碳中和背景下配电网差异化节能降耗潜力评估分

为了提高配电网差异化节能降耗效果，解决现有潜力评估方法存在的应用性能差的问题，提出碳中和背景下配电网差异化节能降耗潜力优化评估方法。根据配电网的空间结构，构建相应的等值电路模型。在该模型下，从设备损耗和运行附加损耗2个方面计算配电网的损耗量。根据损耗量计算结果，确定配电网差异化碳中和节能降耗方式。从静态和动态2个角度设置潜力评估指标，通过指标数据处理、指标权重求解等步骤，得出配电网差异化节能降耗潜力的综合量化评估结果。将设计潜力评估方法应用到配电网的差异化节能降耗改造工作中，能够有效降低配电网的实际线损量、降低区域损耗费用，并具有较高的应用价值。     

Numerical study on laminar burning velocity of ammonia flame with methanol addition

The combustion characteristics of ammonia/methanol mixtures were investigated numerically in this study. Methanol has a dramatic promotive effect on the laminar burning velocity (LBV) of ammonia. Three mechanisms from literature and another four self-developed mechanisms constructed in this study were evaluated using the measured laminar burning velocities of ammonia/methanol mixtures from Wang et al. (Combust.Flame. 2021). Generally, none of the selected mechanisms can precisely predict the measured laminar burning velocities at all conditions. Aiming to develop a simplified and reliable mechanism for ammonia/methanol mixtures, the constructed mechanism utilized NUI Galway mechanism (Combust.Flame. 2016) as methanol sub-mechanism and the Otomo mechanism (Int. J. Hydrogen. Energy. 2018) as ammonia sub-mechanism was optimized and reduced. The reduced mechanism entitled ‘DNO-NH3’, can accurately reproduce the measured laminar burning velocities of ammonia/methanol mixtures under all conditions. A reaction path analysis of the ammonia/methanol mixtures based on the DNO-NH3 mechanism shows that methanol is not directly involved in ammonia oxidation, instead, the produced methyl radicals from methanol oxidization contribute to the dehydrogenation of ammonia. Besides, NO_x emission analysis demonstrates that 60% methanol addition results in the highest NO_x emissions. The most important reactions dominating the NO_x consumption and production are identified in this study.     

塔里木盆地塔西南坳陷柯东构造带甫沙4井原油来源及充注过程

甫沙4井位于塔里木盆地塔西南坳陷昆仑山前冲断带的柯东构造带上，北部和东部分别发育有柯克亚和柯东1井油气田。为研究甫沙4井原油来源与充注过程，对原油样品和连续抽提后的含油砂样各组分（游离态、束缚态、包裹体）进行GC、GC?MS和 GC?IRMS分析，与柯克亚凝析油气田油样进行油—油对比。结果表明：甫沙4井晚期充注原油组分具有C_29?32重排藿烷、重排甾烷和Ts相对含量高，C_27?29甾烷ααα 20R分布呈反“L”型，以及正构烷烃单体碳同位素值较低等特征，与柯克亚凝析油气田来源于二叠系普司格组（P_2?3p）烃源岩的主体原油（I类）地球化学特征一致。而早期充注的原油组分具有重排藿烷、重排甾烷和Ts相对含量较低，C_27?29甾烷ααα 20R分布呈“V”型，以及正构烷烃单体碳同位素值较高等特征，与柯克亚凝析油气田来源于中—下侏罗统湖相泥岩的II类原油地球化学特征一致。甫沙4井经历3个阶段成藏过程：①在上新世，二叠系烃源岩于生油晚期阶段生成的I类原油运移至柯克亚构造带或柯东构造带深部形成油藏；②在更新世早期，侏罗系烃源岩于生油早—中期生成的II类原油运移至甫沙4井白垩系储层；③在第四纪，强烈的构造作用使深部I类原油沿断裂调整进入甫沙4井白垩系储层。最终造成甫沙4井白垩系储层II类原油先充注，I类原油后充注的特殊现象。     

