首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   24943篇
  免费   2024篇
  国内免费   686篇
电工技术   646篇
综合类   1394篇
化学工业   12121篇
金属工艺   312篇
机械仪表   382篇
建筑科学   1359篇
矿业工程   205篇
能源动力   2804篇
轻工业   2288篇
水利工程   159篇
石油天然气   1610篇
武器工业   21篇
无线电   312篇
一般工业技术   2729篇
冶金工业   484篇
原子能技术   173篇
自动化技术   654篇
  2024年   92篇
  2023年   418篇
  2022年   809篇
  2021年   946篇
  2020年   857篇
  2019年   746篇
  2018年   553篇
  2017年   694篇
  2016年   657篇
  2015年   698篇
  2014年   1360篇
  2013年   1361篇
  2012年   1935篇
  2011年   1882篇
  2010年   1501篇
  2009年   1354篇
  2008年   1177篇
  2007年   1556篇
  2006年   1332篇
  2005年   1226篇
  2004年   1104篇
  2003年   986篇
  2002年   738篇
  2001年   634篇
  2000年   592篇
  1999年   497篇
  1998年   410篇
  1997年   313篇
  1996年   251篇
  1995年   199篇
  1994年   187篇
  1993年   157篇
  1992年   118篇
  1991年   88篇
  1990年   54篇
  1989年   34篇
  1988年   32篇
  1987年   20篇
  1986年   15篇
  1985年   12篇
  1984年   9篇
  1983年   4篇
  1982年   11篇
  1981年   1篇
  1980年   8篇
  1979年   1篇
  1977年   1篇
  1976年   1篇
  1951年   22篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Evaluation of kinetic distribution and behaviors of nanoparticles in vivo provides crucial clues into their roles in living organisms. Extracellular vesicles are evolutionary conserved nanoparticles, known to play important biological functions in intercellular, inter‐species, and inter‐kingdom communication. In this study, the first kinetic analysis of the biodistribution of outer membrane vesicles (OMVs)—bacterial extracellular vesicles—with immune‐modulatory functions is performed. OMVs, injected intraperitoneally, spread to the whole mouse body and accumulate in the liver, lung, spleen, and kidney within 3 h of administration. As an early systemic inflammation response, increased levels of TNF‐α and IL‐6 are observed in serum and bronchoalveolar lavage fluid. In addition, the number of leukocytes and platelets in the blood is decreased. OMVs and cytokine concentrations, as well as body temperature are gradually decreased 6 h after OMV injection, in concomitance with the formation of eye exudates, and of an increase in ICAM‐1 levels in the lung. Following OMV elimination, most of the inflammatory signs are reverted, 12 h post‐injection. However, leukocytes in bronchoalveolar lavage fluid are increased as a late reaction. Taken together, these results suggest that OMVs are effective mediators of long distance communication in vivo.  相似文献   
2.
Control of reactive distillation production of high-purity isopropanol   总被引:2,自引:0,他引:2  
The process characteristics and control strategy of a high-purity IPA reactive distillation column were investigated. A robust nominal operation was found by maintaining an excess of propylene feed to the column and recycling the unreacted propylene to the feed instead of the top stage. Stage temperature and propylene composition with one-to-one relationship with reboiler duty and propylene feed are selected as controlled variables for maintaining bottom purity and feed ratio in the presence of possible measurement bias respectively. High nonlinearity between selected input–output pair was reduced by using variable transformation. Dynamic simulations demonstrated that such a control scheme with nonlinear transformed variable was capable of providing much superior control performance than the one using natural variable.  相似文献   
3.
基于进化算法的常减压装置模拟   总被引:1,自引:0,他引:1  
提出了基于优选优生进化算法(Select—best and prepotency evolution algorithm,SPEA)的常减压装置模拟方法。以各塔的温度分布为目标,基于生产过程和分析数据,采用SPEA确定各塔板Murphree效率,从而精确描述各塔板平衡偏离程度。在实际应用中,获得具有良好精度的常减压装置模型。系统分析了SPEA算法的关键参数——优选领域大小与计算复杂性及寻优性能之间的关系,结果显示其取值为群体规模的10%最为合适。  相似文献   
4.
