Studies on high density polyethylene (HDPE) functionalized by ultraviolet irradiation and its application

The structure and properties of high density polyethylene (HDPE) functionalized by ultraviolet irradiation at different light intensities in air were studied by electron analysis, FTIR spectroscopy, contact angle with water, differential scanning calorimetry and mechanical properties measurement. The results show that oxygen‐containing groups such as C?O, C—O and C(?O)O were introduced onto the molecular chain of HDPE following irradiation, and the rate and efficiency of HDPE functionalization increased with enhancement of irradiation intensity. After irradiation, the melting temperature, contact angle with water and notched impact strength of HDPE decreased, the degree of crystallinity increased, and their variation amplitude increased with irradiation intensity. Compared with HDPE, the yield strength of HDPE irradiated at lower light intensity (32 W m^?2 and 45 W m^?2) increases monotonically with irradiation time, and the yield strength of HDPE irradiated at higher light intensity (78 W m^?2) increases up to 48 h and then decreased with further increase in irradiation time. The irradiated HDPE behaved as a compatibilizer in HDPE/polycarbonate (PC) blends, and the interface bonding between HDPE and PC was ameliorated. After adding 20 wt% HDPE irradiated at 78 W m^?2 irradiation intensity for 24 h to HDPE/PC blends, the tensile yield strength and notched Izod impact strength of the blend were increased from 26.3 MPa and 51 J m^?1 to 30.2 MPa and 158 J m^?1, respectively. Copyright © 2003 Society of Chemical Industry     

An Acoustic Converter Used to Measure Ionizing Radiation Energy Loss

A monitor is proposed based on ultrasonic production when ionizing radiation passes through a medium. The recording element is a 0.2 mm aluminum plate mounted in a ceramic acoustic converter AC in the form of a wedge of thickness 2 mm. The low plate thickness minimizes the beam parameter distortion, while special technology used in the AC provides high sensitivity. The device has been calibrated in the proton beam from the ITEP accelerator at 200 MeV with 2·10⁹–6·10¹⁰ particles in a pulse and a pulse length of 70 nsec.     

STRESS INTENSITY FACTORS AND WEIGHT FUNCTIONS FOR SEMI-ELLIPTICAL SURFACE CRACKS IN FINITE-THICKNESS PLATES UNDER TWO-DIMENSIONAL STRESS DISTRIBUTION

Abstract— A Fourier series approach is proposed to calculate stress intensity factors using weight functions for semi-elliptical surface cracks in flat plates subjected to two-dimensional stress distributions. The weight functions were derived from reference stress intensity factors obtained by three-dimensional finite element analyses. The close form weight functions derived are suitable for the calculation of stress intensity factors for semi-elliptical surface cracks in flat plates under two-dimensional stress distributions with the crack aspect ratio in the range of 0.1 ≤ a/c ≤ 1 and relative depth in the range of 0 ≤ a/t ≤ 0.8. Solutions were verified using several two-dimensional non-linear stress distributions; the maximum difference being 6%.     

隔震结构在省防震减灾中心大楼工程中的应用

结合工程实例介绍了隔震结构在工程设计中的应用     

Three dimensional boundary element analysis of internal cracks under sliding contact load with a spherical indenter

Using boundary element based three dimensional modelling for linear fracture mechanics, we present an analysis of cracking in a homogeneous medium subject to contact load. The proposed iterative solution procedure allows a simultaneous treatment of a reasonable number of partially closed cracks. It is shown that the most probable direction of propagation of a vertical internal crack is strongly dependent on its size compared to the contact radius and its location with respect to the axis of maximum normal load.     

