used. Surface quality was dramatically improved in each case and changes to surface colour through densification were quantified. Near surface performance studies indicated a significant improvement for all systems studied. 相似文献