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At present, the synthesis of body temperature triggering shape memory polymers usually requires elaborate structural design, which limits their wide application. Herein, starting from bio-based Eucommia ulmoides gum (EUG), a series of EUG/silica hybrids (ESHs) are prepared through a facile one-pot process, in which EUG is epoxied and then self-crosslinked with SiO2 by epoxy ring-open reaction. Varying the amount of H2O2, the shape memory transition temperature (Ttrans) of ESHs is adjusted to 47.4–36.6 ℃, which is close to human body temperature (37 ℃). Among them, ESH-17 exhibited the best body temperature triggering shape memory ability (Ttrans = 36.6 ℃), which can restore the permanent shape within 60 s at 37 ℃ with a shape fixity ratio of 99% and shape recovery ratio near 100%. In addition, the shape memory mechanism is discussed and shows some application scenarios of ESHs. The as-produced materials can be used as smart biomaterials such as self-tightening sutures, self-sealing root canal filling materials, and so on. 相似文献
3.
Nianxiu Duan Junjun Li Sha Song Feng Wang Yiwei Yang Di Nie Caifen Wang Yingjie Sheng Yali Tao Jie Gao Can Xu Yan Wei Yong Gan 《Advanced functional materials》2021,31(46):2100605
Tumor-specific enhanced delivery of chemotherapeutics and modulators to tumor cells and activated pancreatic stellate cells (aPSCs), respectively, represents safer and more effective therapy for pancreatic cancer. Herein, a membrane type 1-matrix metalloproteinase (MT1-MMP)-cleavable spacer is used to assemble low-density cRGDfK onto thermosensitive liposomes loaded with phosphorylated calcipotriol (PCAL) and doxorubicin (DOX), yielding MR-T-PD. The liposome-linked cRGDfK prodrug on MR-T-PD surface is first activated by MT1-MMP, which is selectively expressed on tumor endothelial cells, to release cRGDfK. The free cRGDfK specifically promotes tumor angiogenesis, leading to 3.4-fold higher accumulation and a wider distribution of MR-T-PD in tumors. Furthermore, MR-T-PD rapidly releases PCAL and DOX into the interstitium under heat treatment. The released DOX enters tumor cells to induce apoptosis, whereas the PCAL prodrug is converted to CAL by alkaline phosphatase on the surface of aPSCs; CAL can then enter aPSCs to induce quiescence and promote the antitumor effect of DOX. Finally, by enhancing the exposure of DOX and CAL to tumor cells and aPSCs, respectively, in a tumor-specific manner, MR-T-PD exerts superior efficacy (a 5.9-fold decrease in tumor weight) without causing additional side effects. Overall, this prodrug-based smart liposome system represents a promising paradigm for pancreatic cancer therapy. 相似文献
4.
Yan He Kangren Kong Zhengxi Guo Weifeng Fang Zaiqiang Ma Haihua Pan Ruikang Tang Zhaoming Liu 《Advanced functional materials》2021,31(26):2101291
Sensitivity and multi-directional motivation are major two factors for developing optimized humidity-response materials, which are promising for sensing, energy production, etc. Organic functional groups are commonly used as the water sensitive units through hydrogen bond interactions with water molecules in actuators. The multi-coordination ability of inorganic ions implies that the inorganic ionic compounds are potentially superior water sensitive units. However, the particle forms of inorganic ionic compounds produced by classical nucleation limit the number of exposed ions to interact with water. Recent progress on the inorganic ionic oligomers has broken through the limitation of classical nucleation, and realized the molecular-scaled incorporation of inorganic ionic compounds into an organic matrix. Here, the incorporation of hydrophilic calcium carbonate ionic oligomers into hydrophobic poly(vinylidene fluoride) (PVDF) is demonstrated. The ultra-small calcium carbonate oligomers within a PVDF film endow it with an ultra-sensitive, reversible, and bidirectional response. The motivation ability is superior to other bidirectional humidity-actuators at present, which realizes self-motivation on an ice surface, converting the chemical potential energy of the humidity gradient from ice to kinetic energy. 相似文献
5.
