首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   53443篇
  免费   5779篇
  国内免费   2841篇
电工技术   872篇
综合类   4171篇
化学工业   19021篇
金属工艺   5952篇
机械仪表   1544篇
建筑科学   3061篇
矿业工程   1721篇
能源动力   1047篇
轻工业   5924篇
水利工程   555篇
石油天然气   3516篇
武器工业   530篇
无线电   1779篇
一般工业技术   7169篇
冶金工业   3330篇
原子能技术   520篇
自动化技术   1351篇
  2024年   44篇
  2023年   736篇
  2022年   1557篇
  2021年   1888篇
  2020年   1842篇
  2019年   1508篇
  2018年   1529篇
  2017年   1971篇
  2016年   1933篇
  2015年   2123篇
  2014年   2717篇
  2013年   3089篇
  2012年   4168篇
  2011年   4051篇
  2010年   3044篇
  2009年   3190篇
  2008年   2486篇
  2007年   3625篇
  2006年   3372篇
  2005年   2828篇
  2004年   2376篇
  2003年   2067篇
  2002年   1768篇
  2001年   1441篇
  2000年   1230篇
  1999年   1059篇
  1998年   896篇
  1997年   661篇
  1996年   632篇
  1995年   485篇
  1994年   484篇
  1993年   312篇
  1992年   290篇
  1991年   177篇
  1990年   97篇
  1989年   73篇
  1988年   69篇
  1987年   63篇
  1986年   32篇
  1985年   36篇
  1984年   31篇
  1983年   19篇
  1982年   12篇
  1981年   14篇
  1980年   12篇
  1979年   6篇
  1977年   3篇
  1976年   3篇
  1973年   2篇
  1959年   9篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
研究了用弱碱性阴离子交换树脂从硫酸浸出液中吸附铀,NaOH预处理负载树脂,碳酸钠和碳酸氢钠解析负载树脂的酸性吸附-碱性淋洗工艺。研究结果表明:该工艺能有效吸附溶液中的铀酰离子,选择性高;NaOH预处理工艺在中和树脂中氢离子的同时,能有效去除硫酸根离子,并降低钼、硅、铁等杂项元素含量;通过控制碳酸钠和碳酸氢钠溶液的流速,可成功将树脂上的铀淋洗到溶液中,实现铀的净化提取。  相似文献   
2.
In a narrow channel, the apparent relative viscosity of a suspension with finite-size particles is strongly dependent on its microscopic particle arrangement. Relative viscosity increases when suspended particles flow near the channel wall; thus, a suspension in a narrow channel does not always exhibit the same rheological properties even if the concentration is the same. In this study, we focus on the inertia and concentration of particles in a narrow channel and consider their effects on the microscopic particle arrangement and macroscopic suspension rheology. Two-dimensional pressure-driven suspension flow simulations were performed using a two-way coupling scheme, and normalized particle density distribution (PDD) were implemented to consider their particle arrangements. The results demonstrated that the velocity profiles for the particle suspension were changed by the Reynolds number and particle concentration because of the interactions between particles according to the power-law index. These changes affected the particle equilibrium positions in the channel, and the subsequent changes in solvent layer thickness caused changes in the macroscopic apparent viscosity. The behavior of microscopic particles played important roles in determining macroscopic rheology. Thus, we have confirmed that a normalized PDD can be used to estimate and assess the macroscopic rheology of a suspension.  相似文献   
3.
Pt–MoO3 was synthesized by microwave-assisted chemical reduction. The physicochemical characterization showed that the electrocatalyst contained nanoparticles of Pt and clusters of MoO3. The average particle size of the catalytic material was 2.5 nm. The electrochemical results showed that the Pt–MoO3/C was suitable to carry out the electrooxidation reactions of ethanol and methanol indistinctly, avoiding CO poisoning. It was possible to compare the results with commercial Pt/C. The synthesized material showed a better electrochemical performance. Different simulations were performed using the Nernst equation to evaluate the influence of temperature, internal resistance, and the current density losses as a function of the fuel used. The theoretical results indicated that the electrical power of the mono-cell improves by 21.5% when the energy vector is changed from methanol to ethanol at the maximum power point, obtaining an electrical potential change ΔE = 87.02 mV and a variation of the electric power of Δp = 114.14 mW cm?2. The use of dual fuels could improve the performance of experimental fuel cells.  相似文献   
4.
This study was conducted to evaluate the effect of red-wine grape pomaces on the quality and sensory attributes of beef hamburger patties. Both phenolic content and antioxidant activity were assessed using Syrah, Merlot and Cabernet Sauvignon pomaces. Following the assessment, hamburger patties were prepared with Merlot pomace at 0%, 2% and 4% for the patty quality and sensory attributes. Grape seeds possessed significantly higher phenolics and antioxidant activities over the seedless pomace (P < 0.05), whereas no significant difference was found for phenolics and antioxidant activities within the seeds and seedless pomaces. The patty pH decreased as the pomace was added for 2% and 4%. Colour values (L*, a* and b*) of patties lowered as the pomace was added. Allo-Kramer shear force and hardness values increased while cooking yield decreased (P < 0.05) with the addition of pomace. No significant difference between control and Merlot patties was found for flavour, juiciness and colour, whereas lower sensory attributes were observed for texture, taste and overall acceptability. It is observed that the addition of fermented red-wine grape pomace provides hamburger patties with health promoting factors such as antioxidant and other functional components, but it also provided darker, sourer and lower cooking yield.  相似文献   
5.
