一种植物油中苯并（a）芘含量测定的固相萃取前处理方法

为了建立一种准确性高、成本低的植物油中苯并(a)芘测定的样品前处理方法，基于GB 5009.7—2016以自制氧化铝柱为固相萃取柱，采用单因素试验对称样量、洗脱剂量、洗脱流速、吸附剂存放时间、吸附剂量这5个影响植物油中苯并（a）芘洗脱的因素进行研究，优化前处理条件，并对测定方法进行考察。结果表明：优化的前处理条件为称样量0.100 0 g、洗脱剂量120 mL、吸附剂（氧化铝）量22 g、洗脱流速1滴/2 s、吸附剂存放时间少于12周；方法检出限为0.2 μg/L，样品加标回收率为94.23%～100.00%，RSD为1.20%～7.36%；同一样品测定结果与SGS测定值接近，相对平均偏差为2.36%～3.50%。说明本试验方法测定结果准确，可应用于油脂企业植物油中痕量苯并（a）芘的测定。     

Electromagnetic transients in the control system of output parameters of a solar power plant in Tajikistan Central Asia region

At present, as the demand for electricity increases in all sectors, there is an urgent need to introduce alternative renewable energy sources into modern energy systems. Renewable energy sources, which consist of solar (photovoltaic, PV), wind and hydro power, are key alternative sources of “green energy’’ energies, but it can also be used to produce “green” hydrogen. Thanks to scientific and technological progress, the cost of photovoltaic solar radiation converters is constantly decreasing at a high rate, which makes it possible to build solar power plants of sufficiently large capacity. In the coming decades, solar energy will become an incentive for the economic development of countries that have the maximum “solar” resource. The Republic of Tajikistan is one of these countries with a high potential for solar energy.The article presents an analysis of the resources and potential of solar energy in the Republic of Tajikistan. The study of electromagnetic transients in networks with photovoltaic solar power plants is performed. The main equations, simulation model and calculations of transients are presented, taking into account changes in voltage on DC buses. An algorithm for controlling the system of automatic control of output parameters is proposed. The analysis of dynamic and static modes in parallel operation of a solar power plant with the grid is carried out. A block diagram and computer model is constructed in the MATLAB package together with Simulink and Power System Blockset.     

Investigation of stress fields for non-standard sized glass plates loaded by ring-on-ring

A ring-on-ring (ROR) test is a prevailing test method for evaluating the equi-biaxial strength of glass materials. However, current ROR test standards limit the strength and size of glass to prevent a nonlinear behavior. In this study, the feasibility of ROR testing for non-standard, high-strength glass, such as tempered or ion-exchanged rectangular glass is investigated. To this end, ROR simulation based on theory and experiment is conducted for thirty non-standard glasses with widths of 100–300 mm and aspect ratios of 1.0–2.0. As a result, the maximum measurable stress was about 215.6 MPa for 100 × 200 mm glass and 481.3 MPa for 300 × 600 mm glass with a 3% deviation, which is well above the strength of regular tempered glass. The main purpose of this work is to understand the range of aspect ratio of horizontal and vertical widths of a glass plate that can be evaluated by the standard ROR test.     

Effect of a sweeping air stream and gas–phase aspect ratio of an isothermal Stefan diffusion column on the experimental estimation of binary gas diffusivities

The Stefan column consists of liquid A evaporating into an inert/stagnant gas B with a sweeping B stream at the top. It was designed to estimate binary gas diffusivities, D_AB’s, but “end effects” such as gas mixing at the top and interfacial curvature have been either ignored or uncorrelated to the operational settings. This study’s hypothesis is that gas mixing at the top and the gas–phase aspect ratio affect D_AB estimation in the acetone (A)-ambient air (B) system at 50?°C. The sweeping stream Reynolds number (Re) and the gas–phase aspect ratio (AR?=?initial gas phase height to column internal diameter) were the variables tested. Isothermal evaporation-diffusion experiments were conducted in which the temporal interfacial descent was tracked. The settings were 492 ≤ Re ≤ 5378 and AR between 5 and 15. A 1D transport model allowed determination of the experimental diffusivity, D_AB,exp, by nonlinear regression. For Re < 600, the D_AB,exp errors relative to D_AB,CE (predicted by the Chapman–Enskog kinetic theory for low-density gases) were small and unrelated to AR, while for Re > 600 the errors increased considerably with Re and were inversely proportional to AR. This study is the first to relate the column’s operational settings to the D_AB estimation errors. The column should be operated at low sweeping gas Re and large AR for accurate D_AB,exp’s. The low Re region deserves further study, while the present transport model may have to be replaced by computational fluid dynamics simulations to account for the multidimensional gas flow patterns.     

Flame characteristics of premixed H2-air mixtures explosion venting in a spherical container through a duct

The explosion venting duct can effectively reduce the hazard degree of a gas explosion and conduct the venting energy to the safe area. To investigate the flame quantitative propagation law of explosion venting with a duct, the effects of hydrogen fraction and explosion venting duct length on jet flame propagation characteristics of premixed H₂-air mixtures were analyzed through experiment and simulation. The experiment results under initial conditions of room temperature and 1 atm show that when hydrogen fraction was high enough, part of the unburned hydrogen was mixed with air again to reach an ignitable concentration, resulting in the secondary combustion was easier produced and the duration of the secondary flame increased. With the increase of venting duct length, the flame front distance and propagation velocity increased. Meanwhile, the spatial distribution of pressure field and temperature field, and the propagation process and mechanism of the flame venting with a duct were analyzed using FLUENT software. The variation of the pressure wave and the pressure reflection oscillation law in the explosion venting duct was captured. Therefore, in the industrial explosion venting design with a duct, the hazard caused by the coupling of venting pressure and venting flame under different fractions should be considered comprehensively.     

