Catalytic behavior in CH4 decomposition of catalysts derived from red mud: Impact of residual Na2O

Catalyst samples for CH₄ decomposition were prepared from red mud (RM) by an acid-leaching neutralization precipitation approach. Water-washing the resultant precipitates multiple times, followed by drying at 105 °C and calcination at 500 °C, resulted in a threshold of residual Na₂O, equivalent to 96% Na₂O removal. Drying the precipitate at a higher temperature of 200 °C, followed by repeated water washing, provided a deeper Na₂O removal of 99% and made the resultant samples more active for the targeted reaction. Subsequently, four catalyst samples with a simulated red mud composition and NaOH contents from 0 to 0.3 wt% were prepared and the catalytic test results revealed that the Na₂O remaining in the RM-derived catalysts did not only inhibit their activation in CH₄ but also lower their maximal activities for CH₄ decomposition. Finally, two catalysts with the same simulated red mud composition and their Na impregnated respectively on Fe₂O₃ and a mixture support of Al₂O₃-SiO₂-TiO₂ were prepared and tested to explore the effect of Na distribution on the activation behavior of RM-derived catalysts for CH₄ decomposition. The activity testing results showed that it was the Na residual dispersed on iron oxides in the RM-derived samples to significantly inhibit the activation of CH₄ decomposition.     

减水剂类型对赤泥—矿渣基地聚物注浆材料性能的影响及机理研究

针对赤泥等固体废弃物对环境危害性大且利用率低等问题,以碱激发赤泥-矿渣基地聚物注浆材料为 研究对象,研究了不同掺量的聚羧酸(PA)减水剂、醛酮缩合物(AKC)减水剂和萘系(N)减水剂对材料凝结时间、流动 性及强度等的影响,并通过 XRD、傅里叶红外光谱及 SEM 等设备对减水剂的作用机理进行研究。 结果表明:减水剂增 强了材料的流动性但降低了材料的剪切应力;N 和 PA 减水剂能缩短材料的凝结时间,但 AKC 减水剂会延长材料的凝 结时间;N 和 AKC 减水剂能提高材料的强度,但 PA 减水剂会降低材料的强度;N 减水剂对材料的综合性能提升效果 更加明显,其最优掺量为 0. 7%;减水剂对赤泥-矿渣基地聚物性能提升的作用机理主要是促进地聚合物凝胶的形成。 研究成果为拓展赤泥在工程上的使用途径和效率提供了理论指导。     

深孔爆破成井技术在三道庄钼矿的试验与应用研究

洛钼集团矿山公司三道庄矿区由于历史原因,露天开采境界地下内存在的采空区已危及矿山公司的正常安全生产,阻碍了洛钼集团可持续发展。为解决这一重大问题,经过充分调研和多方论证,认为深孔一次爆破成井技术是解决此类采空区难题唯一的经济上合理、技术可行、安全可靠的手段与途径。深孔爆破成井实现与采空区顶板的贯通,使采空区边岩稳定,顶岩暴露面积缩小,确保了采空区的稳定;保证了台阶正常推进。     

电气化铁路既有线深路堑扩堑石方控制爆破

介绍电气化铁路既有线无隔墙台阶爆破扩堑方法。沿既有线方向设置低台阶 ,边界处布置光爆孔 ,采用“同列同段和列间微差”的起爆网路。采用自制的“炮被”和架设“钢管排架”阻挡飞石、滚石和滑石 ,确保了既有线的安全。文中还概述了“炮被”和“钢管排架”的制做以及作者的认识和体会。     

破损水文观测孔涌水封堵技术在高河矿的应用

针对高河矿奥灰水文观测孔空水管锈蚀断裂漏水严重的问题,分析了存在的问题,制定了钻孔涌水封堵技术方案及相应的注浆施工工艺,并进行了为期7天的井下试验。封堵注浆压力达到6 MPa,使用注浆水泥50 t,水泥浆液凝固良好,注浆阀门打开后无出水现象。     

大断面切眼支护技术研究与实践

针对古城煤矿S1303综采工作面切眼的地质构造与施工条件,提出了大断面切眼采用“锚网索+π型梁棚+预注浆”联合支护方案,有效地控制了大断面切眼留顶煤施工期间的支护难题,保障了S1303综采面切眼能够满足设计要求和如期完成施工,为同类条件下的切眼施工提供了一定参考。     