《Journal of dairy science》2022,105(5):3926-3938
Sensory and physical properties of 2 lemon-flavored beverages with 5% and 7.5% wt/wt nonfat dry milk (NFDM) at pH 2.5 were studied during storage. The 2 beverages had similar volatile compounds, but the 5% NFDM had higher aroma and lemon flavor, with a preferred appearance by consumers due to the lower turbidity and viscosity. After 28 d of storage at 4°C, lemon flavor decreased in the 5% NFDM beverage but was still more intense than the 7.5% one. During 70 d of storage, no microorganisms were detected, and the beverages were more stable when stored at 4°C than at room temperature according to changes of physical properties measured for appearance, turbidity, color, particle size, zeta potential, rheological properties, and transmission electron microscopy morphology. Findings of the present study suggest that NFDM may be used at 5% wt/wt to produce stable acidic dairy beverages with low turbidity when stored at 4°C.  相似文献   
6.
Conventional pressure swing adsorption (PSA) processes can only produce one high purity product in a single stage, whereas the state-of-art dual-reflux PSA (DR-PSA) can produce two high purity products simultaneously. However, multicomponent gas separation is often required in the industry, targeting at recovering several valued products at the same time. In this study, we propose a novel adsorption process, namely triple-reflux PSA (TR-PSA), to separate three components simultaneously. A middle product outlet and a middle reflux stream were introduced to the adsorption columns of a conventional DR-PSA process to separate ternary mixtures of nitrogen, methane, and helium. Nonisothermal dynamic models were built to investigate the impacts of operating parameters particularly the location of the middle reflux/product stream and the middle reflux flow rates. Results showed that the TR-PSA process successfully separated ternary mixtures obtaining three enriched products simultaneously in a single stage, yielding a separation performance comparable to that of the double-stage DR-PSA with significantly lower capital and energy cost.  相似文献   
7.
采用动态硫化方法制备了混炼型聚氨酯橡胶(MPU)/聚十二内酰胺(PA 12)热塑性硫化胶(TPV),通过控制动态硫化时间探究了该TPV的动态硫化历程,同时研究了不同动态硫化阶段共混物的物理机械性能和动态力学性能。结果表明,随着动态硫化时间的延长,MPU/PA 12 TPV逐步完成相转变,在温度和剪切作用下,MPU相由连续相转变为分散相,而PA 12则由分散相转变为连续相;随着动态硫化时间的延长,MPU/PA 12共混物的储能模量升高,损耗模量降低,损耗因子减小。此外,随着动态硫化时间的延长,MPU/PA 12共混物的综合力学性能提高。  相似文献   
8.
刘星园  张永锋  肖凯  高境泽 《化工进展》2022,41(5):2504-2510
挥发性有机化合物(VOCs)的大量排放对我国大气环境已造成严重污染。本文综述了针对工业VOCs排放浓度低、风量大、含水等特点,分子筛作为较成熟的吸附材料在VOCs吸附处理中的应用。影响分子筛吸附VOCs的因素有孔径结构、表面性质、疏水性等。研究表明,与吸附质动力学尺寸相匹配的孔径和具有多级孔的分子筛吸附性能优良,引入适宜补偿阳离子也可加强吸附。文中指出:提高硅铝比或硅烷化改性来提高分子筛疏水性以及免除模板剂使用,降低成本,减小污染成为当下发展主流;在制备方法上打破传统水热合成法,使用固相法、微波辅助、晶种导入来降低能耗,实现绿色合成已成为新兴话题;研发多功能整体式材料以及吸附法和多种方法相结合来处理VOCs已成为未来发展趋势。  相似文献   
9.
中国含油气盆地超深层广泛发育灰岩,灰岩的主要矿物成分是方解石,其特殊的晶体结构决定了其在超深层具有很强的塑性和韧性。在小变形作用下,灰岩不容易发生断裂。灰岩尤其是泥灰岩,因其较低的孔隙度和渗透率也可以作为盖层。四川盆地元坝气藏埋深超过6 500 m,储气规模大,其盖层和保存条件一直备受关注。下三叠统膏盐岩作为元坝气藏的区域性盖层得到普遍认可,但是飞仙关组灰岩作为其直接盖层尚存争议。在岩心观察、岩石力学参数测试、地质资料分析的基础上,从脆—韧性的角度分析飞仙关组灰岩作为盖层的完整性。飞仙关组灰岩在生气高峰期及之后,韧性显著提高,力学性质处于韧性阶段,不易发生破裂,能够保持岩层完整性,从而成为二叠系长兴组白云岩储层的良好盖层。该实例说明,灰岩在超深层可以作为盖层,对碳酸盐岩区的油气勘探具有重要意义。  相似文献   
10.
为评估玉米芯作为生物滞留设施中填料土添加剂的可行性,通过理化性质测试、摇床淋出试验、等温吸附试验,与现有添加剂柳木屑、陶粒、稻壳生物炭进行对比,研究玉米芯的理化性质和营养素的淋出及吸附特性。结果表明:玉米芯轻质多孔,具有较大的比表面积和阳离子交换量,其氮磷含量低,有丰富的含氧官能团;以玉米芯作为添加剂,在去离子水的淋洗作用下,氮磷营养素淋出量低、淋出速度快,在降雨径流中氮磷营养素淋出量降低,淋出速度减缓;在营养素质量浓度为2mg/L的典型降雨径流中,玉米芯可吸附25mg/kg的NH+4和79mg/kg的PO3-4,相较于其他材料,玉米芯吸附效果突出。玉米芯可作为填料土添加剂用于生物滞留设施中,施用玉米芯可降低填料土营养素淋出风险,提升生物滞留设施对降雨径流中污染物的吸附和去除效果。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号