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1.
《International Journal of Hydrogen Energy》2022,47(67):29172-29183
To improve the safety of wet dust removal systems for processing magnesium-based alloys, a new method is proposed for preventing hydrogen generation. In this paper, hydrogen generation by Mg–Zn alloy dust was inhibited with six common metal corrosion inhibitors. The results showed that sodium dodecylbenzene sulfonate was the best hydrogen inhibitor, while CeCl3 enhanced hydrogen precipitation. The film-forming stability of sodium dodecylbenzene sulfonate was tested with different contents, temperatures, Cl? concentrations and perturbation rates. The results showed that this inhibitor formed stable protective films on the surfaces of Mg–Zn alloy particles, and adsorption followed the Langmuir adsorption model. 相似文献
2.
Xiao-Mei Sha Li-Jun Zhang Wen-Mei Chen Guang-Yao Wang Jin-Lin Li Zi-Zi Hu Zong-Cai Tu 《International Journal of Food Science & Technology》2022,57(3):1573-1586
Thermal action in extraction process had effects on characteristic tryptic peptides identification and gelling properties of porcine gelatin. SDS-PAGE, HPLC-LTQ/Orbitrap high-resolution mass spectrometry, texture analyser and rheometer were used to evaluate collagen depolymerisation degree, characteristic tryptic peptides and gelling properties of gelatins prepared in various thermal actions. Results showed that with increasing temperature and time, depolymerisation degree enlarged, while gel strength, gelling and melting temperature decreased. Mass spectra showed that 47 and 49 common characteristic tryptic peptides were identified in gelatins extracted at 50 °C and 100 °C with various times, respectively. Moreover, 34 common characteristic tryptic peptides were identified in all gelatin samples. Further comparison between this work and our previous investigations yielded 20 common characteristic tryptic peptides, which stably exist in various thermal actions. These common characteristic tryptic peptides may be very helpful for the accurate authentication of porcine gelatin. 相似文献
3.
Najiba Hasan Hamad 《亚洲传热研究》2022,51(5):3794-3814
Classical Fourier's theory is well-known in continuum physics and thermal sciences. However, the primary drawback of this law is that it contradicts the principle of causality. To explore the thermal relaxation time characteristic, Cattaneo–Christov's theory is adopted thermally. In this regard, the features of magnetohydrodynamic (MHD) mixed convective flows of Casson fluids over an impermeable irregular sheet are revealed numerically. In addition, the resulting system of partial differential equations is altered via practical transformations into nonlinear ordinary differential equations. An advanced numerical algorithm is developed in this respect to get higher approximations for temperature and velocity fields, as well as their corresponding wall gradients. For validating our numerical code, the current outcomes are compared with the available literature results. Moreover, it is revealed that the velocity field is more prominent in the suction flow situation as compared with the injection flow case. It is also found that the Casson fluid is hastened in the case of lower yield stress. Larger values of thermal relaxation parameters create a lessening trend in the temperature distribution and its related boundary layer breadth. 相似文献
4.
An analysis has been carried out to examine the heat and mass transfer properties of a two-dimensional incompressible electrically conducting Maxwell fluid over a stretching sheet in the existence of Soret, Dufour, and nanoparticles. In many practical scenarios, such as the polymer extrusion process, the problem presented here is crucial. The flow is examined in terms of the impacts of magnetohydrodynamics and elasticity. Brownian motion and thermophoresis are incorporated into the transport equations. Using adequate similarity variables, the governing partial differential equations and related boundary conditions are non-dimensionalized. The fourth–fifth-order Runge–Kutta–Fehlberg procedure is utilized to solve the consequent transformed ordinary differential equations. The effects of various embedded thermo-physical parameters on the fluid velocity, temperature, concentration, Nusselt number, and Sherwood number have been determined and discussed quantitatively. A comparison of a special case of our results with the one previously reported in the literature shows a very good agreement. An increase in the values of Du and Sr leads to an increase in the temperature and concentration distribution. Nusselt number estimates decrease as Nb estimations increase. Furthermore, this study leads to the study of different flows of electrically conducting fluid over a stretching sheet problem that includes the two-dimensional nonlinear boundary equations. 相似文献
5.
Liu Yang Pengfei Yu Wenyuan Li Fengliang Cao Xin Jin Sheng Xue Xianglong Zhang Tingwei Zhang Mingbo Wu Wenting Wu 《American Institute of Chemical Engineers》2022,68(9):e17760
Hydrogen peroxide (H2O2) has been listed as one of the 100 most important chemicals in the world. However, huge amount of residual H2O2 is hard to timely decomposed into O2 and H2O under acidic condition, easily resulting in explosion hazard. Here, we reported a core–shell structure catalyst, that is graphene with Co N structure encapsulated Co nanoparticles. Co N graphene shell serves as the active site for the H2O2 decomposition, and Co core further enhance this decomposition. Benefiting from it, the H2O2 decomposition were close to 100% after 6 cycles without pH adjustment, which increased 6 orders of magnitude compared with no catalyst. At the same time, the O2 generation reached 99.67% in 2 h with little metal leaching, and ·OH has been greatly inhibited to only 0.08%. This work can cleanly remove H2O2 with little deep oxidation and protect the process of H2O2 utilization to achieve a safer world. 相似文献
6.
