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1.
本文在环氧涂料中添加玄武岩鳞片,提高其防腐蚀性能。针对玄武岩鳞片的团聚问题,通过机械力化学改性工艺,采用正硅酸四乙酯、HY-311型钛酸酯偶联剂、E-44型环氧树脂对玄武岩鳞片进行杂化包覆,结果表明,杂化包覆后玄武岩鳞片的沉降时间从2h提高至96 h。杂化包覆玄武岩鳞片添加量为20%涂层的性能最优,附着力为13.40 MPa,耐盐雾时间为2000 h,在3.5%NaCl溶液中浸泡2000 h后,0.01 Hz的阻抗模值仍然有5.15×109 Ω·cm2。 相似文献
2.
An ecofriendly and biodegradable porous structure was prepared from drying aqueous foams based on nano fibrillated cellulose (NFC), extracted from softwood pulp by subcritical water/CO2 treatment (SC-NFC). The primary aim of this work was to use the modified SC-NFC as stabilizer for a water-based Pickering emulsion which upon drying, yielded porous cellulosic materials, a good dye adsorbent. In order to exploit the carboxymethylated SC-NFC (CMSC-NFC, with a degree of substitution of 0.35 and a charge density of 649 μeqv/g) as a stabilizer for water-based Pickering emulsion in subsequent step, an optimized quantity of octyl amine (30 mg/g of SC-NFC) was added to make them partially hydrophobic. A series of dry foam structures were prepared by varying the concentrations of treated CMSC-NFCs and 4 wt% was found to be the optimum concentration to yield foam with high porosity (99%) and low density (0.038 g/cc) along with high compression strength (0.24 MPa), superior to the conventionally extracted NFC. The foams were applied to capture as high as 98% of methylene blue dyes, making them a potential green candidate for treating industrial effluent. In addition, the dye adsorption kinetics and isotherms were found to be well suited with second order kinetics and Langmuir isotherm models. 相似文献
3.
《Ceramics International》2022,48(4):4722-4731
In recent years, phase change material emulsions (PCMEs) with enhanced energy storage capacities and good flow characteristics have drawn significant attention. However, due to the thermodynamically unstable nature and tiny particle confinement, the nanomaterial modification strategies at PCM/water interface to improve stabilities and reduce supercooling of nano-sized PCMEs (NPCMEs) are very limited and challenging. Herein, we report a facile strategy for constructing MXene-decorated NPCME with good stability, little supercooling, and high thermal conductivity by self-assembly of MXene nanosheets at PCM/water interface. The concentrations of MXene have great influences on the average droplet diameters, stabilities, and thermophysical properties of the NPCMEs. The results show that the PCMs have been well dispersed into the water in the form of quasi-spherical droplets, with average droplet diameters of 242–805 nm. The thermal conductivity of 10 wt% n-tetradecane/water NPCME containing 9 mg ml-1 MXene is 0.693 W m-1·K-1, achieving an enhancement by 15.5%, as compared to that of water. Besides, the MXene-decorated paraffin/water NPCMEs exhibit little supercooling and enhanced heat storage capacities. More importantly, this facile self-assembly strategy opens a new platform for preparing high-performance NPCMEs, which can be used as novel heat transfer fluids for thermal energy storage systems. 相似文献
4.
《Ceramics International》2022,48(7):9426-9433
A gradient porous ceramic membrane with surface super-hydrophilic and underwater super-oleophobic performance was prepared by combining hydrogel directional freezing method and low temperature oxidation process. The effects of solid contents and sintering temperature on the ceramic membrane matrix were examined. The reaction time and synthesis temperature on the TiO2 nanowire array were also evaluated. In addition, the related effects on pore size distribution, permeation flux, contact angle, and oil-in-water emulsion separation were systematically investigated. The ceramic membrane matrix pore size changed from 0.5 μm to 25 μm gradually, indicating the gradient structure controlled by the growth of ice. The super-hydrophilic and underwater super-oleophobic performance of ceramic membrane surface was obtained with surface modification by TiO2 nanowire array, and the surface water contact angle and underwater oil contact angle were less than 5° and over 158°, respectively. The bonding strength between TiO2 nanowire and ceramic membrane matrix was high enough to withstand ultrasonic waves. The ceramic membrane modified with TiO2 nanowire array was used for 1000 ppm diesel oil-in-water emulsion separation, and the stable separation efficiency and flux were about 97% and 100–200 L/(m2 h bar) even after 10 filtration cycles. 相似文献
5.
