高深溜井井筒堵塞的爆破处理实践

溜井是采用平硐-溜井方式开拓矿山的运输咽喉,溜井正常与否对矿山生产影响极大。本文通过黑沟铁矿高深溜井井筒堵塞处理实例,对其堵塞爆破处理方法及经验做了系统分析。重点介绍的爆破冲击波破拱疏通高深溜井井筒高位堵塞的爆破方法,富有新意,可供国内外同类型矿山参考借鉴。     

Microbial fuel cell (MFC)-based biosensor for combined heavy metals monitoring and associated bioelectrochemical process

To explore the feasibility and related mechanism of MFC biosensor for wastewater detection under the action of combined heavy metals. Cyclic voltammetry (CV) and scanning electrochemical impedance spectroscopy (EIS) were used to explore the related bioelectrochemical process. The response of the reactor to single/combined heavy metals, low/high heavy metal concentrations, and the differences in ohmic resistance (Rs) and charge transfer resistance (Rct) were investigated using Ni as the core heavy metal and the combined action of Cd, Cu and Zn. The results indicated that there was a linear relationship between the concentration and output voltage of the MFC biosensor under the action of combined heavy metals (R² = 0.8803–0.973). However, the internal resistance (Rint) of the MFC biosensor under the action of single heavy metal was far less than that of the combined heavy metal group, and the power density (19.849 W m^?3) was 4 times that of the combined heavy metal group (3.109–4.589 W m^?3). The Rs of the biosensors in the combined heavy metal group were 0.868Ω and 0.860, which were higher than 0.768Ω of the single heavy metal sensor. With the increase of the concentration of heavy metals in the influent, the increase of Rct was more obvious in the combined group, while the Rs in the single group significantly increased (P < 0.05). The results imply that it is possible for MFC biosensors to be used in the detection of actual water polluted by various heavy metals, but the biosensor performance is mainly limited by Rct, which needs to be further improved.     

塔里木盆地塔西南坳陷柯东构造带甫沙4井原油来源及充注过程

甫沙4井位于塔里木盆地塔西南坳陷昆仑山前冲断带的柯东构造带上，北部和东部分别发育有柯克亚和柯东1井油气田。为研究甫沙4井原油来源与充注过程，对原油样品和连续抽提后的含油砂样各组分（游离态、束缚态、包裹体）进行GC、GC?MS和 GC?IRMS分析，与柯克亚凝析油气田油样进行油—油对比。结果表明：甫沙4井晚期充注原油组分具有C_29?32重排藿烷、重排甾烷和Ts相对含量高，C_27?29甾烷ααα 20R分布呈反“L”型，以及正构烷烃单体碳同位素值较低等特征，与柯克亚凝析油气田来源于二叠系普司格组（P_2?3p）烃源岩的主体原油（I类）地球化学特征一致。而早期充注的原油组分具有重排藿烷、重排甾烷和Ts相对含量较低，C_27?29甾烷ααα 20R分布呈“V”型，以及正构烷烃单体碳同位素值较高等特征，与柯克亚凝析油气田来源于中—下侏罗统湖相泥岩的II类原油地球化学特征一致。甫沙4井经历3个阶段成藏过程：①在上新世，二叠系烃源岩于生油晚期阶段生成的I类原油运移至柯克亚构造带或柯东构造带深部形成油藏；②在更新世早期，侏罗系烃源岩于生油早—中期生成的II类原油运移至甫沙4井白垩系储层；③在第四纪，强烈的构造作用使深部I类原油沿断裂调整进入甫沙4井白垩系储层。最终造成甫沙4井白垩系储层II类原油先充注，I类原油后充注的特殊现象。     

“半翻转”教学模式下评价指标体系研究与实践

研究基于“半翻转”教学模式的线上教学评价指标体系,包括课前活动开展、课中教学活动设计、课后任务以及基于此过程中的评价指标体系设计。最后通过层次分析法设计评价指标权重,设计评价算法得到动态评价结果。该评价指标体系应用在本专业“数据结构与算法”课程中,并得到良好的应用效果。     

Effect of organic solvent on the cold sintering processing of SrFe12O19 platelet-based permanent magnets

In this work we have investigated the effect of the solvent during the processing of SrFe₁₂O₁₉ platelet-based permanent magnets by cold sintering process (CSP) plus a post-thermal treatment. Several organic solvents: glacial acetic acid, oleic acid and oleylamine have been analyzed, optimizing the CSP temperatures at 190?270 °C, under pressures of 375?670 MPa and 6?50 wt% of solvent. Modifications in the morphological and structural properties are identified depending on the solvent, which impacts on the magnetic response. Independently of the solvent, the mechanical integrity of ferrite magnets obtained by CSP is improved by a post-annealing at 1100 °C for 2 h, resulting in relative densities around 92 % with an average grain size of 1 μm and a fraction of SrFe₁₂O₁₉ phase >91 %. H_C ≥ 2.1 kOe and M_S of 73 emu/g are obtained in the final sintered ceramic magnets, exhibiting the highest H_C value of 2.8 kOe for the magnet sintered using glacial acetic acid.     

