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1.
基于密度泛函理论(DFT)第一性原理方法,研究了Si、Ni、Mn、Cr、Mo在fcc-Fe/NbX (X=C, N)界面的偏析行为,并分析了合金元素偏析对界面体系的影响。结果表明,fcc-Fe/NbN界面结合强度相较于fcc-Fe/NbC界面结合强度略有提升;Si稳定存在于Fe基体中,Ni、Mn在界面有轻微偏析倾向,Cr、Mo在界面和NbX (X=C,N)内均存在偏析,其中,Mo向界面偏析倾向更大;Cr、Mo偏析在fcc-Fe/NbC界面一定程度上降低了界面的结合能力,但体系稳定性有所提升,Cr、Mo偏析在fcc-Fe/NbN界面一定程度上提高了界面的结合能力,但Mo使得体系稳定性下降。  相似文献   
2.
The process of blending powders using stirring blades involves complicated granular flows, particle-scale mechanisms, and blade–particle interactions, which is challenging to predict and control. This article proposes a continuum-based model for such a process by incorporating the flow rheology, isotropic particle diffusion and the percolation of granular materials. A method combining finite element method (FEM), finite difference method (FDM), and immersed boundary method (IBM) is developed to numerically implement the continuum model and applied to a cylindrical blade mixer. The model well describes the tempo-spatial distribution of small/large particles in the stirring process, such as the accumulation of small particles in the vicinity of blades. Remarkably, this model can capture the various intricate effects of blade parameters, including the blade rake angle, rotating speeds, filling level, and the friction coefficient of the mixer wall. It is therefore promising for optimizing the blade mixers in industries.  相似文献   
3.
针对冷轧高强HC250IF带钢冲压分层问题,通过化学成分分析、显微组织观察及能谱分析等手段,明确了铸坯中心P偏析是导致成品带钢冲压分层的根本原因。为此,采取钢水过热度20~30 ℃稳定浇注、提高连铸二冷水冷却强度、投用电磁搅拌、凝固末端精准定位、增加动态轻压下量等措施,有效改善了铸坯中心P偏析,杜绝了冷轧高强HC250IF带钢冲压分层问题。  相似文献   
4.
Dense high-entropy (Hf,Zr,Ti,Ta,Nb)B2 ceramics with Nb contents ranging from 0 to 20 at% were produced by a two-step spark plasma sintering process. X-ray diffraction indicated that a single-phase with hexagonal structure was detected in the composition without Nb. In contrast, two phases with the same hexagonal structure, but slightly different lattice parameters were present in compositions containing Nb. The addition of Nb resulted in the presence of a Nb-rich second phase and the amount of the second phase increased as the Nb content increased. The relative densities were all >99.5 %, but decreased from ~100 % to ~99.5 % as the Nb content increased from 0 to 20 at%. The average grain size decreased from 13.9 ± 5.5 μm for the composition without Nb additions to 5.2 ± 2.0 μm for the composition containing 20 at% Nb. The reduction of grain size with increasing Nb content was due to the suppression of grain growth by the Nb-rich second phase. The addition of Nb increased Young’s modulus and Vickers hardness, but decreased shear modulus. While some Nb dissolved into the main phase, a Nb-rich second phase was formed in all Nb-containing compositions.  相似文献   
5.
Multifluid model (MFM) simulations have been carried out on liquid–solid fluidized beds (LSFB) consisting of binary and higher-order polydisperse particle mixtures. The role of particle–particle interactions was found to be as crucial as the drag force under laminar and homogenous LSFB flow regimes. The commonly used particle–particle closure models are designed for turbulent and heterogeneous gas–solid flow regimes and thus exhibit limited to no success when implemented for LSFB operating under laminar and homogenous conditions. A need is perceived to carry out direct numerical simulations of liquid–solid flows and extract data from them to develop rational closure terms to account for the physics of LSFB. Finally, a recommendation flow regime map signifying the performance of the MFM has been proposed. This map will act as a potential guideline to identify whether or not the bed expansion characteristics of a given polydisperse LSFB can be correctly simulated using MFM closures tested.  相似文献   
6.
一批风电齿轮箱中42CrMo4钢一级行星架调质后机加工过程中发现内孔开裂。从成分偏析分析、淬火工艺验证、机加工表面磁粉探伤检测、金相分析等方面,对一级行星架进行了分析。结果表明,淬火冷却过于激烈是导致开裂的直接原因,严重的成分偏析是导致淬火开裂的主要原因。  相似文献   
7.
8.
对粮食入仓自动分级问题进行研究,理论上分析了矩形筒仓装粮过程中产生自动分级现象的主要原因。并采用离散单元法的PFC~(3D)程序建立实际仓体的缩尺模型,通过设置不同的颗粒模拟粮食入仓自动分级的过程,在颗粒流动的动态过程中观察分级形成。在仓内装料完成并达到静力平衡后显示颗粒分级状态,.在仓内设置测量圈,分别监测圈内满仓时和删除完整颗粒时的两种孔隙率,计算出所有测量圈中破碎颗粒的含有率,得到分级情况的定量描述。  相似文献   
9.
李高盛  余伟  蔡庆伍 《轧钢》2018,35(4):12-16
由于对高性能钢的需求越来越广,进而对其连铸坯的质量要求不断提高,而铸坯中又以疏松缺陷最难消除。因此,对表面950℃、中心1 300℃以上的差温条件下的铸锭进行预压下试验,在铸锭大变形量部分,由于芯部处于高温奥氏体脆性区,塑性较差从而出现热裂;而小变形量部分,在差温作用下,铸锭内部优先变形,疏松和微观空洞被明显压合,又由于一定范围内的再结晶,减轻了铸锭内部的晶界偏析。试验结果表明,小变形量的差温预压下技术可以显著提高铸坯质量,具有进一步研究和在连铸坯生产中应用的重要价值。  相似文献   
10.
In 1941, the Baltimore City Council passed a law, the Ordinance on the Hygiene of Housing, declaring that all property in the city should be ‘maintained in good repair by the owner or agent, and fit for human habitation’. The campaign of housing-code enforcement that followed, known as the Baltimore Plan, made the city famous. When historians write about American housing-reform efforts during the mid-20th century, they tend to focus on big-ticket federal policies; by contrast, the Baltimore Plan seems too small to be significant. But it is more than a curiosity. First in Baltimore and then across the country, the neat cause-and-effect it posited between good stewardship and good housing crowded out more challenging ways of thinking about the problem. Eventually, the Baltimore Plan turned into a policy tool that reinforced the interests of the real estate industry at the expense of poor people. In that regard, the Baltimore Plan laid the foundations for federal disinvestment in the provision of decent housing and the midcentury tragedy of urban renewal.  相似文献   
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