6.
《International Journal of Hydrogen Energy》2022,47(80):34244-34256
A conducting and anticorrosive coating is crucial for the application of metal bipolar plates (BP) in proton exchange membrane fuel cell (PEMFC). In this work, a Ti3C2Tx (T)-carbon black (C)-acrylic epoxy (AE) coating is prepared on 304 stainless steel (SS) with enhanced corrosion resistance and conductivity. The corrosion resistance of the T-C-AE coating is investigated in a 0.5 M H2SO4 solution as compared to the AE, T, and T-AE coatings. The T-C-AE coated 304SS exhibits the strongest corrosion resistance with the most positive corrosion potential and the lowest corrosion current density of 0.00673 μA cm?2 in all the samples, while retaining intact and compact surface morphology with the lowest metal ion dissolution even after immersed for 720 h. The addition of Ti3C2Tx and carbon black into the AE matrix greatly decreases interfacial contact resistance (ICR), and the T-C-AE coating achieves a low ICR of 15.5 mΩ cm?2 under 140 N cm?2 compaction force. The excellent anticorrosion performance is mainly attributed to the physical barrier and the cathodic protection provided by the stacked Ti3C2Tx (MXene) nanosheets in the T-C-AE coating. This eco-friendly, conducting, and anticorrosive T-C-AE coating has a good application prospect on SS BP of PEMFC. 相似文献
7.
Yuhang Xing Ruyi Li Lu Xue Mianhong Chen Xuli Lu Zhihao Duan Wei Zhou Jihua Li 《International Journal of Food Science & Technology》2022,57(8):5268-5279
Mangiferin (MGF) is a phenolic compound isolated from mango, but its poor solubility significantly limits its use. In this study, MGF was embedded into the inner aqueous phase of W1/O/W2 emulsions. Firstly, the dissolution method of MGF was determined. MGF remained stable in solution with pH 13 at 30 min, and its solubility reached 10 mg mL−1. When the pH of MGF solutions was adjusted from pH 13 to pH 6, MGF did not immediately crystallise, providing sufficient time to construct the MGF-loaded W1/O/W2 emulsions. Subsequently, the MGF-loaded W1/O/W2 emulsions were constructed using polyglycerol polyricinoleate (PGPR) and calcium caseinate (CAS). The formation and stability of the W1/O/W2 emulsions were investigated. The MGF-loaded W1/O/W2 emulsions stabilised with 1% PGPR and 1% – 3% CAS exhibited a low viscosity, limited loading capacity, and poor stability. Conversely, the MGF-loaded W1/O/W2 emulsions stabilised by 3%PGPR–3%CAS exhibited optimal loading capacity (encapsulation efficiency = 95.31% and loading efficiency = 0.91%) and stability, which was attributed to the fact that high viscosity and gel state retarded the migration of inner aqueous phase. These results indicated that the W1/O/W2 emulsions stabilised by PGPR and CAS may be a potential alternative for encapsulating mangiferin. 相似文献
8.
Yunpeng Zhang Jiaofeng Ye Dongan Qu Haitao Wang Changsheng Chai Libang Feng 《Polymer Engineering and Science》2021,61(9):2257-2266
Micro-damage in materials could be repaired by endowing materials with self-healing performance. Herein, an epoxy resin with excellent self-healing performance grounded on thermo-reversible Diels–Alder dynamic chemical reaction was developed. Results showed that the bending strength and adhesive behavior of epoxy resin were influenced dramatically upon treatment with various temperatures. More importantly, damages created in epoxy resin could be repaired completely after suitable heat treatments. What is more, the healed epoxy resin exhibited much higher bending strength and adhesive performance than the pristine one did. The materials could be damaged and then repaired repeatedly. Meanwhile, the as-prepared self-healing epoxy resin exhibited excellent thermal reversibility and controllable adhesion. The thermo-adjusted self-healing performance endowed epoxy resin with recyclable and reusable performance. Therefore, the research made it possible of recycling waste epoxy resins. 相似文献
10.