全文获取类型
收费全文 | 11489篇 |
免费 | 1109篇 |
国内免费 | 706篇 |
专业分类
电工技术 | 1209篇 |
综合类 | 571篇 |
化学工业 | 4078篇 |
金属工艺 | 405篇 |
机械仪表 | 268篇 |
建筑科学 | 85篇 |
矿业工程 | 125篇 |
能源动力 | 280篇 |
轻工业 | 669篇 |
水利工程 | 12篇 |
石油天然气 | 89篇 |
武器工业 | 34篇 |
无线电 | 2608篇 |
一般工业技术 | 1943篇 |
冶金工业 | 172篇 |
原子能技术 | 265篇 |
自动化技术 | 491篇 |
出版年
2024年 | 56篇 |
2023年 | 281篇 |
2022年 | 342篇 |
2021年 | 447篇 |
2020年 | 419篇 |
2019年 | 451篇 |
2018年 | 428篇 |
2017年 | 482篇 |
2016年 | 397篇 |
2015年 | 376篇 |
2014年 | 503篇 |
2013年 | 767篇 |
2012年 | 675篇 |
2011年 | 791篇 |
2010年 | 557篇 |
2009年 | 641篇 |
2008年 | 613篇 |
2007年 | 677篇 |
2006年 | 698篇 |
2005年 | 534篇 |
2004年 | 491篇 |
2003年 | 428篇 |
2002年 | 341篇 |
2001年 | 298篇 |
2000年 | 266篇 |
1999年 | 205篇 |
1998年 | 189篇 |
1997年 | 148篇 |
1996年 | 133篇 |
1995年 | 107篇 |
1994年 | 84篇 |
1993年 | 76篇 |
1992年 | 86篇 |
1991年 | 73篇 |
1990年 | 43篇 |
1989年 | 52篇 |
1988年 | 45篇 |
1987年 | 19篇 |
1986年 | 21篇 |
1985年 | 18篇 |
1984年 | 13篇 |
1983年 | 12篇 |
1982年 | 12篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
The aim of this article is to synthesis tungsten oxide (WO3) nanoparticle along with Manganese (3 wt% and 10 wt%) by Microwave irradiation method. The physical properties of the synthesized Manganese doped Tungsten oxide materials were characterized by X-Ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Transmission Electron Microscope (TEM), UV-Diffuse Reflectance Spectroscopy, SEM-EDAX and Photoluminescence studies. The predominant peaks obtained in X-ray diffraction pattern reveal the crystalline nature of the nanoparticles and the structure belongs to Monoclinic for pure and Mn doped WO3. FTIR analysis shows the presence of Tungsten and oxygen in the synthesis material and verified with EDAX. TEM analysis shows both pristine and Mn doped WO3 nanopaticles. They are having spherical shaped morphology with average particle size from 35 to 40 nm. UV-DRS revealed that the bandgap energy for pure and Manganese doped WO3 are discussed in this article. The Scanning Electron Microscope analysis shows the plate like morphology for pure WO3 and the morphology were decreased by doping Manganese. The defects and oxygen deficiencies were analysed by photoluminescence spectroscopy. 相似文献
2.
Hao Li Pengcheng Zhang Shengquan Yu Hongyu Yang Bin Tang Fuhai Li Shuren Zhang 《Ceramics International》2019,45(9):11639-11647
Mg2(Ti1-xSnx)O4 (x?=?0–1) ceramics were prepared through conventional solid-state method. This paper focused on the dependence of microwave dielectric properties on crystal structural characteristics via crystal structure refinement, Raman spectra study and complex chemical bond theory. XRD spectrums delineated the phase information of a spinel structure, and structural characteristic of these compositions were achieved with the help of Rietveld refinements. Raman spectrums were used to depict the correlations between vibrational phonon modes and dielectric properties. The variation of permittivity is ascribed to the Mg2(Ti1-xSnx)O4 average bond covalency. The relationship among the B-site octahedral bond energy, tetrahedral bond energy and temperature coefficient are discussed by defining on the change rate of bond energy and the contribution rate of octahedral bond energy. The quality factor is affected by systematic total lattice energy, and the research of XPS patterns illustrated that oxygen vacancies can be effectively restrained in rich oxygen sintering process. Obviously, the microwave dielectric properties of Mg2(Ti1-xSnx)O4 compounds were obtained (= 12.18, ?=?170,130?GHz, ?=??53.1?ppm/°C, x?=?0.2). 相似文献
3.
