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目的 菱形纹样是我国古老的几何纹样之一,其历史悠久、应用广泛,在不同地域和文化背景下被赋予了不同的文化内涵,厘清纹样的在地性符号所指,是提升传统工艺传承与设计创新的方法路径。方法 以贵州花戛乡布依族扎染技艺中的菱形纹样为研究个案,结合人类学的田野调查法和艺术设计学的比较研究法,对花戛布依族服装配饰中的扎染菱形纹样进行综合考证和分析。结论 认为花戛扎染菱形纹样是布依族日用器物“升”的形态转译,是农耕背景下布依人祈求丰收的文化符号载体。有着文化符号功能的菱形“Ndaeh Sengh”纹样,与布依人生活、习俗、地域环境等方面存在多维的联结,“Ndaeh Sengh”越多代表农作物收成越好,寓意丰收和富足。“Ndaeh Sengh”作为农耕记忆背景下布依族集体无意识原型形式的外化,其制作工艺和纹样所承载的文化记忆对于非遗保护、工艺传承、非遗设计等方面都有一定的理论指导意义。 相似文献
3.
《International Journal of Hydrogen Energy》2022,47(93):39586-39594
The H2 storage properties of isoreticular metal-organic framework materials (IRMOFs), MOF-5 and IRMOF-10, impregnated with different numbers and types of heterogeneous C48B12 molecules were investigated using density functional theory and grand canonical Monte Carlo (GCMC) calculations. The excess hydrogen adsorption isotherms of IRMOFs at 77 K within 20 bar indicate that suitable number and type of C48B12 molecules play a crucial role in improving the H2 storage properties of IRMOFs. Among the studied pure and nC48B12 (n = 1, 2, 4, 8) in Ci symmetry impregnating into MOF-5, at 77 K under 6 bar, MOF-5-4C48B12 with a 3.5 wt% and 29.9 g/L hydrogen storage density, and at 77 K under 12 bar, the pure MOF-5 with a 4.9 wt% and 31.0 g/L hydrogen storage density has the best hydrogen storage properties. Whereas, among the studied pure and nC48B12 (n = 1, 2, 4, 8) in S6 symmetry impregnating into IRMOF-10, IRMOF-10-8C48B12 always shows the best hydrogen storage properties among the pure and C48B12-impregnated IRMOF-10 at 77 K within 20 bar. IRMOF-10-8C48B12 has a 6.0 wt% and 34.6 g/L hydrogen storage density at 77 K under 6 bar, and has a 7.1 wt% and 41.4 g/L hydrogen storage density at 77 K under 12 bar. The confinement effect of IRMOFs on C48B12 molecules, and steric hindrance effect of C48B12 molecules on IRMOFs mainly affects the H2 uptake capacity by comparing the absolute H2 molecules in individual IRMOFs units, C48B12 molecules, and IRMOFs-nC48B12 compounds. The absolute hydrogen adsorption profiles show that eight C48B12 molecules impregnating into MOF-5 can exert obvious steric effects for H2 adsorption. The saturated gravimetric and volumetric H2 densities of IRMOF-10-8C48B12 higher than those of MOF-5-8C48B12 due to with larger free volume. 相似文献
4.
Liu Yang Pengfei Yu Wenyuan Li Fengliang Cao Xin Jin Sheng Xue Xianglong Zhang Tingwei Zhang Mingbo Wu Wenting Wu 《American Institute of Chemical Engineers》2022,68(9):e17760
Hydrogen peroxide (H2O2) has been listed as one of the 100 most important chemicals in the world. However, huge amount of residual H2O2 is hard to timely decomposed into O2 and H2O under acidic condition, easily resulting in explosion hazard. Here, we reported a core–shell structure catalyst, that is graphene with Co N structure encapsulated Co nanoparticles. Co N graphene shell serves as the active site for the H2O2 decomposition, and Co core further enhance this decomposition. Benefiting from it, the H2O2 decomposition were close to 100% after 6 cycles without pH adjustment, which increased 6 orders of magnitude compared with no catalyst. At the same time, the O2 generation reached 99.67% in 2 h with little metal leaching, and ·OH has been greatly inhibited to only 0.08%. This work can cleanly remove H2O2 with little deep oxidation and protect the process of H2O2 utilization to achieve a safer world. 相似文献
5.
Guishang Pei Junyi Xiang Qingyun Huang Xuewei Lv 《Journal of the American Ceramic Society》2022,105(10):6359-6369
A double pyrovanadate CaMgV2O7 sample was synthesized via a facile solid-state route under an air atmosphere. The nonequilibrium formation pathways of the CaMgV2O7 were investigated via powder X-ray diffraction. A multistep reactions path (metavanadates–pyrovanadates–double pyrovanadate CaMgV2O7) was proposed to describe the formation of the CaMgV2O7 considering the thermodynamic and kinetic factors. The cell unit parameters of the CaMgV2O7 sample indicated the crystallization according to a monoclinic system with space group P12/c1(14), and the lattice parameters of a = 6.756 Å, b = 14.495 Å, c = 11.253 Å, β = 99.12, and V = 108.806 Å3. X-ray photoelectron spectroscopy also confirmed the +5 oxidation state vanadium in CaMgV2O7. The endothermic effects at 1033 and 1143 K were related to the incongruent melting and liquidus temperatures of CaMgV2O7, respectively. The comprehensive thermodynamic properties of CaMgV2O7 were established in both low- and high-temperature regions, utilizing a physical property measurement system and multi-high-temperature calorimetry (96 lines). The heat capacity (200 J mol K−1) and entropy (198 J mol K−1) at 298.15 K were computed based on the low-temperature heat capacity values, and the enthalpy of formation at 298.15 K was also estimated. The fitted high-temperature capacity can be used to obtain the changes in the enthalpy, entropy, and Gibbs free energy. This study is part of building a reliable thermodynamic database of the CaO–MgO–V2O5 system. 相似文献
6.
