受老空水威胁工作面巷道防治水实践

针对高庄煤矿3_上1104回风巷为沿空掘巷,巷道掘进期间受3_上1102老空水威胁,掘进开采存在严重的水患安全问题,采用超前打设疏水孔的方案来治理老空水威胁,对巷道采用调向增大护巷煤柱厚度等措施实现巷道安全快速掘进,探放水期间无淹巷情况发生,探放水后巷道顶板和上帮无淋水现象发生。     

Synthesis of Hollow Three-Dimensional Channels LiNi_(0.5)Mn_(1.5)O_4 Microsphere by PEO Soft Template Assisted with Solvothermal Method

A appropriate size with three-dimension(3 D) channels for lithium diffusion plays an important role in constructing highperforming LiNi_(0.5)Mn_(1.5)O_4(LNMO) cathode materials, as it can not only reduce the transport path of lithium ions and electrons, but also reduce the side effects and withstand the structural strain in the process of repetitive Li~+ intercalation/deintercalation. In this work, an e fficient method for designing the hollow LNMO microsphere with 3 D channels structure by using polyethylene oxide(PEO) as soft template agent assisted solvothermal method is proposed. Experimental results indicate that PEO can make the reagents mingle evenly and nucleate slowly in the solvothermal process, thus obtaining a homogeneous distribution of carbonate precursors. In the final LNMO products, the hollow 3 D channels structure obtained by the decomposition of PEO and carbonate precursor in the calcination can provide abundant electroactive zones and electron/ion transport paths during the charge/discharge process, which benefits to improve the cycling performance and rate capability. The LNMO prepared by adding 1 g PEO possesses the most outstanding electrochemical performance, which presented an excellent discharge capacity of 143.1 mAh g~(-1) at 0.1 C and with a capacity retention of 92.2% after 100 cycles at 1 C. The superior performance attributed to the 3 D channels structure of hollow microspheres, which provide uninterrupted conductive systems and therefore achieve the stable transfer for electron/ion.     

渗流作用下新型装配重力式挡土墙有限元分析

为研究渗流作用下新型装配重力式挡土墙应力变化及墙体排水通道对墙后土体固结的影响,采用ABAQUS进行有限元分析,有限元分析结果与模型试验结果相吻合,证明该模型的合理性。在此基础上研究渗流作用下墙体应力变化趋势及墙体排水通道对墙后土体固结效果的影响。研究结果表明:横向排水通道对墙后土体固结效果的影响优于纵向排水通道对土体固结效果的影响,墙体底部横向排水通道的影响作用最显著;渗流作用下墙体应力由上往下呈先增大后减小的趋势,墙体下部所受最大水平剪应力最大。     

下向瓦斯抽采钻孔自动排水技术研究与应用

为解决下向钻孔由于孔内积水而造成瓦斯抽采效果差的问题，通过时控开关和电磁阀自动控制高压风，在封孔管上增设直达孔底的导风管，利用压风将瓦斯抽采钻孔内积水压入到排渣放水器内，从而能够达到定时清除孔底积水和杂质的目的。该技术应用于上良煤矿石门揭煤下向抽采钻孔，经考察表明下向瓦斯抽采钻孔自动排水技术能有效提高瓦斯抽采效果，该地质单元区域设定为每隔4 h进行一次压风排水效果最佳。     

油砂SAGD水平井钻井液体系

针对SAGD水平井在油砂开发过程中井壁失稳、托压易黏附卡钻及沥青沾染钻具和固控设备等难题，室内通过核心处理剂的优选，研发了一套强抑制高润滑水基钻井液体系。室内性能评价表明，该钻井液抗温180℃，抗沥青20%，抗钻屑25%，岩屑滚动回收率为91.7%，润滑性能与油基钻井液基本相当。强抑制高润滑水基钻井液在麦凯河区块5对（10口） SAGD水平井施工过程中性能稳定易调整，润滑效果突出，机械钻速高，无任何复杂事故。结果表明，强抑制高润滑水基钻井液完全满足浅层油砂SAGD水平井施工工艺的技术需求，具有推广应用价值。      