《Journal of the European Ceramic Society》2019,39(2-3):340-345
The Ca(1+2y)Sn(1-x)Si(1+y)O(5-2x+4y) low-permittivity microwave dielectric ceramics were prepared through solid-state reaction at 1350–1450 °C for 5 h. The relations between microwave dielectric properties and phase compositions for non-stoichiometric Ca(1+2y)Sn(1-x)Si(1+y)O(5-2x+4y) ceramics have been investigated. A single CaSnSiO5 phase with abnormally positive temperature coefficient of resonant frequency (τf = + 62.5 ppm/°C) was synthesised at 1450 °C. This composition was an effective τf compensator of CaSiO3 and Ca3SnSi2O9 phases with typically negative τf value. The CaSiO3 second phase was related to the Sn deficiency in the CaSn(1-x)SiO(5-2x) (0 < x < 1.0) composition, whereas the Ca3SnSi2O9 second phase was obtained by controlling the Ca:Sn:Si ratios on the basis of the Ca(1+2y)SnSi(1+y)O(5+4y) (0 < y < 1.0) composition. A promising low-permittivity millimetre-wave ceramic with most excellent microwave dielectric properties (εr = 10.2, Q×f = 81,000 GHz and τf = −4.8 ppm/°C) was produced from the Ca(1+2y)SnSi(1+y)O(5+4y) (y = 0.4) ceramic. 相似文献
4.
5.
新型高k栅介质材料研究进展 总被引:5,自引:0,他引:5
随着半导体技术的不断发展,MOSFET(metal-oxide-semiconductor field effect transistor)的特征尺寸不断缩小,栅介质等效氧化物厚度已小至nm数量级。这时电子的直接隧穿效应将非常显著,将严重影响器件的稳定性和可靠性。因此需要寻找新型高k介质材料,能够在保持和增大栅极电容的同时,使介质层仍保持足够的物理厚度来限制隧穿效应的影响。本文综述了研究高k栅介质材料的意义;MOS栅介质的要求;主要新型高k栅介质材料的最新研究动态;展望了高k介质材料今后发展的主要趋势和需要解决的问题。 相似文献
6.
Low dielectric poly[methylsilsesquioxane‐ran‐trifluoropropylsilsesquioxane‐ran‐(2,4,6,8‐tetramethyl‐2,4,6,8‐tetraethylenecyclotetrasiloxane)silsesquioxane]s {P[M‐ran‐TFP‐ran‐(TCS)]SSQs} having various compositions were synthesized using trifluoropropyl trimethoxysilane, methyl trimethoxysilane and 2,4,6,8‐tetramethyl‐2,4,6,8‐tetra(trimethoxysilylethyl)cyclotetrasiloxane. The chemical composition of the polymers and the content of SiOH end‐groups were controlled by adjusting the reaction conditions, and they were characterized by 1H‐NMR. The thermally decomposable trifluoropropyl groups on the P[M‐ran‐TFP‐ran‐(TCS)]SSQ backbone and heptakis(2,3,6‐tri‐O‐methyl)‐β‐cyclodextrin (CD) were employed as pore generators. The dielectric constants of the porous CD/P[M‐ran‐TFP‐ran‐(TCS)]SSQ films were in the range 2.0–2.7 (at 100 kHz) depending on the concentration of the porogens, and showed no change over 4 days under aqueous conditions. The pore size of the films showed a bimodal distribution, with diameters of ca 0.5–1.0 nm for those originating from the trifluoropropyl groups and 1.7 nm from the CD. The elastic modulus and hardness of the 30 vol% CD‐blended film with a dielectric constant of 2.26 were 2.40 and 0.38 GPa, respectively, as determined by a nanoindenter. Copyright © 2005 Society of Chemical Industry 相似文献
7.
Gasification of polyethylene (PE) pellet was studied using atmospheric argon-steam plasma generated by microwave discharge and the feasibility of the process was examined. The experimental results showed that additional steam to argon plasma promoted the weight decrease of PE and enhanced the production of H2, CO, CO2 and CH4. The results confirmed that the treatment of plastics with the steam plasma was effective to obtain synthesis gas. 相似文献
8.
5(4H)-Oxazolones react with ammonium acetate under microwave irradiation and using graphite as support in an eco-friendly process.
The reaction was carried out under solvent-free conditions and the imidazolones were obtained quantitatively. Moreover the
reaction time was reduced too. 相似文献
9.
WKB近似下的Fourier衍射成象方法 总被引:1,自引:0,他引:1
对于介质目标微波衍射成象,本文引入了WKB近似来模拟目标内部总场。基于这种近似,我们导出了Fourier衍射公式,并采用了广义滤波逆传播方法由目标空间谱实现目标特性的重建。计算机模拟结果表明采用WKB近似重建目标特性较Born近似有明显改善。 相似文献
10.
Chemical mechanical polishing of polymer films 总被引:2,自引:0,他引:2
Strategies to reduce capacitance effects associated with shrinking integrated circuit (IC) design rules include incorporating
low resistivity metals and insulators with low dielectric values, or “low-κ” materials. Using such materials in current IC
fabrication schemes necessitates the development of reliable chemical mechanical polishing (CMP) processes and process consumables
tailored for them. Here we present results of CMP experiments performed on FLARE™ 2.0 using a specialized zirconium oxide
(ZrO2) polishing slurry. FLARE™ 2.0 is a poly(arylene) ether from AlliedSignal, Inc. with a nominal dielectric constant of 2.8.
In addition, we provide insight into possible removal mechanisms during the CMP of organic polymers by examining the performance
of numerous abrasive slurries. Although specific to a limited number of polymers, the authors suggest that the information
presented in this paper is relevant to the CMP performance of many polymer dielectric materials. 相似文献