MAH接枝EPDM增韧PA66的研究

研究了MAH(马来酸酐)接枝三元乙丙橡胶(EPDM—g-MAH)对尼龙66(PA66)的增韧作用。利用SEM(扫描电镜)观察了共混体系的微观形貌(形态结构)，并运用小角激光散射(SALS)方法研究了EPDM的加入对PA66结晶性能的影响。结果表明，未接枝的EPDM与PA66的相容性很差，而EPDM—g—MAH与PA66相容性明显增加，EPDM-g—MAH粒子均匀分散在PA66中，共混体系力学性能有很大提高。随着EPDM—g—MAH用量的增加，PA66球晶尺寸变小，共混体系界面结合更加紧密。     

三元乙丙橡胶/蒙脱土纳米复合材料的制备方法与应用前景

橡胶／蒙脱土纳米复合材料的优异性能使其成为橡胶工业中富有潜力的一类新型材料。笔者综述了三元乙丙橡胶(EPDM)／蒙脱土纳米复合材料的制备方法、性能和工业应用领域等，讨论了蒙脱土片层的表面修饰、插层剂的选择以及复合材料的制备方法对材料性能的影响，并提出了三元乙丙橡胶／蒙脱土纳米复合材料这一新型橡胶材料在轮胎工业上的应用前景。     

三元乙丙橡胶/聚丙烯热塑性硫化胶细观力学数值模拟分析Ⅱ.三元乙丙橡胶结构对细观力学性能的影响

通过建立三元乙丙橡胶(EPDM)/聚丙烯(PP)热塑性硫化胶(TPV)的细观尺寸多颗粒随机分布的RVE模型,研究了分散相EPDM粒子形状及大小、间距对TPV应力和弹性模量的影响。结果表明,在分散相EPDM体积分数不变的条件下,EPDM粒子形状越接近圆形,TPV的应力值越低,EPDM粒径的减小可提高TPV的弹性模量;EPDM粒子间距增大,TPV的应力值下降,TPV中EPDM体积分数越高,其应力值受EPDM粒子间距的影响越显著。     

三元乙丙橡胶共混改性的研究进展

综述了三元乙丙橡胶(EPDM)与其他橡胶共混及无机纳米粒子改性EPDM的研究进展,通过共混使EPDM共混胶兼具不同橡胶的特性,如优良的物理机械性能、黏合性、耐热老化性能、耐化学药品、介电性能及加工性能等;通过改性,可使EPDM纳米复合材料不仅具有优异的综合性能,还具有相对密度小、高充油、高填充性以及与多种高聚物良好的相容性。     

EPDM／St-AN相反转乳液接枝共聚合及AES的结构与性能

以过氧化二苯甲酰为引发剂,正庚烷为溶剂,用"相反转"乳液共聚合法合成了三元乙丙橡胶和苯乙烯-丙烯腈(St-AN)的接枝共聚物(EPDM-g-SAN),并与苯乙烯-丙烯腈共聚物(SAN)熔融共混(共混物简称 AES)。研究了丙烯腈 AN 在共单体中的含量和 EPDM/St-AN 的质量比对单体转化率、接枝率和接枝效率的影响。冲击实验表明,AN 含量为35%～40%时,接枝率约为35%,所制备的 EPDM-g-SAN 对 SAN 树脂有显著的增韧作用,增韧后所制得的工程塑料 AES 的悬臂梁缺口冲击强度最高可达50.7 kJ/m~2;差示扫描量热分析表明 AES 存在界面相;动态热力学分析表明 EPDM-g-SAN 与 SAN 树脂之间的相界面结合紧密;透射电镜和扫描电镜分析表明,AN 在共单体中的含量为35%时,EPDM-g-SAN 在 SAN 树脂基体中有良好的分散性,相界面模糊,因而两相结合紧密,其增韧机理以空穴化为主兼有剪切屈服。     

Dynamically Vulcanized EPDM/PP (40/60) Blends

Dynamically vulcanized thermoplastic elastomer (TPE) blends were first described by Fisher. In the 1960s, the usage of TPE was low. However, the consumption of TPE is increasing today. Due to hard and soft polymer phases in its structure, TPE replaced a lot of materials. TPE materials are preferred today due to their good thermal properties, oxidation resistance, transparency, adhesion, compatibility with other polymers etc. As a result of the studies that were done in 1975, TPV—vulcanized thermoplastic elastomers were developed. In this study, TPV elastomers were produced by forming crosslinks with peroxide from different ratios, of EPDM and PP. Mixing was done with twin screw extruder. After that yield and tensile strength, the modulus of elasticity, % elongation, Izod impact strength, hardness, Melt Flow Index (MFI), Vicat Softening Point, Heat Deflection Temperature (HDT), and density of crosslinks were determined. Thermal transition temperatures and microstructure were determined with DSC and SEM, respectively.     

The surface energy as an indicator of miscibility of SAN/EDPM polymer blends

Surface properties of blends prepared of styrene-acrylonitrile and ethylene-propylene-diene changing the homopolymer proportions and compatibilized by high impact polystyrene have been studied by contact angle measurement. The surface free energy of interphase of homopolymers pairs, work of adhesion, and wetting coefficient were calculated using Wu’s geometric mean method and the total surface free energy and acid–base components of the blends by using van Oss, Good and Chaudhury method. Blends were also characterized by dynamic mechanical analysis and by scanning electron microscopy. The miscibility of studied blends was estimated through changes of surface free energy, energy of interface and through the shifts of glass transition temperature and changes in morphology. From the results, it can be seen that added compatibilizer reduces the interface energy and provides more homogenous system by interfacial segregation and rearrangements of molecules at the blend surface. The results of morphological observations reveal that the addition of a small percentage of compatibilizer decreases the domain size of the dispersed phase and enhances the compatibility of the blends.     

钛酸铜钙-氮化硼掺杂EPDM复合介质的电学和力学性能研究

非线性电导材料的应用是解决高压直流电缆附件内部电场集中问题的一种有效方案.因此,通过掺杂钛酸铜钙(calcium copper titanate,CCTO)纳米填料对三元乙丙橡胶(ethylene-propylene-diene monomer,EPDM)进行改性,在较低的掺杂体积分数(2％CCTO)下,复合介质展现出...     

EPDM/ENR宽温域阻尼材料的制备及阻尼机理

采用饱和非极性三元乙丙橡胶(EPDM)和不饱和强极性环氧化天然橡胶ENR-50制备出EPDM/ENR-50二元共混阻尼材料。利用扫描电镜/X射线能谱分析、原子力显微镜分析表明,该共混体系拓宽阻尼温域的机理在于两相中硫化剂的迁移,即共混硫化交联过程中,饱和非极性的EPDM相中的硫化剂向极性不饱和的ENR-50相迁移,导致二元共混物中ENR-50交联密度比其单独硫化时高,阻尼内耗峰向高温方向外扩,而EPDM相的交联密度比单独硫化时低,阻尼内耗峰向低温方向外扩,最终得到了温度范围从-72.3℃到52.9℃(tanδ0.13)的宽温域阻尼材料。为了改进二元共混橡胶的阻尼性能和力学性能,进一步制备了EPDM/ENR-50/氯丁橡胶(CR)三元共混阻尼材料,所得三元共混胶的有效阻尼(tanδ0.3)温域范围超过120℃,同时材料具有良好的力学性能。