基于改进灰狼优化算法的服务功能链映射算法

随着工业互联网、车联网、元宇宙等新型互联网应用的兴起，网络的低时延、可靠性、安全性、确定性等方面的需求正面临严峻挑战。采用网络功能虚拟化技术在虚拟网络部署过程中，存在服务功能链映射效率低与部署资源开销大等问题，联合考虑节点激活成本、实例化开销，以最小化平均部署网络成本为优化目标建立了整数线性规划模型，提出基于改进灰狼优化算法的服务功能链映射（improved grey wolf optimization based service function chain mapping，IMGWO-SFCM）算法。该算法在标准灰狼优化算法基础上添加了基于无环K最短路径（K shortest path，KSP）问题算法的映射方案搜索、映射方案编码以及基于反向学习与非线性收敛改进三大策略，较好地平衡了其全局搜索及局部搜索能力，实现服务功能链映射方案的快速确定。仿真结果显示，该算法在保证更高的服务功能链请求接受率下，相较于对比算法降低了11.86%的平均部署网络成本。     

Adenine-functionalized conjugated polymer as an efficient photocatalyst for hydrogen evolution from water

Conjugated polymers have emerged as a promising class of organic photocatalysts for photocatalytic hydrogen evolution from water splitting due to their adjustable chemical structures and electronic properties. However, developing highly efficient organic polymer photocatalysts with high photocatalytic activity for hydrogen evolution remains a significant challenge. Herein, we present an efficient approach to enhance the photocatalytic performance of linear conjugated polymers by modifying the surface chemistry via introducing a hydrophilic adenine group into the side chain. The adenine unit with five nitrogen atoms could enhance the interaction between the surface of polymer photocatalyst and water molecules through the formation of hydrogen bonding, which improves the hydrophilicity and dispersity of the resulting polymer photocatalyst in the photocatalytic reaction solution. In addition, the strong electron-donating ability of adenine group with plentiful nitrogen atoms could promote the separation of light-induced electrons and holes. As a result, the adenine-functionalized conjugated polymer PF6A-DBTO2 shows a high photocatalytic activity with a hydrogen evolution rate (HER) of 25.21 mmol g^?1 h^?1 under UV-Vis light irradiation, which is much higher than that of its counterpart polymer PF6-DBTO2 without the adenine group (6.53 mmol g^?1 h^?1). More importantly, PF6A-DBTO2 without addition of a Pt co-catalyst also exhibits an impressive HER of 21.93 mmol g^?1 h^?1 under visible light (λ > 420 nm). This work highlights that it is an efficient strategy to improve the photocatalytic activity of conjugated polymer photocatalysts by the modification of surface chemistry.     

Influence of thermal runaway in styrene–acrylonitrile bulk copolymerization revealed by computational fluid dynamics modeling

The computational fluid dynamics (CFD) and kinetic-based moment methods coupled approach is adopted to simulate the bulk copolymerization of styrene–acrylonitrile (SAN) in a stirred tank reactor. Numerical simulations are carried out to investigate the impacts of impeller speed, monomer ratio, initiator ratio, and initial reaction temperature on the copolymerization process and product properties. Particularly, the Chaos theory is selected as a criterion for evaluating the occurrence of the thermal runaway. The Flory's and Stockmayer's distributions are employed to calculate chain length distribution and copolymer composition distribution of copolymer. The simulation results highlight that the appearance of thermal runaway can be postponed by properly increasing the rotation speed, decreasing the initiator loadings, initial acrylonitrile contents and initial reactor temperature. Furthermore, significant differences exist in the product properties that predicted by the ideal and non-ideal models, which demonstrates that the temperature heterogeneity plays a crucial role in SAN copolymerization. This study could offer references for the safe operation and design of polymerization processes.     