红心火龙果发酵液喷雾干燥工艺优化及红心火龙果籽油的研究

以红心火龙果发酵液作为研究对象,通过优化喷雾干燥工艺制备粉剂,最佳工艺条件为:20%麦芽糊精,进液量:10mL/min,进口温度为120℃,出口温度为65℃;得到的粉剂为紫红色粉末,益生菌含量达到108cfu/g以上,口感酸甜。将发酵后的火龙果籽进行提取,得到的火龙果籽油含有丰富的十六酸、亚油酸和油酸。     

Effect of ultrasonic waveforms on gas–liquid mass transfer in microreactors

This study aims to investigate the effect of ultrasonic waveforms on the gas–liquid mass transfer process. For a given load power (P), continuous rectangular wave yielded stronger bubble oscillation and higher mass transfer coefficient (k_La) than continuous triangular and sinusoidal wave. For pulsed ultrasound, the k_La decreased monotonically with decreasing duty ratio (D), resulting in weak enhancement at low D (≤33%). For a given average load power (P_A), concentrating the P for a shorter period resulted in a higher k_La due to stronger cavitation behavior. For a given P_A and D, decreasing the pulse period (T) led to an increase in k_La, which reached a constant high level when the T fell below a critical value. By optimizing the D and T, a k_La equivalent to 92% of that under continuous ultrasound was obtained under pulsed ultrasound at a D of 67%, saving 33% in power consumption.     

Investigation of corrosion properties with Ni–P/TiNO coating on aluminum alloy bipolar plates in proton exchange membrane fuel cell

Aluminum alloy bipolar plates have unique application potential in proton exchange membrane fuel cell (PEMFC) due to the characteristics of lightweight and low cost. However, extreme susceptibility to corrosion in PEMFC operation condition limits the application. To promote the corrosion resistance of aluminum alloy bipolar plates, a Ni–P/TiNO coating was prepared by electroless plating and closed field unbalanced magnetron sputter ion plating (CFUMSIP) technology on the 6061 Al substrate. The research results show that Ni–P interlayer improves the deposition effect of TiNO outer layer and increase the content of TiN and TiO_xN_y phases. Compared to Ni–P and TiNO single-layer coatings, the Ni–P/TiNO coating samples exhibited the lowest current density value of (1.10 ± 0.02) × 10^?6 A·cm^?2 in simulated PEMFC cathode environment. Additionally, potential cyclic polarization measurements were carried out aiming to evaluate the durability of the aluminum alloy bipolar plate during the PEMFC start-up/shut-up process. The results illustrate that the Ni–P/TiNO coating samples exhibit excellent stability and corrosion resistance.     

Influence of density on the post-suffusion behavior of gap-graded sand with fines

Suffusion erosion, characterized as the selective detachment and transportation of finer particles by seepage flow, is hazardous to the stability and serviceability of geotechnical structures. The removal of finer particles deteriorates the structure and fabric of the soil, leading to the degradation of its mechanical properties. Studies into the effects of suffusion on mechanical behavior have so far produced disparate results depending on the pre-erosion relative density of the specimens tested. To investigate this issue, small cyclic and monotonic loading tests were performed on intact and eroded gap-graded silty sand specimens in three dispersed density states, using a triaxial cell modified for the purpose of erosion. The variation of Young's modulus showed an inverse relationship with the pre-erosion density of the specimen, as the small strain stiffness decreased in the dense cases and increased in the loose cases. Conversely, Poisson's ratio increased in value as suffusion progressed regardless of the initial density of the specimens. In the contractive phase of monotonic loading, the densification of the coarse soil skeleton by the downward seepage flow resulted in a decrease in contractiveness and an increase in secant stiffness. In the dilative phase, the increase in porosity by the erosion of finer particles reduced the dilatancy and peak strength of the specimens. The results suggest that the pre-suffusion density determines the primary locus of affected mechanical behavior in triaxial compression, which shifts from the contractive phase to the dilative phase with the increase in pre-suffusion density. The critical state strength, inferred using stress–dilatancy theory, was largely unaffected by the erosion of finer particles. As the results indicate, pre-erosion density may be of practical significance in assessing the vulnerability to deterioration and collapse of geotechnical formations and structures subjected to suffusion erosion.     

Post-erosion mechanical responses of internally unstable gap-graded soil under drained torsional simple shear and triaxial compression

Internal erosion is a major threat to hydraulic earth structures, such as river levees and dams. This paper focuses on suffusion and suffosion phenomena which are caused by the movement of fine particles in the granular skeleton due to seepage flow. The present study investigates the impact of internal erosion on the dynamic response under cyclic torsional shear and monotonic responses under triaxial compression and torsional simple shear. A series of experiments, using a gap-graded silica mixture with a fines content of 20%, is performed under loose, medium, and dense conditions using a novel erosion hollow cylindrical torsional shear apparatus. The erosion test results indicate that the critical hydraulic gradient and the rate of erosion are density-dependent, where a transition from suffosion to suffusion is observed as the seepage continues. Regardless of the sample density, variations in the radial strain and particle size distribution, along the specimen height after erosion, are no longer uniform. Furthermore, the dynamic shearing results show that the small-strain shear modulus increases, but the initial damping ratio decreases after internal erosion, probably due to the removal of free fines. In addition, the elastic threshold strain and reference shear strain values are found to be higher for the eroded and non-eroded specimens, respectively. Finally, based on drained monotonic loading, the post-erosion peak stress ratio increases remarkably under triaxial compression, while that under torsional simple shear depends on the relative density where the direction of loading is normal to the direction of seepage. These observations indicate that the horizontal bedding plane becomes weaker, while the vertical one becomes stronger after downward erosion.