Manik Chandra Biswas Samit Chakraborty Abhishek Bhattacharjee Zaheeruddin Mohammed 《Advanced functional materials》2021,31(19):2100257
Shape memory materials (SMMs) in 3D printing (3DP) technology garnered much attention due to their ability to respond to external stimuli, which direct this technology toward an emerging area of research, “4D printing (4DP) technology.” In contrast to classical 3D printed objects, the fourth dimension, time, allows printed objects to undergo significant changes in shape, size, or color when subjected to external stimuli. Highly precise and calibrated 4D materials, which can perform together to achieve robust 4D objects, are in great demand in various fields such as military applications, space suits, robotic systems, apparel, healthcare, sports, etc. This review, for the first time, to the best of the authors’ knowledge, focuses on recent advances in SMMs (e.g., polymers, metals, etc.) based wearable smart textiles and fashion goods. This review integrates the basic overview of 3DP technology, fabrication methods, the transition of 3DP to 4DP, the chemistry behind the fundamental working principles of 4D printed objects, materials selection for smart textiles and fashion goods. The central part summarizes the effect of major external stimuli on 4D textile materials followed by the major applications. Lastly, prospects and challenges are discussed, so that future researchers can continue the progress of this technology. 相似文献
6.
为探索镁合金整体壁板压弯成形的可行性,以及镁合金壁板压弯成形过程中金属的流动规律,对AZ31镁合金网格壁板压弯成形进行了数值模拟和实验研究。建立了有限元数值模拟的几何模型,采用有限元计算软件对AZ31镁合金网格壁板压弯成形过程进行了数值模拟研究,分析了镁合金网格壁板压弯成形中的温度场、应变场、应力场、破坏系数等的分布规律。确定了合适的AZ31镁合金壁板压弯成形工艺参数,并对镁合金网格壁板压弯成形进行了实验研究,获得了合格的镁合金网格壁板弯曲件,并分析了镁合金网格壁板成形件尺寸精度,模拟结果与实验结果相吻合,最大相对误差为16.7%。 相似文献
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8.
With the development of 5G, big data, cloud computing, IOT, mobile Internet and other information technologies of new
generation, the design of forestry information system establishes a new mode of forestry development integrating three-dimensional
perception, collaborative management and internal and external services by means of perception, IOT and intelligence. Intelligent
forestry system is a comprehensive information management system integrating forest management, intelligent forestry business
management, green maintenance management and emergency command and dispatching management. Based on the specific project
practice, this paper puts forward the overall framework design scheme and management platform design scheme of intelligent forest-
ry. 相似文献
9.
冀东马头营地区馆陶组低幅度构造具有很大的油气勘探潜力。该区地表结构复杂、断层发育,一直受深度域速度模型精度限制,低幅度构造圈闭难以识别。为此,提出一套新的综合速度建模方案:首先,考虑断层的影响,在时间偏移域建立准确的层位解释模型,采用基于地质层位解释的横向速度建模方法,有效消除断层导致的横向速度剧烈变化带来的影响;其次,考虑在叠前深度域偏移中浅层速度模型的误差累积会影响深层目的层成像质量,浅层采用回转波层析成像反演出精确的近地表速度场,中深层采用反射波层析成像速度建模,二者结合获得融合速度场;最后,在融合速度场基础上,采用以地质层位为约束、基于模型的高精度网格层析进行速度优化,提高速度模型精度。应用上述方案建立的高精度层速度模型,明显提高了冀东马头营低幅度构造的成像精度及与钻井资料的吻合度,该建模方案可为相似地质条件下低幅度构造成像提供借鉴。 相似文献
10.
随着云计算、物联网、大数据、人工智能等技术的发展,智慧应急救援已成为矿山安全生产监察的迫切需求。提出了基于云平台的矿井水害智慧应急救援服务体系,采用混合云架构,提供按需和弹性计算能力及存储资源。通过集成与挖掘所有可能的历史和实时数据,建立云环境下多源异构、大规模、跨领域、动态信息资源"一张图",推动信息资源共享,建设应急救援智库。在此基础上,研发了应急救援系统,实现数值模拟、预测预警、应急疏散、应急评估、人员设备管理等功能,支持矿山应急演练和应急决策,依托现代信息技术为矿井水害应急救援提供智能化的服务和管理,实现矿井水害事故预防、检测、预警、处置、评估等全过程动态管理和控制。 相似文献