Review on development of metal/ceramic interpenetrating phase composites and critical analysis of their properties

Metal/ceramic composites are in high demand in several industries because of their superior thermo-mechanical properties. Among various composite types, the interpenetrating phase composites (IPCs) with percolating metallic and ceramic phases offer manifold benefits, such as a good combination of strength, toughness, and stiffness, very good thermal properties, excellent wear resistance, as well as the flexibility of microstructure and processing route selection, etc. The fabrication of metal/ceramic IPCs typically involves two steps - i) processing of an open porous ceramic body, and ii) infiltration of metallic melt in the pores to fabricate the IPC. Although significant progress has been made in recent years for developing both porous ceramics and melt infiltration methods, to the best of the knowledge of the authors, no review article summarizing all the aspects of processing and properties of IPCs has been published till date. This review article is aimed at filling this gap. Starting with a brief introduction about the current status and applications of IPCs, the various processing routes for fabricating open porous ceramic preforms and melt infiltration techniques have been discussed. Subsequently, the data available for various important physical, mechanical, and thermal properties for IPCs have been critically analyzed to thoroughly understand their dependence on various structural and processing parameters. To compare the properties of IPCs with other relevant materials, seven different Ashby material property maps have been used, and the domains for IPCs have been created in them. For each map, the concept of material indices has been employed to critically discuss how IPCs perform in relation to other material classes for various optimum design conditions. Finally, a detailed future outlook for further research on IPCs has been provided.     

Antibacterial activity of V- doped rod-like MgO crystals decorated with nanoflake layer

In present study, we report a V doping fabrication method for obtaining rod-like MgO crystals decorated with a nanoflake layer. This novel structure has only been minimally reported in literature. Pure MgO and Mg₂V₂O₇–MgO composite materials were obtained by precipitation and impregnation methods, with vanadium added concentrations of 0–9%. The influence of V doping on crystal structure and particle morphology of MgO was investigated by scanning electron microscopy (SEM). X-ray diffraction (XRD) analysis demonstrated that MgO has a cubic structure, while X-ray photoelectron spectroscopy (XPS) revealed that V⁵⁺ exists on the surface of MgO. The specific surface areas and pore sizes of MgO composites were calculated by BET and BJH analysis. These techniques revealed that specific surface area and pore size of MgO increased due to vanadium doping. The antibacterial effects of Mg₂V₂O₇–MgO composite materials against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) were assessed using a bacterial killing/colony-forming unit (CFU) assay and bacteriostatic ring method. Our results demonstrate that V doping dramatically improved antimicrobial properties of MgO, with 7 mol% doping inducing the best antibacterial activity. The antibacterial mechanisms of Mg₂V₂O₇–MgO composite material were also proposed.     

Deposition of UF5 on the surface of steel material having oxide coating in contact with gaseous UF6

When UF6 is handled in leak tight system, the amount of uranium compound formed on the surface of containers, valves, and others in UF6 handling facilities is not so significant for a short term that special attention has not been given to this problem. The present work was done to throw some more light on this problem based on the recent experiment. We discuss the possibility that the intermolecular transfer of a fluorine atom from UF6 to UF5 may participate in the formation of uranium compound. The discussion includes also the unique features contained in the experimental result, the reaction processes assumed in this problem, and the derivation of a rate equation for expressing the deposition of uranium compound. Furthermore, we propose a new method for determining nonlinear parameters included in a governing differential equation having two variables for expressing the deposition of uranium compound from experimental raw data.     

基于组合双向拍卖的云资源调度方法

针对跨数据中心的资源调度问题，提出了一种基于组合双向拍卖（PCDA）的资源调度方案。首先，将云资源拍卖分为三个部分：云用户代理报价、云资源提供商要价、拍卖代理组织拍卖；其次，在定义用户的优先级及任务紧迫度的基础上，在拍卖过程中估算每一个工作发生的服务等级协议（SLA）违规并以此计算云提供商的收益，同时每轮竞拍允许成交多项交易；最终达到根据用户等级合理分配云资源调度的效果。仿真实验结果表明该算法保证了竞拍成功率，与传统一次拍卖成交一项的组合双向拍卖方案相比，PCDA在竞拍时间段产生的能耗降低了35.00%，拍卖云提供商的利润提高了约38.84%。     

爆破荷载作用下新建与既有隧道支护结构

系统研究爆破冲击同时对新建隧道和既有隧道支护结构动力影响具有重要意义。以某隧道接近既有隧道为例，建立爆破施工对既有隧道和新建隧道支护结构的影响三维模型，利用高能炸药材料模型及JWL状态方程来模拟爆破荷载作用下既有隧道的动力响应特性，结合LS-DYNA显式动力分析程序和多物质流固耦合算法较为准确地对新建隧道的爆破机理进行数值模拟，对爆破荷载作用下既有隧道二次衬砌与新建隧道初期支护的动力响应规律展开研究，得到了不同工况下新建隧道二衬和既有隧道初支在不同时刻的振速分布规律、位移变化云图。结果表明：不同围岩等级既有隧道二次衬砌的动力响应规律十分相似，爆破冲击波最先传到既有隧道二次衬砌上迎爆侧边墙上，既有隧道二次衬砌结构上质点沿X方向振速峰值最大，衰减较快。当距离掌子面一定距离后，新建隧道拱脚处振速峰值超过拱顶位置，不同位置振速大小依次是拱脚＞拱顶＞拱腰。初期支护上质点X、Y、Z 3个振动方向中沿Z方向即隧道中心线方向振动较大，衰减较快。炸药起爆后，新建隧道初期支护上不同位置在爆破冲击波的作用下，沿着掌子面往洞口方向依次发生振动，同一断面上，拱顶和拱脚位置振速较大，施工中应加强监测。