高抽巷合理层位研究及分期配抽采空区瓦斯技术

针对郭庄煤矿采空区和邻近层瓦斯大量涌入回采工作面造成的上隅角超限频繁的问题，利用顶板裂隙移动规律及岩石物理力学参数，确定了高抽巷的最佳布置层位，经在3316回采工作面试验表明:第2阶段高抽巷小幅度开启抽采瓦斯最大浓度9.4%，瓦斯纯量4.65 m³/min，上隅角瓦斯浓度能控制在0.5%以内；第3阶段高抽巷全面开启抽采瓦斯浓度稳定在3%～4%，高抽巷混合流量225.21 m³/min，纯流量8.11 m³/min，上隅角瓦斯浓度能控制在0.4%以内。高抽巷分段配抽有效保障了工作面回采安全。     

Nanoconfined (Bio)Catalysts as Efficient Glucose‐Responsive Nanoreactors

Herein, the design, synthesis, and characterization of bifunctional hybrid nanoreactors used for concurrent one‐pot chemoenzymatic reactions are shown. In the design, the enzyme, glucose oxidase, is wrapped with a peroxidase‐mimetic catalytic polymer. Hemin, the organic catalyst, is linked to the flexible polymeric scaffold through coordination to the imidazole groups that hang out the network. This spatial arrangement, which works as a metabolic channel, is optimized for cooperative chemoenzymatic reactions in which the enzyme catalyzes first. A deep characterization of the integrated nanoreactors demonstrates that the confinement of two distinct catalytic sites in the nanospace is very effective in one‐pot reactions. Moreover, besides its role as scaffold material, the polymeric mantel protects both the biocatalyst and the chemical catalyst from degradation and inactivation in the presence of organic solvents. Furthermore, the polymeric environment of the nanoreactors can be tailored in order to trigger the assembly of those into highly active heterogeneous hybrid catalysts. Finally, the new nanoreactors are applied to the efficient degradation of organic aromatic compounds using glucose as the only fuel.     

屯宝煤矿I011502综放面瓦斯预抽必要性论证分析

针对高瓦斯矿井部分煤层瓦斯含量总体不高，采用整体预抽瓦斯增加了生产成本，但部分区域可能煤层瓦斯含量高，还需要抽采才能进行采掘等活动。以屯宝煤矿M₁₅煤层I011502综放工作面为例，通过现场测试及分析，对高瓦斯矿井低瓦斯含量煤层工作面采前瓦斯抽采必要性进行了论证。结果表明，I011502综放工作面可以不采取预抽措施，有效缓解了矿井接替紧张问题，同时节约了生产成本。     

采场动压分布特征及高效瓦斯抽放技术研究

河南地区大部分煤矿所采煤层均属于三软煤层，煤层透气性差，瓦斯治理困难。现阶段河南区域煤与瓦斯突出矿井主要采用穿层钻孔及开采保护层作为区域防突措施，而低瓦斯矿井或临突矿井（低瓦斯矿井与煤与瓦斯突出矿井相邻）存在高瓦斯区时，仅仅用风排瓦斯很难达到治理效果，近些年煤矿发生瓦斯事故多数为低瓦斯矿井，所以低瓦斯矿井和临突矿井存在高瓦斯区域的工作面回采期间瓦斯治理尤为重要。根据采场“竖三带”和“横三区”理论，利用钻孔抽放效果考察法和工作突出预测指标法研究了采场围岩动压分布特征。在此基础上，通过优化动压区抽放钻孔设计，提高了瓦斯抽放效果。瓦斯抽放量提高了1.8倍，有效降低了工作面生产期间的风排瓦斯量，提高了生产效率，保证了矿井安全生产。