Fabrication and properties of the superhydrophobic ceria-based composite coating on magnesium alloy

A superhydrophobic ceria-based composite coating is developed to improve anticorrosion properties of AZ61 magnesium alloy, fabricating via chemical conversion method followed by hydrothermal treatment. The cerium conversion coating has a block structure with microcracks. After the hydrothermal treatment, a dense CeO₂ layer, porous CeO₂ nanorods, and stearic absorbing layers are grown stepwise on the conversion coating. And the composite coating is hydrophobic or even superhydrophobic and has almost no microcracks. As the hydrothermal reaction time increases, the water contact angle of the composite coating first increases and then decreases, and it reaches the maximum value of 152° after hydrothermal treatment for 4 h. Both the dense CeO₂ layer and the superhydrophobic stearic absorbing layer can effectively prevent the electrolyte from contacting the substrate; the corrosion current density of the superhydrophobic composite coating is lower than that of the hydrophilic composite coating and the cerium conversion coating, and has the best corrosion resistance.     

涪陵地区茅三段热液白云岩展布影响因素分析

针对热液白云岩展布非均质性强的问题,开展基底断裂与茅三段沉积演化关系研究,分析断裂样式与白云岩分布关系,建立沉积演化模式,预测白云岩的分布。研究结果表明:茅三段可划分为5个小层,1~3小层为白云岩发育主要时期,4~5小层为台地均一化时期,不发育白云岩;15-1、15-2和16号基底断裂控制了早期“台-洼”相间的沉积地貌,断裂附近的地貌高部位为生屑滩发育有利部位,为白云岩的发育提供物质基础;15-1、15-2号基底断裂样式为花状,周边生屑滩白云石化程度高,为白云岩发育最有利区;16号基底断裂为直立状,附近白云石化发育程度较低,为白云岩发育较有利区。研究成果可为热液白云岩领域的进一步勘探提供指导依据。     

紫金山东南矿段成矿期次、阶段浅析

通过对紫金山东南矿段铜钼(金)矿床地质矿化特征分析,指出铜钼矿化带主要赋存于花岗闪长斑岩的内外接触带,处于似斑状花岗闪长斑岩的上部,金矿化带赋存在表生氧化带的英安玢岩、隐爆角砾岩中。经过对矿石的组构特征、矿物生成顺序等特征分析,将矿床的成矿演化过程分为斑岩热液期、高硫化浅成低温热液期、表生氧化期三个主要矿化期次,进一步将斑岩热液期分为黑云母-钾长石化阶段、石英-绢云母化阶段、碳酸盐化阶段三个阶段;高硫化浅成低温热液期分为地开石化阶段、明矾石化阶段、硅化阶段三个阶段。研究结果为进一步研究矿床成因提供了依据。     

Conversion of aqueous extracts from thermochemical treatment of bagasse into functional emulsifiers

Synthetic emulsifiers in food industries are being replaced with a customer-friendly food ingredient that is derived from biomass using sustainable green technologies. After hydrothermal liquefaction treatment, raw bagasse (21%), pith (26%), and rind portions (25%) were obtained with reduced ash contents. As aqueous extracts, with oligosaccharides and lignin residues, it was used in the preparation of oil-in-water emulsions with 5% soybean oil. Results showed that the emulsions stabilised the oil droplets with particle size between 11 and 17 µm by steric repulsion with raw bagasse-stabilised emulsion showing a better stability at 25 °C (31 days). It was demonstrated that raw bagasse extracts, without alteration, maybe a potential unconventional source for food-grade emulsifiers by integrating a versatile thermochemical conversion of waste without the use of chemicals.     

