[学科发展]机构学中机构重构的理论难点与研究进展——变胞机构演变内涵、分岔机理、设计综合及其应用

生产力发展与工程技术革新要求机构具备可自重组与可重构及“一机多用”的功能，以满足复杂工况需求。可重构机构具有可变活动度和可变构态，可以满足多任务、多工况与多功能的要求，然而，决定其设计方法的演变内涵与分岔机理的研究目前仍不为学者们充分了解。从变胞机构的演变与分岔机理的角度，以旋量理论、李群与李代数及微分流形为主要工具，揭示了机构演变内涵及运动与约束空间的内在关联关系；探究了机构演变中的分岔机理与可控奇异位形，回顾了变胞机构与折纸及折展机构的历史渊源，综述了变胞机构的构型设计、性能综合与新型设计理念及其创新应用。     

Comprehensive analysis on anomalous phenomenon of ethanol-soluble poly(vinyl butyral) membrane for ethanol recovery via pervaporation

Poly(vinyl butyral) (PVB) is selected as a promising ethanol-permselective membrane based on the solubility parameter theory; however, it exhibits anomalous water perm-selectivity in practical pervaporation (PV) process. Comprehensive analysis based on experimental and theoretical methods were carried out to explore the inherent mechanism of the anomalous performance. Firstly, sum frequency generation vibrational spectra and contact angle were developed to quantify the surface reconstruction of membrane in air and ethanol, which indicated that hydrophilic hydroxyl tended to expose on membrane surface with ethanol thus improving the membrane affinity to water. Meanwhile, swelling behaviors proved more water would accumulate in the ethanol swollen membrane. Furthermore, theoretical analysis in terms of sorption and diffusion process, based on the UNIFAC-FV model and Fujita free-volume theory, confirmed the mechanism of anomalous phenomenon of PVB membrane. The comprehensive investigation was expected to provide insights into the basic separation mechanism of PV process.     

Simulation of temperature and reaction time prediction of the torrefaction process: case of hard-wood biomass

Direct utilisation of biomass for energy application is less profound due to the problems of low calorific value, high water content, and low grindability of biomass. For this reason, pre-heating treatment, sometimes called torrefaction, is necessary to improve the physical properties of biomass similar to ‘coal-like’ material. Unfortunately, only few comprehensive but simple theoretical models focused on hard-wood biomass were available to describe the torrefaction process. In this discussion, a simple proposed torrefaction model was developed and reported. The model has ability to estimate the yield of product mass and energy after the torrefaction process and determine the optimum conditions.     

某铁矿隔水护顶矿柱厚度计算及安全影响预测

科学合理地确定矿山隔水护顶矿柱安全厚度是矿山安全生产的前提条件，为保障某铁矿地表民房、道路等建（构）筑物安全，防止矿山开采过程中产生的导水裂隙带贯通第四系含水层，采用荷载传递交汇线法、K.B.鲁别涅依他估算法和冒落带、导水裂隙带高度估算法3种理论分析方法对隔水护顶矿柱厚度进行计算，并利用数值模拟手段对留设隔水护顶矿柱后的开采过程安全影响进行了分析，对理论计算结果进行了验证。3种理论计算方法得出的隔水护顶矿柱厚度分别为14.3～17.3 m、17.5～31.4 m和41.8～57.4 m，推荐隔水护顶矿柱留设厚度为60 m。通过数值模拟分析得出，在留设60 m厚的隔水护顶矿柱的基础上，开采区域和隔水护顶矿柱位置产生的最大拉应力约0.47 MPa，矿山开采不会对隔水护顶矿柱造成破坏；地表产生的最大水平位移约5.8 cm，最大垂直位移约26.5 cm，最大倾斜为1.70 mm/m，最大曲率为0.20 mm/m2，最大水平变形值为0.70 mm/m，满足相关规范要求，预测矿山开采不会造成地表建（构）筑物破坏。     

壮族布傣族群女子“长袍黑衣”服饰的艺术特征

布傣族群是古骆越人的后裔,属于壮族的一个支系,是中国与越南的跨境民族。“长袍黑衣”是布傣族群女子演奏天琴时所穿着的服饰,地域性特色鲜明,与其他壮族支系有较大的区别;服饰款式与制作工艺独特,具有较强的民族文化内涵和较高的艺术审美价值。通过实地考察调研后,解析了“长袍黑衣”服饰的款式特点及形成原因,阐释了布傣族群的服饰文化。在全球化语境下,如何挖掘布傣族群服饰的特色与价值,传承、弘扬民族文化,有待关注与更深入的探讨。     