Stress-deformable state of isotropic double curved shell with internal cracks and a circular hole

This work is devoted to the stress–strain state of isotropic double curved shell with defect system. The construction is weakened by two non-through thickness (internal) cracks of different length and by a circular hole located between cracks. In this study we use the line-spring model. Within the framework of this model cracks are modeled as mathematical cuts of shell’s middle surface. This leads to a two-dimensional problem. The problem is reduced to a system of eight boundary integral equations. To ensure the uniqueness of solution an additional equation is added. In the numerical solution of the problem special quadrature formulas for singular integrals of Cauchy type and the finite difference method are applied. The influence of defects on each other for double curved shell has been investigated. The given theoretical results can be used for the calculation of structural elements with holes, cracks on the strength and fracture toughness in various branches of engineering.     

转底炉处理赤泥工艺技术

为了综合利用氧化铝冶炼产生的赤泥，探索在转底炉中直接还原赤泥、磨矿磁选获得高品位直接还原铁。通过实验室试验摸索了转底炉还原工艺参数，并在转底炉工业试验线进行了工业试验。实验室结果表明，赤泥还原后的直接还原铁(DRI)金属化率可达88.6%，磁选后的铁品位可达82.1%，磁选后的铁回收率可达88.9%。工业试验中，转底炉还原后，产品金属化率平均为69.2%，将还原后的DRI磁选获得高品位的DRI产品，磁选后DRI的铁品位为72.8%，磁选后铁回收率达到了85.2%,初步打通了在转底炉中还原赤泥、磁选的工艺路径。     

机加工孔套管抗挤压强度有限元分析

套管屈服强度直接影响套管抗挤压性能，套管在加工孔过程中可能诱发孔眼附近材料发生金属相变，导致套管屈服强度不再均匀分布，进而影响套管抗挤压强度。在相同工况下，对比了P110完整套管和机加工孔套管的抗挤压强度，以此为参照组分析了相变区域面积和相变区域屈服强度对机加工孔套管抗挤压强度的影响。结果表明，机加工孔会改变材料屈服强度，进而影响套管抗挤压性能。随金属相变区域屈服强度减小，机加工孔套管抗挤压强度减弱；当金属相变区域屈服强度增大时，机加工孔套管抗挤压强度增强。且机加工孔套管相变区域面积对机加工孔套管抗挤压强度的影响随相变区域屈服强度增加而逐渐削弱。     

Anchoring single Pt atoms on hollow Ag3VO4 spheres for improved activity towards photocatalytic H2 evolution reaction

The high cost of noble metal catalysts has been a great bottleneck for the catalyst industry. Using the noble metal at a single-atom level for catalytic applications could dramatically decrease the cost. The impacts of single Pt atoms on the photocatalytic performance of Ag₃VO₄ have been investigated and reported. In this report, single Pt atoms were anchored on the surface of Ag₃VO₄ (AVO) as a cocatalyst, and the resultant composite photocatalyst has been studied for photocatalytic H₂ production from water driven by visible light. The as-prepared AVO particles are hollow nanospheres in the monoclinic phase with a bandgap of 2.20 eV. The light absorption edge of AVO/Pt is slightly red-shifted compared to that of the pristine AVO, indicating more visible light absorption of AVO/Pt. The XPS peaks of Ag, V, and Pt exhibit a significant shift after AVO and Pt get into contact, suggesting the strong interaction between the surface Ag and V atoms, and single Pt atoms. After 3-h illumination, the photocatalytic H₂ evolution amount from AVO/Pt is improved up to 1400 μmol, which is 2.8 times that on the bare AVO. Such efficient photocatalytic H₂ evolution on AVO/Pt is still maintained after five reaction cycles. The better photocatalytic performance of AVO/Pt has been attributed to the more efficient visible light utilization and the lower interfacial charge transfer resistance, as demonstrated in the DRS and EIS spectra. The presence of the surface Pt atoms also leads to a higher amount of reactive radicals, which could efficiently promote the surface redox reactions.