价值网络语境下企业设计价值创新路径研究

目的 在新的视角下，提出一种价值创新路径模型，对设计驱动型企业的价值实现方式进行有效补充。方法 通过文献研究，论述了企业关系由价值链到价值网转变的历史趋势;通过比较研究，对价值实现过程中主客体之间的4种关系进行了类比分析，提出了不同主客体关系状态下设计实践的具体表现方式。结果 在价值网络语境下，以价值论为理论依据，从主客体之间的关系入手，构建设计价值创新路径模型。结论 通过分析证明:“主客体统一状态”是企业价值创造的理想状态;主客体关系一直处于动态的变化过程中;客体对主体的“意义”也一直处于动态变化中。在这种动态变化的关系网络中，设计驱动方式已经成为企业创新的重要模式，企业如何捕获并诠释“意义”，成为价值实现的关键所在。     

个性化学习路径推荐综述

近年来，伴随着现代信息技术的迅猛发展，以人工智能为代表的新兴技术在教育领域得到了广泛应用，引发了学习理念和方式的深刻变革.在这种大背景下，在线学习超越了时空的限制，为学习者“随时随地”学习提供了更多的可能性，从而得到了蓬勃发展.然而，在线学习中师生时间、空间分离的特征，导致教师无法及时掌握学生的学习状态，一定程度上制约了在线学习中教学质量的提升.面对多元化的学习需求及海量学习资源，如何迅速完成学习目标、降低学习成本、合理分配学习资源等问题成为限制个人和时代发展的重大问题.然而，传统的“一刀切”的教育模式已经不能满足人们获取知识的需求了，需要一个更高效、更科学的个性化教育模式，以帮助学习者以最小的学习成本最大限度地完成学习目标.基于以上背景，如何自动高效识别学习者特征，高效地组织和分配学习资源，为每一位学习者规划个性化路径，成为面向个体的精准化教育资源匹配机制研究中亟待解决的问题.系统地综述并分析了当前个性化学习路径推荐的研究现状，并从多学科领域的角度分析了对于同一问题的不同研究思路，同时也归纳总结了当前研究中最为主流的核心推荐算法.最后，强调当前研究存在的主要不足之处.     

Formation of Sn filled CNTs nanocomposite: Study of their magnetic,dielectric properties and enhanced microwave absorption performance at gigahertz frequencies

The Simplistic formation, advantageous configuration, non-colossal magnetoresistance and broadband absorption are important parameters for microwave absorbent materials. In this study, a core-shell nanocomposite comprising of Sn-filled carbon nanotubes (Sn/CNTs) was prepared by arc discharge method. The microstructure, morphology and surface composition of Sn/CNTs-based core-shell nanocomposites were characterized in detail. Sn/CNTs nanocomposite showed a magnetic signal due to the broken bonds and defects at interfaces in Sn/CNTs. The weak ferromagnetism was found to be helpful in improving magnetic permeability in the Sn/CNTs which confirms its role as a magnetic loss material under incident electromagnetic wave. Sn-filled CNTs revealed an appropriate value of dielectric constant, which plays an important role in impedance matching upon incident electromagnetic wave. The composite of Sn-CNTs and paraffin with a 50 wt % loading showed the lowest reflection loss (RL) of ?43.87 dB at 10 GHz, with a wide effective absorption band (RL ≤ ?10 dB) of 3 GHz in thickness of 2.3 mm. This enhanced performance is attributed to the combined effect of the conduction loss in one-dimensional core-shell architecture, the interfacial loss Sn-CNT interface, the magnetic loss due to defects-induced ferromagnetism in Sn shell, and in the carbon-containing atomic layers of CNTs.     

Recent insights in synthesis and energy storage applications of porous carbon derived from biomass waste: A review