草原石林：东北亚早白垩世花岗岩伸展穹隆和岩浆成矿爆发的地质遗迹及其形成过程

东北亚地区至少发育9个大型草原石林,属花岗岩石林的一种,是东北亚早白垩世巨量伸展和第四系冰川、风化作用的共同产物,主要特点是发育密集的近水平节理。本文通过整理岩浆岩专题填图和构造研究发现,这些石林的主体是早白垩世东北亚地区巨量伸展过程中形成众多的不对称花岗岩穹隆或同减薄岩体,岩体边部发育韧性剪切带,核部发布近水平岩浆流动面理,伸展和岩浆多期侵位导致与成矿密切相关的岩浆热液大量上涌,岩体抬升至地表,沿岩浆面理发育密集的近水平节理和部分垂直节理,后期沿这些构造面理发生的物理风化和化学作用(包括风蚀、冰川以及盐风化等)造就了千奇百怪的形态。草原石林是花岗岩地貌中的“另类”,不仅具有指示东北亚地区花岗岩形成时代(早白垩世)的特点,也是寻找晚中生代中国北方大规模成矿的良好标志体,而且风化形成的千姿百态的景色极具观赏价值,可以作为整个蒙古草原地区和大兴安岭南段地区特色的地学科普和生态旅游资源。     

基于信任链的骚扰电话预判技术研究

当前,骚扰电话乱象屡禁不止,严重影响了人民群众的正常生活,甚至威胁到个人财产安全,因此简单有效地识别骚扰电话技术成为亟待解决的问题。区别于现有的对电话号码进行黑白名单标记、大数据分析等识别方法,提出基于信任链的骚扰电话预判技术,从可信度量的角度计算来电号码的可靠程度,并针对高危受害群体的典型应用场景进行分析,通过对骚扰电话的预判,降低其受到电话骚扰甚至电话诈骗的可能性。     

转基因甜菜GTSB77品系特异性实时荧光聚合酶链式反应检测方法建立

目的 为实现转基因甜菜GTSB77的标识管理,建立其品系特异性实时荧光聚合酶链式反应(PCR)检测方法。方法 针对GTSB77的3′端外源插入片段与甜菜基因组DNA之间的邻接区序列设计引物和探针,建立GTSB77品系特异性实时荧光PCR检测方法,并对该方法的特异性、灵敏度和重复性进行检测。结果 建立的GTSB77检测方法特异性强,定量限(LOQ)为16拷贝,扩增效率为102%,重复性测试结果相对标准偏差(RSD)介于0.21%～1.66%之间。结论 建立的实时荧光PCR方法可应用于GTSB77的鉴定检测。     

考虑交叉销售的O2O供应链合作广告策略研究

基于网络零售平台与制造商的合作广告实践，运用Stackelberg博弈理论研究了平台交叉销售效应及合作广告引导作用对O2O供应链合作广告决策的影响，并通过数值算例对参与合作广告计划前后渠道成员的决策变量均衡结果和利润进行对比分析，研究发现平台交叉销售效应是影响网络零售平台合作广告计划制定和实施的关键因素，只有当其达到一定水平时，制造商才拥有参与网络零售平台合作广告计划的资格；在一定条件时，合作广告计划能够实现制造商和网络零售平台利润的提升；当平台交叉销售效应较大时，网络零售平台获得的利润大于制造商。     

歧口凹陷断裂密集带形成演化特征及油气富集差异研究

断裂密集带作为斜向伸展作用的标志性产物,是断块油气藏形成与聚集的主要场所。针对歧口凹陷不同走向断裂密集带油气富集差异较大的问题,通过统计密集带几何学特征及构造组合样式,结合断裂带形成演化规律,分析不同走向断裂带油气富集差异。结果表明:歧口凹陷主要发育NEE、EW向及NNE向3种断裂带。其中,NNE向断裂带形成时期最早,断裂的垂向输导能力最弱,油气在深部富集;NEE向断裂带随后形成,断裂对盖层的破坏作用最强,油气在深、浅层均有分布;EW向断裂带形成时期最晚,断裂的垂向输导能力介于前两者之间。研究成果可为歧口凹陷及相似的多期裂陷盆地断裂密集带的油气勘探工作提供理论支撑。