Sk Tanbir Islam Sudip K. Samanta Santanu Das Himadri Chattopadhyay 《Journal of the American Ceramic Society》2022,105(7):4608-4620
The micro-powder injection molding (micro-PIM) process has the potential to bridge the gap between the design and manufacturing of micro-components that are often used in small and handy devices. Numerical modeling helps to analyze and overcome various difficulties of micro-PIM. In the present work, a numerical model is developed to predict the powder–binder separation (a common defect in PIM and especially severe in micro-PIM) during the injection of an alumina feedstock. A powder–binder separation criterion is proposed dealing with applied injection pressure and friction force between the powder and binder. An indirect comparison of feedstock travel time between two locations is used to validate the model. The predicted segregation from the simulated result is supported by a qualitative experimental measurement. The developed model can be used to optimize injection parameters to get a defect-free product. 相似文献
7.
《Ceramics International》2022,48(20):29862-29872
Thermal shock parameters (R, R''', R'''' and Rst) of MgAlON–MgO composites obtained with additions of spent MgO–C brick were calculated using measured mechanical properties and thermal expansion coefficient, determining their resistance to fracture initiation and crack propagation. The cyclic thermal shock experiments of MgAlON–MgO composites performed from 1398 K to ambient temperature indicate that as number of thermal shock cycle increases, retained strength ratio of MgAlON and MgAlON–4.2 wt%MgO sharply decrease and then keep constant, while that of MgAlON–10.5 wt%MgO and MgAlON–15.7 wt%MgO slowly decrease. The reason for the difference is that MgAlON and MgAlON–4.2 wt%MgO show low value of R''' and R'''', and high value of R and Rst. Moreover, precipitation of impurity containing Fe may play a positive role in improvement of thermal shock resistance of MgAlON–MgO composites. MgAlON?4.2 wt%MgO has the maximum retained strength (55 MPa) even after 5 thermal shock cycles, which is expected to be used in the metallurgical industry. 相似文献
8.
The thermodynamics modeling of a Reiner–Philippoff-type fluid is essential because it is a complex fluid with three distinct probable modifications. This fluid model can be modified to describe a shear-thinning, Newtonian, or shear-thickening fluid under varied viscoelastic conditions. This study constructs a mathematical model that describes a boundary layer flow of a Reiner–Philippoff fluid with nonlinear radiative heat flux and temperature- and concentration-induced buoyancy force. The dynamical model follows the usual conservation laws and is reduced through a nonsimilar group of transformations. The resulting equations are solved using a spectral-based local linearization method, and the accuracy of the numerical results is validated through the grid dependence and convergence tests. Detailed analyses of the effects of specific thermophysical parameters are presented through tables and graphs. The study reveals, among other results, that the buoyancy force, solute and thermal expansion coefficients, and thermal radiation increase the overall wall drag, heat, and mass fluxes. Furthermore, the study shows that amplifying the space and temperature-dependent heat source parameters allows fluid particles to lose their cohesive force and, consequently, maximize flow and heat transfer. 相似文献
9.
《Ceramics International》2022,48(11):15268-15273
SiC/SiC mini-composites reinforced with SiC fibers coated with different numbers of ZrSiO4 sublayers prepared via a non-hydrolytic sol-gel process were fabricated. The tensile strength and work of fracture of the prepared SiC/SiC mini-composites were determined, and the relationship between their mechanical properties and fracture morphologies was discussed. The toughening mechanism and the variation tendency of their mechanical properties were further elaborated by analyzing the interfacial debonding morphologies of the SiC/SiC mini-composites with 1 and 4 layers of ZrSiO4 interphase as well as the results of prior studies. A relatively rare phenomenon—the delamination of the multilayer ZrSiO4 interphase in the SiC/SiC mini-composites but not on the SiC fibers—was observed, which clearly demonstrated the weak bonding between the ZrSiO4 sublayers in the SiC/SiC mini-composites. The ZrSiO4 sublayer delamination mechanism was then explained based on the high-magnification morphologies found in and beside the ZrSiO4 interphase. 相似文献
10.
Joint photographic experts group (JPEG) can provide good quality with small file size but also eliminate extensively the redundancies of images. Therefore, hiding data into JPEG images in terms of maintaining high visual quality at small file sizes has been a great challenge for researchers. In this paper, an adaptive reversible data hiding method for JPEG images containing multiple two-dimensional (2D) histograms is proposed. Adaptability is mainly reflected in three aspects. The first one is to preferentially select sharper histograms for data embedding after histograms are established by constructing the th () histogram using the th non-zero alternating current (AC) coefficient of all the quantized discrete cosine transform blocks. On the other hand, to fully exploit the strong correlation between coefficients of one histogram, the smoothness of each coefficient is estimated by a block smoothness estimator so that a sharply-distributed 2D-histogram is constructed by combining two coefficients with similar smoothness into a pair. The pair corresponding to low complexity is selected priorly for data embedding, leading to high embedding performance while maintaining low file size. Besides, we design multiple embedding strategies to adaptively select the embedding strategy for each 2D histogram. Experimental results demonstrate that the proposed method can achieve higher rate–distortion performance which maintaining lower file storage space, compared with previous studies. 相似文献