综采工作面巷道内瓦斯分布规律研究

为了研究综采工作面巷道内瓦斯运移规律，摸清瓦斯流动的状态，采用理论分析、数值模拟和现场试验相结合的方法，理论分析得到了工作面风流特性及瓦斯运移规律，数值模拟得到了瓦斯异常释放后工作面瓦斯浓度分布变化情况及工作面正常工作瓦斯浓度分布，然后进行现场试验，试验结果和数值模拟结果相似。研究为工作面瓦斯治理提供了技术支持。     

Excited States and Photodebromination of Selected Polybrominated Diphenyl Ethers: Computational and Quantitative Structure—Property Relationship Studies

This paper presents a density functional theory (DFT)/time-dependent DFT (TD-DFT) study on the lowest lying singlet and triplet excited states of 20 selected polybrominateddiphenyl ether (PBDE) congeners, with the solvation effect included in the calculations using the polarized continuum model (PCM). The results obtained showed that for most of the brominated diphenyl ether (BDE) congeners, the lowest singlet excited state was initiated by the electron transfer from HOMO to LUMO, involving a π–σ* excitation. In triplet excited states, structure of the BDE congeners differed notably from that of the BDE ground states with one of the specific C–Br bonds bending off the aromatic plane. In addition, the partial least squares regression (PLSR), principal component analysis-multiple linear regression analysis (PCA-MLR), and back propagation artificial neural network (BP-ANN) approaches were employed for a quantitative structure-property relationship (QSPR) study. Based on the previously reported kinetic data for the debromination by ultraviolet (UV) and sunlight, obtained QSPR models exhibited a reasonable evaluation of the photodebromination reactivity even when the BDE congeners had same degree of bromination, albeit different patterns of bromination.     

金属薄板平面铣削形变分析与控制

由于初始残余应力的作用,金属薄板平面加工普遍存在加工难度大,加工变形严重等问题,难以保证板面的加工质量。以不锈钢薄板的平面加工为基础,通过理论分析、仿真模拟和实验验证的方式,对金属薄板的加工形变进行较为系统的研究,分析了金属薄板加工形变的关键因素,总结了金属薄板残余应力分布形式以及有效避免加工形变的工艺方法,为类似金属板材加工提供理论参考依据。     

打印层厚度对FDM薄板固有特性的影响

针对不同打印层厚度对熔融沉积成型(fused deposition modeling,简称FDM)薄板固有特性的影响规律及相应的机理进行了研究。首先,以悬臂边界条件下的FDM薄板为研究对象,创建了固有特性理论模型;其次,完成了薄板样件的制备,同时搭建了样件的动力学测试系统,实验研究了样件的固有特性参数;最后,对比分析理论与实验结果,以验证理论模型的正确性。研究结果表明,所建模型可以准确预测FDM薄板结构的固有特征参数;打印层越厚,样件的固有频率越高,但其模态振型不会随着打印层厚度的变化而变化。该研究为提高FDM产品动力学性能提供了理论基础和技术支持。     

基于保水采煤理念的地质环境承载力研究

我国西部生态脆弱区采煤引起的水资源破坏和地质环境变化,已经严重制约了矿区经济、社会、环境的可持续发展。通过梳理保水采煤、煤矿区地质环境承载力的研究进展,结合目前西部富煤缺水地区的地质环境现状,提出了基于保水采煤理念的地质环境承载力内涵及基本研究思路。分析认为:基于保水采煤理念的地质环境承载力研究,应将保水采煤理念与地质环境承载力理论有机融合,系统分析"采煤活动—水资源破坏—地质环境效应"作用机理,从寻求煤炭开采、水资源保护、地表生态环境保护3者之间的最优解中阐述内涵。地质环境承载力评价方法研究,可采用属性分析、生态需求分析、数值分析、突变理论等方法,重点研究评价指标的量化方法、综合评价方法、承载能力及承载状态等级划分方法。对于承载能力的计算,可采用模拟实验,取得典型煤矿区承载能力下地质环境与开采强度临界值的关系数据,进而提取出控制和减轻煤矿区地质环境问题的保水采煤技术方法,确定合理的开采强度和规模。在承载力评价和计算的基础上,提出地质环境承载力影响因素的协同监测技术方法,并给出了承载力预警等级判定标准。所提出的基于保水采煤理念的地质环境承载力内涵及基本研究思路,以期丰富和发展保水采煤及地质环境承载力的科学内涵,为西部生态环境脆弱区煤炭资源开发与水资源保护协调发展提供理论与技术支持。