In the last few decades, global warming, environmental pollution, and an energy shortage of fossil fuel may cause a severe economic crisis and health threats. Storage, conversion, and application of regenerable and dispersive energy would be a promising solution to release this crisis. The development of porous carbon materials from regenerated biomass are competent methods to store energy with high performance and limited environmental damages. In this regard, bio-carbon with abundant surface functional groups and an easily tunable three-dimensional porous structure may be a potential candidate as a sustainable and green carbon material. Up to now, although some literature has screened the biomass source, reaction temperature, and activator dosage during thermochemical synthesis, a comprehensive evaluation and a detailed discussion of the relationship between raw materials, preparation methods, and the structural and chemical properties of carbon materials are still lacking. Hence, in this review, we first assess the recent advancements in carbonization and activation process of biomass with different compositions and the activity performance in various energy storage applications including supercapacitors, lithium-ion batteries, and hydrogen storage, highlighting the mechanisms and open questions in current energy society. After that, the connections between preparation methods and porous carbon properties including specific surface area, pore volume, and surface chemistry are reviewed in detail. Importantly, we discuss the relationship between the pore structure of prepared porous carbon with surface functional groups, and the energy storage performance in various energy storage fields for different biomass sources and thermal conversion methods. Finally, the conclusion and prospective are concluded to give an outlook for the development of biomass carbon materials, and energy storage applications technologies. This review demonstrates significant potentials for energy applications of biomass materials, and it is expected to inspire new discoveries to promote practical applications of biomass materials in more energy storage and conversion fields.     

Surface energies in high-entropy carbides with variable carbon stoichiometry

The carbon vacancy in high-entropy carbides (HECs) has a significant impact on their physical and chemical properties, yet relevant studies have still been relatively few. In this study, we investigate the surface energies of HECs with variable carbon vacancies through first-principles calculations. The results show that the surface energy of the (1 0 0) surface of the stoichiometric HECs is significantly lower than that of (1 1 1) surface. With the decrease in carbon stoichiometry, the surface energies of both (1 0 0) and (1 1 1) surfaces increase gradually, which is mainly due to the weakening of covalent bonding and the decrease of metal Hirshfeld-I (HI) charges. However, the surface energy of (1 0 0) surface increases more quickly than that of (1 1 1) surface and will exceed that of (1 1 1) surface when the carbon stoichiometry decreases to a certain extent, which is primarily attributed to the greater decrease rate of metal HI charges of (1 0 0) surface.     

Ternary type BaY2ZnO5: Eu3+ deep-red phosphor for possible latent fingerprint,security ink and WLED applications

Pc-WLEDs are considered to play a spectacular role in future generation light sources in view of their outstanding energy efficiency. In this regard, Eu³⁺ activated BaY₂ZnO₅ phosphor was prepared and investigated by XRD, PL and SEM analyses. Rietveld refinement analysis was carried out to confirm the structure of the synthesized phosphor. The prepared phosphor shows an intense red emission around 627 nm under excitation by near UV light. The ⁵D₀-⁷F₂ transition intensity of the prepared phosphor is three times higher compared to the commercial (Y,Gd)BO₃:Eu³⁺ red phosphor. The CIE colour coordinates of BaY₂ZnO₅:Eu³⁺ (9mol%) phosphor corresponds to be (0.6169, 0.3742) and it has a high 97.9 % colour purity. The obtained results reveal the utility of BaY₂ZnO₅:Eu³⁺ phosphor as an efficient red component in WLEDs, anti-counterfeiting and fingerprint detection applications.     

Multi-skeletal PtPdNi nanodendrites as efficient electrocatalyst with high activity and durability towards oxygen reduction reaction

Engineering alloy nanostructures with a combination of highly active noble metals (Pt and Pd) and less electronegative non-noble metal (Ni) is found to be crucial for improving surface reactivity by enriching with active Pt sites. Herein, a multi-skeletal PtPdNi nanodendrites (NDs) was successfully formed by a simple one-pot method with structure directing agent. The modification of Pt electronic structure and their interaction due to compressive strain were explored using benchmark characterization techniques, which showed that the PtPdNi NDs possess Pt-enriched surface, corroborating to more active catalyst sites for oxygen reduction reaction (ORR) in acidic medium. The PtPdNi NDs have a higher electrochemical surface area (63 m² g^?1) and an earlier onset potential (1.01 V) than PtPd NDs, PtNi NDs, and commercial Pt/C catalysts, indicating the outstanding ORR performance. The high mass and specific activities, as well as superior durability after accelerated degradation test (ADT), highlight the remarkable electrocatalytic performance of PtPdNi NDs over others. As a result, enhancing Pt utilization through the formation of PtPdNi NDs could be a reliable strategy to improve ORR electrocatalysis for polymer electrolyte membrane fuel cell (PEMFC) applications.