The application of ion exchange membranes as solid polymer electrolytes (SPE) in fuel cells is state-of-the-art. This technology needs no supporting electrolyte; consequently it can be applied for electro-organic syntheses in order to save process steps. In this case the process is not predetermined to a maximized energy efficiency so that the selection of the cell design, of the electrode materials and of the operating conditions can be focused on a high selectivity of the electrode reactions. The electro-osmotic stream, which is caused by the solvation shells of the ions during their migration through the membrane, and hence is a typical property of SPE technology, has a significant effect on the electrode reactions. It generates enhanced mass transfer at the electrodes, which is beneficial for reaction selectivity. It can be influenced by the choice of, and possibly by the preparation of, the membrane. An additional remarkable advantage of SPE technology is the exceptional long durability of oxide coated electrodes. By combination of several process engineering methods stable operation of SPE cells has been realized, even for examples of non-aqueous reaction systems. Experiments up to 6000 h duration and in cells of up to 250 cm2 membrane area show the potential for industrial application.  相似文献   
5.
A batch reactor may be combined directly with a distillation column by distilling off the light component product in order to increase the reactor temperature or to improve the product yield of an equilibrium reaction. The same amount of the light product should be removed as the amount being formed by the reaction at any time. A linearized model has been developed which describes the process behaviour satisfactorily for control analysis purposes. The controllability of a combined batch reactor/batch distillation column is found to depend strongly on the operating conditions and on the time during the run. In general, controlling only the reactor temperature (one-point bottom control) is difficult since the set-point has to be specified below a maximum value in order to avoid break-through of an intermediate component in the ditillate. This maximum value may be difficult to know a priori. For the example considered in this study, control of both reactor temperature and distillate composition (two-point control) is also found to be difficult due to large interactions in the column. As with one-point bottom control, the reactor temperature has to be specified below a maximum value. However, energy can be saved since the heat duty can be decreased with time. Controlling the temperature on a tray in the column (one-point column control) is found to give good performance for the given process with no loss of reactant and a high reactor temperature, although no direct control of the reactor temperature is obtained.  相似文献   
6.
CA/PAN中空纤维血浆分离膜的结构与性能   总被引:4,自引:2,他引:2  
本研究以CA及PAN的共混溶液,通过干-湿法纺丝制取中空纤维,利用共混高聚物各组分在凝固剂中相分离速度的差异,形成具有稳定结构的中空纤维孔膜,该膜用于分离血液中的血浆成分具有良好效果。讨论了成型条件及添加剂等对膜结构、性能的影响,用SEM及图相分析仪、MAP压汞仪及DSC等分析手段,对膜的微孔结构、形态、孔尺寸及中空纤维膜的血浆通量和水通量等进行了系统的考查。  相似文献   
7.
软X射线不仅能引起红细胞表面电荷的变化,同时也能导致淋巴细胞和血小板表面电荷下降,表现为照射后它们的电泳率下降。低剂量范围内,这种电荷的变化是暂时性的,照后4小时降到最低点,24小时后恢复到对照的水平。细胞电泳率的下降与辐射剂量相关。淋巴细胞是一个复杂的细胞群,正常状态下,按细胞在电场中泳动速度的快慢,可分为两个组分:快峰为T细胞,慢峰为B细胞。软X射线照射以后,T和B细胞的电泳率皆减慢,频数分布峰值下降,离散度加大。血小板成分单一,电泳率较一致。 从照射浓集的血小板再加回自身血浆中电泳率的下降较照射血浆再加到血小板中的电泳率下降大得多;受照射的血小板在磷酸缓冲液中电泳率下降较在血浆悬液中严重得多;2000 rad照后,悬浮于血浆中的血小板电泳率能恢复,而悬浮于磷酸缓冲液中则不能恢复,三个方面来看,血浆中可能存在抗辐射因子。超氧化物岐化酶能有效地预防血小板电泳率的下降,从而可阻止血小板的凝聚。  相似文献   
8.
Emig  G.  Liauw  M.A. 《Topics in Catalysis》2002,21(1-3):11-24
In order to enhance product yields in selective oxidation reactions, numerous reaction engineering concepts are being studied worldwide. Periodic operation has been investigated for decades, yet its application is limited to a few examples, such as the butane oxidation after DuPont or reverse-flow reactors for VOC removal. The use of microchannel reactors is a younger field, but it has already yielded promising results for process optimization. Catalytic wall reactors have proved to be a helpful tool for kinetic studies. On the laboratory scale, membrane reactors have displayed favorable behavior in selective oxidation. The Na vapor-catalyzed dehydrogenation of methanol to formaldehyde is a final example of an unusual new concept for selective oxidation.  相似文献   
9.
10.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号