Couple-based particle swarm optimization for short-term hydrothermal scheduling

A novel couple-based particle swarm optimization (CPSO) is presented in this paper, and applied to solve the short-term hydrothermal scheduling (STHS) problem. In CPSO, three improvements are proposed compared to the canonical particle swarm optimization, aimed at overcoming the premature convergence problem. Dynamic particle couples, a unique sub-group structure in maintaining population diversity, is adopted as the population topology, in which every two particles compose a particle couple randomly in each iteration. Based on this topology, an intersectional learning strategy using the partner learning information of last iteration is employed in every particle couple, which can automatically reveal useful history information and reduce the overly rapid evolution speed. Meanwhile, the coefficients of each particle in a particle couple are set as distinct so that the particle movement patterns can be described and controlled more precisely. In order to demonstrate the effectiveness of our proposed CPSO, the algorithm is firstly tested with four multimodal benchmark functions, and then applied to solve an engineering multimodal problem known as STHS, in which two typical test systems with four different cases are tested, and the results are compared with those of other evolutionary methods published in the literature.     

Super-oleophilicity Co-doping Co2+/F-/TiO2 one-dimensional nanotubes for photocatalytic denitrification of light oil

In this study, a simple hydrothermal synthesis method was adapted for the preparation of Co-doping Co²⁺/F^-/TiO₂ nanotubes photocatalyst, and the micro-nano structure of catalysts prepared by biomimetic technology which makes the catalyst have super-oleophilicity property. Co²⁺/F^-/TiO₂ revealed improved photocatalytic performance for denitrification of light oil compared to single TiO₂ photocatalysts. The enhance of photocatalytic activity can be attributed to narrowing the band gap, increasing the light response wavelength and exposing more highly active crystal surfaces due to synergistic effects of Co²⁺ and F^? in the photocatalyst.     

花状与颗粒状NiMn2O4纳米材料的制备及其超级电容性能

分别以尿素和氨水为沉淀剂，采用热溶剂法制备了多孔的花状NiMn₂O₄和颗粒状NiMn₂O₄纳米电极材料，采用 X射线衍射仪、扫描电镜、透射电镜和N₂ 吸附-脱附等手段对NiMn₂O₄材料的物相、形貌结构和孔径分布进行了表征，并通过循环伏安、恒电流充放电、交流阻抗等方法测试了所制备材料的电化学性能。研究了沉淀剂对NiMn₂O₄材料形貌、微观结构及电化学性能的影响。结果表明：以尿素为沉淀剂的NiMn₂O₄是由纳米片组成的花状结构，纳米片厚度为50～60nm，比表面积为104m²/g。在 1A/g 电流密度下比电容为1614F/g，在5A/g电流密度下，尿素为沉淀剂的花状NiMn₂O₄材料经1000次恒电流充放电后其比电容可达初始值的89%。以氨水为沉淀剂的多孔NiMn₂O₄为直径约30nm的纳米颗粒结构，颗粒间团聚严重，比表面积为91m²/g。在1A/g电流密度下比电容为1147F/g，在5A/g电流密度下，氨水为沉淀剂的颗粒状NiMn₂O₄材料经1000次恒电流充放电后其比电容可达初始值的80%。尿素为沉淀剂的花状NiMn₂O₄具有优越的超级电容性能。     

水热法主要提取因素对光皮木瓜多糖结构的影响

目的 优化水热法提取光皮木瓜（Chaenomeles sinensis）多糖的提取工艺条件，对光皮木瓜不溶性多糖的组成和结构进行分析。方法 预处理后的光皮木瓜样品经水热法提取、抽滤、冲洗，浓缩等操作，分别得到不溶性多糖、醇沉多糖和醇溶多糖，通过傅里叶变换红外光谱、扫描电子显微镜及X射线衍射分析不溶性多糖的组成和结构。 结果 多糖提取的较优条件为150 ℃/45 min，料液比1∶10 (W/V)；温度对水热法提取效果影响显著，适当升高温度、延长提取时间和减少料液比有利于多糖提取；高温虽能促进半纤维素溶解，但无法使木质素和木聚糖降解；即使提取温度不同，光皮木不溶性多糖的结构差异也极小；水热法提取光皮木瓜多糖不会导致多糖的功能性基团变化，只改变多糖的化学组成。结论 该研究可为光皮木瓜多糖的结构与功能研究提供实验依据，也为陕西白河光皮木瓜资源的综合利用提供研究参考。