This work describes facile synthesis of a porous polymeric material ( T-HCP ) using readily available reagents. Specifically, T-HCP is a thermally stable and hypercrosslinked polymer (HCP) that is essentially microporous with a high BET specific surface area (940 m2 g?1). Triptycene based polymers are known to feature internal free volume. Thus, the incorporation of triptycene units and extensive crosslinking by an external cross-linker in T-HCP makes it a promising adsorbent for small gas capture applications. Experimental results show that T-HCP demonstrated good CO2 capture capacity of 132 mg g?1 (273 K, 1 bar). Molecular hydrogen storage capacity of T-HCP is estimated to be 17.7 mg g?1 (77 K, 1 bar). T-HCP revealed high CO2/N2 selectivity (up to 63) as well as promising CO2/CH4 (up to 9.1) selectivity suggesting its potential applicability for CO2 separation from flue and natural gases. 相似文献
7.
摘 要:核心网业务模型的建立是5G网络容量规划和网络建设的基础,通过现有方法得到的理论业务模型是静态不可变的且与实际网络存在偏离。为了克服现有5G核心网业务模型与现网模型适配性较差以及规划设备无法满足用户实际业务需求的问题,提出了一种长短期记忆(long short-term memory,LSTM)网络与卷积LSTM (convolution LSTM,ConvLSTM)网络双通道融合的 5G 核心网业务模型预测方法。该方法基于人工智能(artificial intelligence,AI)技术以实现高质量的核心网业务模型的智能预测,形成数据反馈闭环,实现网络自优化调整,助力网络智能化建设。 相似文献
8.
设计了一种基于阿基米德螺线的新型螺旋光子晶体光纤,该光纤以二氧化硅为基底材料,包层由24个螺旋臂组成,每个螺旋臂包含11个小空气孔,纤芯设有大空气孔,包层与纤芯中间的环形区域用于传输轨道角动量模式。该结构在1300~1800 nm波段上可支持22种轨道角动量模式稳定传输,在1550 nm波长下,有效折射率差最高可达2.89×10^(-3),色散系数最低可达66.4 ps/(nm·km),非线性系数最低可达2.17 W^(-1)·km^(-1),且1500~1600 nm波段上的色散值变化均小于15.15 ps/(nm·km)。此螺旋光子晶体光纤不仅结构简单,且具有低非线性、色散平坦的性能,为螺旋光子晶体光纤的设计提供了思路。 相似文献
9.
Christian Soize Roger Ghanem 《International journal for numerical methods in engineering》2022,123(1):268-290
The probabilistic learning on manifolds (PLoM) introduced in 2016 has solved difficult supervised problems for the “small data” limit where the number N of points in the training set is small. Many extensions have since been proposed, making it possible to deal with increasingly complex cases. However, the performance limit has been observed and explained for applications for which N is very small and for which the dimension of the diffusion-map basis is close to N. For these cases, we propose a novel extension based on the introduction of a partition in independent random vectors. We take advantage of this development to present improvements of the PLoM such as a simplified algorithm for constructing the diffusion-map basis and a new mathematical result for quantifying the concentration of the probability measure in terms of a probability upper bound. The analysis of the efficiency of this extension is presented through two applications. 相似文献
10.
目的 了解近年来传统纺织服饰图案的研究动态及发展趋势,归纳学术研究成果并进行评价,总结研究传统服饰图案的意义和对现代设计的启示。方法 基于史论视角、社会文化视角、工艺美术视角和设计艺术视角梳理相关文献,结合现有研究分析中国传统服饰图案的资料来源及其特色、传统服饰图案的研究热点、新时代传统服饰图案的生存策略及中国传统服饰图案创新设计的应用领域。结果指出传统服饰图案的研究史料取材丰富、研究类型呈现多元;当前传统服饰图案的传承与创新体现了数字化发展、美育引导、政策支持的特点;传统服饰图案在服装设计、公共空间、文创产品中大放异彩。结论 中国传统纺织服饰图案研究多点开花,但缺乏系统整体的“中国传统纺织服饰图案知识谱系”用于指导相关研究和实践,对中国传统纺织服饰图案的研究多处于实证分析的层面且欠缺深入独到的理论,通过综述与价值阐述,提出研究的不足之处,纵深学术研究,同时为中国传统纺织服饰图案的现代设计提供新思路。 相似文献