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1.
《Ceramics International》2022,48(5):6266-6276
Porous diatomite ceramics with hierarchical pores and high apparent porosity (50.29–56%) were successfully fabricated via direct stereolithography. The pre-ball-milling time, dispersant type and dispersant concentration were systematically investigated to prepare diatomite pastes with high solid loading, low viscosity and a self-supporting effect. The results showed that a pre-ball-milling time of 24 h was more suitable to prepare diatomite pastes with high solid loading, and Span80 at 2 wt% was the optimal dispersant to obtain 40 vol% diatomite paste with a low viscosity and a self-supporting effect. To restrain the formation of defects, a heating rate as low as 0.2 °C/min was allowed to control the pyrolysis rate in the multistage debinding process. At sintering temperatures ranging from 900 °C to 1000 °C, porous diatomite ceramics exhibited a typical bimodal porosity, high apparent porosity and great flexural strength. 相似文献
2.
Processing and properties of Nextel™ 720 fiber reinforced alumina-zirconia ceramic matrix composites
《Ceramics International》2022,48(18):25849-25857
The continuous Nextel? 720 fiber-reinforced zirconia/alumina ceramic matrix composites (CMCs) were prepared by slurry infiltration process and precursor infiltration pyrolysis (PIP) process. The introduction of submicron zirconia powders into the aqueous slurry was optimized to offer comprehensively good sintering activity, high thermal resistance and good mechanical properties for the CMCs. Meanwhile, the zirconia and alumina preceramic polymers were used to strengthen the porous ceramic matrix through the PIP process. The final CMC sample achieved a high flexural strength of 200 MPa after one infiltration cycle of alumina preceramic polymer and thermal treatment at 1150 °C for 2 h. The flexural strength retention of the improved CMC sample was 104% and 89% respectively after thermal exposure at 1100 °C and 1200 °C for 24 h. 相似文献
3.
《Ceramics International》2022,48(4):5091-5099
The impact of the addition of TiO2 nanoparticles and nanowires on the morphology, phase characteristics, contact angle, and electrochemical performance of chemically bonded phosphate ceramic coatings (CBPCs) was investigated. The chemical composition and surface morphology of the TiO2 nanoparticle and nanowire modified with and without (heptadecafluoro-1,1,2,2-tetradecyl) trimethoxysilane were characterized. Results indicated that the hydrophobic –CF2– and –CF3 groups were successfully introduced into the TiO2 nanoparticles and nanowires after modification. Corrosion resistance of CBPCs with TiO2 was evidently improved compared with that without TiO2. Such improvement was mainly due to the combined effects of low surface energy materials and micro/nano structures. In addition, CBPCs with TiO2 nanowires exhibited higher hydrophobicity and corrosion resistance than those with TiO2 nanoparticles because of the special columnar structure of the nanowires. 相似文献
4.
《Ceramics International》2022,48(18):26351-26360
Foams glass were obtained from solid waste of flat glass and exhausted alkaline batteries. The physical, chemical, crystalline and morphological properties of the samples were obtained using the Archimedes principle, X-ray diffractometry (XRD), scanning electron microscopy (SEM). The results revealed glass foams with apparent porosities in the range of 55–64% and apparent densities in the range of 0.40–0.79 g cm?3. The manganese oxide and graphite contained within the cathode of alkaline batteries acted as both oxidizing agents and as foaming agents. The zinc contained in the anode acted as a pore stabilizing agent and the zinc oxide as a semiconductor material. The foam glass that was composed of flat glass with an anode of Zn and ZnO, and a cathode of Mn2O3 and Mn3O4 (named An8), showed the greatest potential for heterogeneous photocatalysis, with a maximum efficiency of 95.9% after 3 h of treatment of solution containing dye. These results suggest the feasibility of producing foam glass from waste, as well as its potential application in photocatalytic systems, such as in the low-cost treatment of water. 相似文献
5.
《Journal of the European Ceramic Society》2022,42(13):5684-5690
In this work, Zn-Ni co-modified LiMg0.9Zn0.1-xNixPO4 (x = 0–0.1) microwave dielectric ceramics were fabricated using a solid state synthesis route. Rietveld refinement of the XRD data revealed that all ceramic samples have formed a single phase with olivine structure. SEM images showed that the samples have a dense microstructure, that agrees with the measured relative density of 97.73 %. Based on the complex chemical bond theory, Raman and infrared reflectance spectra, we postulate that εr is mainly affected by the ionic polarizability, lattice and bond energy, while P-O bond plays a decisive role in Q×f and τf value. Optimum properties of Q×f ~ 153,500 GHz, εr ~ 7.13 and τf ~ ?59 ppm/°C were achieved for the composition LiMg0.9Zn0.06Ni0.04PO4 sintered at 875 ℃ for 2 h. This set of properties makes these ceramics an excellent candidate for LTCC, wave-guide filters and antennas for 5 G/6 G communication applications. 相似文献
6.
