Experimental investigation on gasification characteristics of polycarbonate (PC) microplastics in supercritical water

In order to solve the problem of marine microplastics and realize the harmless resource utilization of plastics, the gasification experiments of polycarbonate (PC) microplastics were carried out in supercritical water and a novel seawater gasification of microplastic experiment was investigated. In this paper, the effects of different operating conditions (temperature, time, feedstock concentration, pressure) on gasification performance were discussed. The gasification kinetic of microplastics in supercritical water was calculated. The experimental results showed that the increase in gasification temperature and time enhanced the cracking reaction and free radical reaction of the microplastics to increase the gasification efficiency, while the reduction in feedstock concentration improved the gasification efficiency by increasing the gasification level of unit feedstock. The change in pressure had no significant effect on gasification due to the fact that the properties of the supercritical water were not significantly changed. It was found that the valuable results that all alkali metal salts in seawater promote hydrogen conversion, while in terms of carbon conversion, only KCl, CaCl₂, NaHCO₃ and seawater had a significant catalytic effect on the gasification. Seawater gasification of microplastics was a potential resource utilization method. Finally, it was considered that the PC plastic gasification conformed to the random nucleation and subsequent growth model (n = 3), and the reaction activation energy was 230.45 kJ/mol, which was smaller than that of traditional pyrolysis.     

大跨度先张法预应力混凝土双T板的生产

大跨度先张法预应力混凝土双T板具有跨度大、结构性能好、成本低、整体性好等特点,被广泛应用于工业建筑。结合实际工程,介绍了大跨度双T板的生产工艺,并重点阐述了钢绞线张拉、预应力控制、混凝土浇筑和养护工艺,可为大跨度双T板的生产应用提供参考。     

薄板坯连铸连轧流程专利分析

以Orbit专利分析平台为主要研究工具，从专利文献中抽取专利数量指标和专利质量指标来构建评价薄板坯连铸连轧技术竞争力和企业创新能力的指标体系，结合其他文献研究的成果，从产业发展的实际出发做出分析，系统揭示了自薄板坯连铸连轧技术开发以来的技术进步、专利布局、发展演化、国内外发展现状、技术竞争实力等，有助于在专利文献提供的线索启发下开发新产品、新技术，从而有效提高研发效率。     

吹氩流量对结晶器流场影响的插钉工业试验

 结晶器吹氩流量对流场分布有明显影响，因此明确吹氩流量对结晶器内流场分布的影响规律对提高铸坯质量有重要意义。通过插钉法工业试验研究了吹氩流量对结晶器内流场分布的影响，并且定量分析了液位波动的变化。结果表明，随着吹氩流量的增大，流场形态从双环流逐步转变为复杂流和单环流。结晶器内流场形态从双环流转变为复杂流和单环流的过程中，水口附近速度逐渐增大，液位逐渐升高，弯月面速度分布逐渐转变为从水口流向窄面，液位波动也相应增大。因此，生产过程中应选择合适的吹氩流量，避免产生复杂流和单环流，以提高铸坯质量。     

砂砾石地基上水闸闸墩下局部灌浆效果及合理范围分析

水闸通常需要进行地基处理,以降低差异沉降和底板应力。根据水闸荷载集中在闸墩上的特点,提出了一种在闸墩下的砂砾石地基局部灌浆的处理方式。结合工程实例,通过有限元软件ABAQUS计算和比较地基局部灌浆前后闸底板的应力,该地基处理方式降低了底板应力。比较不同灌浆范围时闸底板的最大拉应力,发现当地基局部灌浆区域总宽度与闸室宽度的比值约为35%时,闸底板最大拉应力的降幅效果最好。     

PLC控制在气力除灰系统的应用

本文根据攀钢发电厂除灰系统的控制性能要求,采用“上位机+PLC”组成的控制系统实现对除灰系统的控制.该控制系统具有抗干扰能力强、可靠性高、操作简便、扩展方便等优点.     

垂直段高度对特厚板坯内部夹杂物的影响

夹杂物是降低铸坯内部质量的重要缺陷。增加连铸机垂直段高度有利于减少铸坯内部夹杂物的数量并改善其分布。为了得出适宜的垂直段高度,采用数值模拟方法研究了连铸机垂直段高度对特厚板坯内部钢液流动和夹杂物运动的影响。研究结果表明,垂直段高度为3.5m时,有利于特厚板坯中夹杂物上浮并良好分布。研究结果对选择特厚板坯连铸机的垂直段高度具有重要意义。     

Electroactive polythiophene/polystyrene bottlebrushes as morphology compatibilizers in photovoltaic systems

Poly(3‐thiophene ethanol) (P3ThEt)‐graft‐polystyrene (PSt) bottlebrushes were synthesized and applied in active layers of poly(3‐hexylthiophene) (P3HT):phenyl‐C71‐butyric acid methyl ester (PC71BM) solar cells as morphology compatibilizers. In the presence of 15 wt% of P3ThEt‐graft‐PSt bottlebrush compatibilizers, the P3HT crystallite dimensions (D₍₁₀₀₎ = 45.67 nm and D₍₀₂₀₎ = 30.12 nm) and R_mean (38.96 nm) of PCBM clusters were the largest and the layer spacings were all the smallest (d₍₁₀₀₎ = 1.054 nm, d₍₀₂₀₎ = 0.301 nm and d_(PCBM) = 0.406 nm). These dimensional properties led to better hole (1.9 × 10^?3 cm² V^?1 s^?1) and electron (1.2 × 10^?2 cm² V^?1 s^?1) mobilities. The content of bottlebrushes was optimized at 15 wt%, and thereby the best photovoltaic results including the maximum cell efficiency of 5.37% were obtained for this turning point (12.75 mA cm^?2, 61%, 0.69 V). On exceeding the optimum weight percentage, all photovoltaic parameters decreased markedly and reached even less than that of pristine devices (1.92% versus 2.24%). After an optimum weight percentage of compatibilizers, further enhancement in bottlebrush content in active layers saturated and finally oversaturated the system and, consequently, the cell parameters significantly decreased. Accumulation of bottlebrushes in interfaces and donor/acceptor phases ruined the system function even with large and packed P3HT crystallites and PC71BM clusters. © 2019 Society of Chemical Industry     

固溶处理对节镍型2101双相不锈钢组织及力学性能的影响

采用光学显微镜、透射电镜和X射线衍射等研究了固溶处理对2101节镍型双相不锈钢连铸坯边部试样的组织、相比例和力学性能的影响。结果表明:在1050~1150℃固溶处理时,双相不锈钢具有很好的高温塑性;在1000~1150℃温度范围,随着温度的升高,实验钢的断面收缩率和铁素体相比例先减小后增加;随着固溶温度增加,实验钢的抗拉强度逐渐降低,但在1050℃时有所增加,这是由于在此温度固溶过程中,铸态试样相界处Cr2N析出相完全溶解,使得大量的N原子集中在相界处,促进了相界附近的铁素体相发生相变,转变成奥氏体相,导致在此1050℃时实验钢铁素体相的比例减小,断面收缩率减小,抗拉强度增加。