Threshold and growth mechanism of fatigue cracks under mode II and III loadings

ABSTRACT The fatigue crack growth behaviour of 0.47% carbon steel was studied under mode II and III loadings. Mode II fatigue crack growth tests were carried out using specially designed double cantilever (DC) type specimens in order to measure the mode II threshold stress intensity factor range, ΔK_IIth. The relationship ΔK_IIth > ΔK_Ith caused crack branching from mode II to I after a crack reached the mode II threshold. Torsion fatigue tests on circumferentially cracked specimens were carried out to study the mechanisms of both mode III crack growth and of the formation of the factory‐roof crack surface morphology. A change in microstructure occurred at a crack tip during crack growth in both mode II and mode III shear cracks. It is presumed that the crack growth mechanisms in mode II and in mode III are essentially the same. Detailed fractographic investigation showed that factory‐roofs were formed by crack branching into mode I. Crack branching started from small semi‐elliptical cracks nucleated by shear at the tip of the original circumferential crack.     

Significance of the elastic peak stress evaluated by FE analyses at the point of singularity of sharp V-notched components

The paper presents an expression useful to estimate the notch stress intensity factor (NSIF) from finite element analyses carried out by using a mesh pattern with a constant element size. The evaluation of the NSIF from a numerical analysis of the local stress field usually requires very refined meshes and then large computational effort. The usefulness of the presented expression is that (i) only the elastic peak stress numerically evaluated at the V‐notch tip is needed and no longer the whole stress–distance set of data; (ii) the adopted meshes are rather coarse if compared to those necessary for the evaluation of the whole local stress field. The proposed expression needs the evaluation of a virtual V‐notch tip radius, i.e. the radius which would produce the same elastic peak stress than that calculated by FEM at the sharp V‐notch tip by means of a given mesh pattern. Once such a radius has been theoretically determined for a given geometry, the expression can be applied in a wide range of notch depths and opening angles.     

Analytical Calculation of Large-Scale Deflection of Pulse-Loaded Elliptic Plates

Large deflections of pulse-loaded elliptic and round plates made of hardenable elastoplastic materials are investigated analytically using an energy-based approach. Formulas that are convenient for engineering design have been derived.     

Design consideration of photocatalytic oxidation reactors using TiO2-coated foam nickels for degrading indoor gaseous formaldehyde

In the design process of the photocatalytic oxidation (PCO) reactor using TiO₂-coated foam nickels, the optimum of catalyst film thickness, light intensity and flow velocity were considered. A model was developed to study the effect of catalyst film thickness on photocatalytic degradation of formaldehyde by a TiO₂-coated foam nickel at continuous flow mode. In this model, external mass transfer and internal molecule diffusion-reaction were considered. A first-order kinetics equation was used to account for the photocatalytic reaction. Two exponential equations were employed to describe the distribution of light intensities in foam nickels and catalyst films, respectively. Validated with experimental data, the model can be used to predict the optimal thickness of catalyst films. A method for determining appropriate light intensities was proposed and discussed. The appropriate light intensity can be obtained by giving a margin, regarded as an excess coefficient, to the light intensity calculated based on the assumption of complete use of excited electron–hole pairs. The excess coefficient needs to be determined experimentally. In addition, the optimal flow velocity of PCO reactors could be consistent with the required one by changing the windward area of foam nickels. Based on the theoretical analyses, a novel PCO reactor containing 15 parallel-connected cells was designed. Each reaction cell was composed of an UV lamp and a TiO₂-coated tubular foam nickel. The performance of the reactor was tested by degrading gaseous formaldehyde at an indoor concentration level. The results showed that the reactor had low pressure loss and good degradation capability.     

Determining stress intensity factors of composites using crack opening displacement

The main purpose of this paper is to find the mixed-mode stress intensity factors of composite materials using the crack opening displacement (COD). First, a series solution of the composite material with a crack was used to evaluate COD values. Then, the least-squares method was used to calculate mixed-mode stress intensity factors. This algorithm can be applied to any method that generates or measures COD values. The major advantage of this method is that COD values very near the crack tip are not necessary. Both finite element simulations and laboratory experiments were applied to validate this least-squares method with acceptable accuracy if the even terms of the series solution are removed.