《International Journal of Hydrogen Energy》2022,47(73):31202-31222
Dark fermentation of sugarcane vinasse can be used as a “cleaning” step to remove sulfate prior to methanogenesis because sulfidogenic conditions can be successfully established in parallel with biohydrogen production. Using a 22 central composite rotational design (CCRD) and response surface methodology (RSM), this study assessed the impacts of bicarbonate and sulfate availability on the establishment of sulfidogenesis in the thermophilic (55 °C) fermentation of vinasse in batch reactors, equally assessing the impacts on biohydrogen evolution. CCRD-RSM results indicated the favoring of biohydrogen production at the lowest sulfate and bicarbonate concentrations, whilst the opposite was observed for sulfidogenesis. Glycerol, lactate, and hydrogen were the preferential electron donors utilized by sulfate-reducing bacteria (SRB), whilst ethanol was markedly consumed only at high sulfate concentrations. SRB were inhibited by sodium when dosing excess NaHCO3 and Na2SO4. Complementary tests revealed maximum biohydrogen production (2.40 mmol) out of the CCRD, at pH exceeding 7.5 with no interference of sulfidogenesis. Non-efficient biohydrogen production was observed at low pH (<5.0; ~1.90 mmol) because the uptake of lactate was inhibited. Meanwhile, homoacetogenesis was established under intermediate pH range (5.5–6.5), as revealed by the accumulation of acetate (up to 2.5 g L?1). 16S rRNA gene amplicon sequencing further revealed the genera Thermoanaerobacterium/Pseudoclostridium, Desulfotomaculum/Desulfohalotomaculum and Sporomusaceae/Moorella as the main biohydrogen-producing, sulfate-removing and biohydrogen-consuming (homoacetogens) microbial groups, respectively. Hence, using a single inoculum source, vinasse may provide a butyrate-rich (along with biohydrogen-rich biogas) or a sulfate-free and acetate-rich fermented effluent, depending mainly on proper pH control. 相似文献
7.
《Ceramics International》2022,48(24):36620-36628
In order to solve the problem of low charging and discharging energy density of dielectric capacitors, the structure design of layered polymer matrix composites is carried out in this paper. Ba0.7Sr0.3TiO3, Ba0.8Sr0.2TiO3 and Ba0.9Sr0.1TiO3 nanoparticles were successfully prepared by the oxalate coprecipitation method. The surface of BaxSr1-xTiO3 was successfully coated with dopamine, which promoted the dispersion of the polymer matrix of the ceramic powder. Monolayer BaxSr1-xTiO3/PVDF composites containing BaxSr1-xTiO3 with different Ba/Sr ratios were successfully prepared by the casting method. Three-layer asymmetric composites with different fillers were successfully prepared by layer-by-layer casting. The phase and microstructure of the as-prepared materials were analyzed by XRD and SEM. The dielectric, electrical conductivity, ferroelectric and energy storage properties of the composites were tested. The effects and laws of the design of the three-layer asymmetric structure on the dielectric properties and energy storage properties of the layered composites are mainly studied. When the structure of the three-layer asymmetric composite is 1-2-3, the breakdown field strength reaches 330 kV/mm, the discharge energy density reaches 8.51 J/cm3, and the charge-discharge efficiency is 67%. This work demonstrates that layered composites with asymmetric properties can facilitate the development of electrical energy storage. 相似文献
8.
三维异质异构集成技术是实现电子信息系统向着微型化、高效能、高整合、低功耗及低成本方向发展的最重要方法,也是决定信息化平台中微电子和微纳系统领域未来发展的一项核心高技术。文章详细介绍了毫米波频段三维异质异构集成技术的优势、近年来的发展趋势以及面临的挑战。利用硅基MEMS 光敏复合薄膜多层布线工艺可实现异质芯片的低损耗互连,同时三维集成高性能封装滤波器、高辐射效率封装天线等无源元件,还能很好地处理布线间的电磁兼容和芯片间的屏蔽问题。最后介绍了一款新型毫米波三维异质异构集成雷达及其在远距离生命体征探测方面的应用。 相似文献
9.
为研制车船等壳体所用的轻质、高强复合板材,选用超高分子量聚乙烯(UHMWPE)短纤维纱,制备成单层经纬为120根/(10 cm)的平纹组织,采用多组经纱持续更替交织层的方法制成2L(1+0)型、4L(2+1)型、6L(3+2)型3种多层角联锁结构织物,采用扦插芯棒、模压成型方法制成菱形蜂窝状的热固性环氧树脂基中空板,并与2块真空吸液法制成的面板组成“三合一”复合板,同时测定了复合板材的结构特征及其平拉、平压和弯曲性能。结果表明:3种类型复合板的密度均远小于水的密度,其中6L(3+2)型最小,为0.48 g/cm3;复合板层数越多,环氧树脂越难渗透尤其是在中空板菱形交叉点处,复合板平拉、平压、抗弯曲强度则呈现递增,制成的6L(3+2)型复合板试样平压强度可达到1.03 MPa。 相似文献
10.
Qing Li Jun Wang Jie Ma Meng Ni Fan Yang Peng Liu Kuo Yang Lee Hsing-I Hsiang Deyuan Shen Dingyuan Tang 《Journal of the American Ceramic Society》2022,105(5):3375-3381
High-efficiency Yb:Y2O3 laser ceramics were fabricated using the vacuum-sintering plus hot isostatic pressing (HIP) without sintering additives. High-purity well-dispersed nanocrystalline Yb:Y2O3 powder was synthesized using a modified co-precipitation method in-house. The green bodies were first vacuum sintered at a temperature as low as 1430°C and then HIPed at 1450°C. Finally, the samples were air annealed at 800°C for 10 h. Although no sintering aids were used, full density of the samples with excellent optical homogeneity and an inline transmission of 80% at 400 nm could be obtained. Moreover, photodarkening phenomenon was not detected in the ceramics. Preliminary laser experiment with the fabricated ceramics in a two-mirror cavity has demonstrated 32 W continuous-wave (CW) output at ∼1077 nm with an optical-to-optical conversion efficiency of 58.2%. To the best of our knowledge, this is so far the highest CW output power and optical-to-optical conversion efficiency achieved with the Yb3+-doped sesquioxide ceramics in a simple two-mirror cavity. 相似文献