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To gain a better understanding of the ultra-high molecular weight polyethylene (UHMWPE) wear mechanism in the physiological environment, the effects of protein and lipid constituents of synovial fluid on the specific wear rate of UHMWPE were examined experimentally. The multidirectional sliding pin-on-plate wear tester was employed to simulate the simplified sliding condition of hip joint prostheses. Bovine serum γ-globulin and synthetic l--DPPC were used as model protein and lipid constituents of synovia, respectively. Results of the wear test indicated that the UHMWPE wear rate primarily depended on the protein concentration of the test lubricant. Lipids acted as a boundary lubricant and reduced polyethylene wear in the low protein lubricants. However, the polyethylene wear rate increased with increasing lipid concentrations if the protein concentration was within the physiological level. Increased interactions between protein and lipid molecules and lipid diffusion to polyethylene surface might be responsible for the increased wear. 相似文献
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硅烷交联超高分子量聚乙烯 总被引:7,自引:0,他引:7
采用硅烷对超高分子量聚乙烯(UHMWPE)进行交联改性,系统地研究了交联UHMWPE的凝胶率、熔点、结晶度、力学性能与耐磨性。结果表明,硅烷偶联剂导致了UHMWPE的交联,使UHMWPE的凝胶率提高。当硅烷含量较低时,UHMWPE的熔点增高、结晶度增大;当硅烷含量较高时,UHMWPE的熔点、结晶度呈下降的趋势;硅烷交联导致了UHMWPE材料的模量和强度提高,磨耗率降低;当硅烷含量较高时,交联UHMWPE材料的力学性能和磨耗率均变差;当硅烷含量为0.2份~0.4份时,交联UHMWPE材料的综合性能最佳。 相似文献
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Summary: Compacted fiber composites offer unique properties due to their lack of an extraneous matrix. The conditions of processing ultra‐high molecular weight polyethylene (UHMWPE) fibers were simulated in a heated pressure cell. In situ X‐ray diffraction measurements were used to follow the relevant transitions and the changes in the degree of crystallinity during melting and crystallization. The results strongly support the suggestion that the hexagonal crystal phase, in which the chain conformation is extremely mobile on the segmental level, constitutes the physical basis of compaction technologies for processing UHMWPE fibers into a single‐polymer composite. This report suggests that using a pseudo‐phase diagram outlining the occurrence of different phases during slow heating and the degree of crystallinity can provide valuable insight into the technological parameters relevant for optimal processing conditions.
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通过对超高分子量聚乙烯(UHMWPE)特性的分析,指出用其制作瓷机滤板的可能性,并针对UHMWPE的成型加工性能及瓷机滤板的结构特点,确定了压制、烧结成型的工艺方案,阐述了瓷机滤板压制、烧结成型工艺务件,压缩模具结构,模具工作过程,以及成型过程中使用的加热与冷却装置及加热与冷却油路设计,介绍了压制、烧结成型工艺要点和UHMWPE瓷机滤板的应用情况。 相似文献
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Two surface modification methods—plasma surface treatment and chemical agent treatment—were used to investigate their effects on the surface properties of ultrahigh‐molecular‐weight polyethylene (UHMWPE) fibers. In the analyses, performed using electron spectroscopy for chemical analysis, changes in weight, and scanning electron microscope observations, demonstrated that the two fiber‐surface‐modified composites formed between UHMWPE fiber and epoxy matrix exhibited improved interfacial adhesion and slight improvements in tensile strengths, but notable decreases in elongation, relative to those properties of the composites reinforced with the untreated UHMWPE fibers. In addition, three kinds of epoxy resins—neat DGEBA, polyurethane‐crosslinked DGEBA, and BHHBP‐DGEBA—were used as resin matrices to examine the tensile and elongation properties of their UHMWPE fiber‐reinforced composites. From stress/strain measurements and scanning electron microscope observations, the resin matrix improved the tensile strength apparently, but did not affect the elongation. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 655–665, 2007 相似文献