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1.
Aromatic and functional polymers with processibility derived from biobased starting materials are prerequisite considering sustainable society. Poly(2,5-benzimidazole)s are rigid-rod polymers to show ultrahigh thermal stability such as flame retardance, while usually suffer from poor solubility. Here, poly(benzimidazole-co-amide)s are synthesized from two biobased monomers, 3,4-diaminobenzoic acid and a semirigid comonomer, 4-aminohydrocinnamic acid. The copolymers with an amide composition of 80 mol% and higher are soluble in widely used polar solvents to fabricate the films keeping high flame retardance, which is comparable with popular high-performance polymers such as aromatic polyimides, polyetheretherketone, polyphenylene sulfide, etc.  相似文献   
2.
为清晰认知短波定向扇形天线阵,改进阵列波束合成方法,提升波束合成系统性能,利用鱼骨天线阵列模型模拟接收实际不同极化的天波信号,分析阵列合成波束的指向、增益随来波极化和阵列单元数的变化规律,得到在高极化角来波信号时,来波极化补相时阵列的合成波束比按主极化补相时指向更稳定且增益最大可提高2 dB. 同时利用实测数据对两种补相方式下阵列的波束合成性能进行了验证,与理论分析吻合很好. 本文方法为进一步深入研究阵列极化特性提供了理论基础,并对波束合成实际工程化应用提供了理论依据.  相似文献   
3.
基于GaN HEMT工艺研制了一款8~12.5 GHz宽带6 bit数字移相器.通过采用优化的宽带拓扑和集总元件,以及在片上集成GaN并行驱动器,提高了移相精度,缩小了芯片的尺寸,减少了控制端数量.测试结果表明,在8~12.5 GHz频带内,全部64个移相状态下,插入损耗小于11 dB,输入回波损耗小于-14 dB,输出回波损耗小于-16 dB,移相均方根误差小于1.8°,幅度变化均方根误差小于0.5 dB.在8 GHz频率下,1 dB压缩点输入功率高达33 dBm.芯片尺寸为5.05 mm×2.00 mm×0.08 mm.  相似文献   
4.
5.
The strengthening method of multi-element M-site solid solution is a common approach to improve mechanical properties of MAX phase ceramic. However, the research on capability of multi-element A-site solid solution to improve mechanical properties has rarely been reported. Thereupon, quasi-high-entropy MAX phase ceramic bulks of Ti2(Al1?xAx)C and Ti3(Al1?xAx)C2 (A = Ga, In, Sn, x = 0.2, 0.3, 0.4) were successfully synthesized by in situ vacuum hot pressing via multi-elements solid solution. The multi-elements solid solution in single-atom thick A layer was confirmed by X-ray diffraction and X-ray photoelectron spectroscopy as well as by energy dispersive X-ray spectroscopy mappings. Effects of doped multi-elements contents on the phase, microstructure, mechanical properties, and high temperature tribological behaviors were studied. Results demonstrated that the Vickers hardness, anisotropic flexural strength, fracture toughness, and tribological properties of Ti–Al–C based MAX ceramics could be remarkably improved by constitution of quasi-high-entropy MAX phase in A layers. Moreover, the strengthening and wear mechanisms were also discussed in detail. This method of multi-element solid solution at A-site provides new way to enhance mechanical properties of other MAX phase ceramics.  相似文献   
6.
A detailed study of butyl rubber-based vibration damping formulations linking their composition, morphology, phase structure, viscosity, mechanical loss factor, and other characteristics is presented for the first time. High performance of the compositions including aromatic petroleum oil is explained by limited solubility of the plasticizer that leads to the formation of a highly-viscous emulsion (η20°C ≈ 1000 Pa·s) consisting of a swollen butyl rubber matrix and dispersed oil droplets in the broad composition range. Chalk is found to be the best inorganic filler as its spherical particles provide strong adhesion to the reinforcing layer of aluminum foil. Aiming to eliminate ecologically unfriendly aromatic compounds, a new low-cost binding agent formulation based on butyl rubber mixed with polyisobutylene and highly refined mineral oil is suggested. Being environmentally safe, it possesses high viscosity of 1000–3000 Pa·s, cohesion strength of 3.5–5.0 N/cm, penetration of 4.5–6.0 mm, and mechanical loss factor up to 0.34 at room temperature, which are as good as, or even better than, the properties of currently produced vibration damping materials containing aromatic compounds. New materials can be used in car and aircraft parts for effective vibration isolation.  相似文献   
7.
The transient liquid phase (TLP) bonding of CoCuFeMnNi high entropy alloy (HEA) was studied. The TLP bonding was performed using AWS BNi-2 interlayer at 1050 °C with the TLP bonding time of 20, 60, 180 and 240 min. The effect of bonding time on the joint microstructure was characterized by SEM and EDS. Microstructural results confirmed that complete isothermal solidification occurred approximately at 240 min of bonding time. For samples bonded at 20, 60 and 180 min, athermal solidification zone was formed in the bonding area which included Cr-rich boride and Mn3Si intermetallic compound. For all samples, the γ solid solution was formed in the isothermal solidification zone of the bonding zone. To evaluate the effect of TLP bonding time on mechanical properties of joints, the shear strength and micro-hardness of joints were measured. The results indicated a decrement of micro-hardness in the bonding zone and an increment of micro-hardness in the adjacent zone of joints. The minimum and maximum values of shear strength were 100 and 180 MPa for joints with the bonding time of 20 and 240 min, respectively.  相似文献   
8.
采用扫描电镜、拉-拉疲劳试验机等研究了低温卷取热轧双相钢的显微组织及疲劳性能。结果表明:热轧双相试验钢的疲劳极限约为530 MPa;低温卷取工艺生产的热轧双相试验钢夹杂物平均尺寸多在5 μm以下,晶粒比较细小,马氏体组织较细小且弥散均匀分布,具有良好的综合力学性能。热轧双相试验钢疲劳裂纹源位于样品表面的棱角处,疲劳裂纹扩展区上有大量的韧窝、撕裂棱、疲劳辉纹和二次裂纹,瞬断区以浅韧窝为主,由于铁素体和马氏体发生不同程度的应变,最终二次裂纹在铁素体和马氏体的相界面萌生。二次裂纹虽然萌生但并未扩展,大量二次裂纹分散主裂纹尖端应力集中,可有效降低裂纹扩展的驱动力,降低疲劳裂纹扩散速率,抑制疲劳裂纹扩展,使疲劳强度得到提升。  相似文献   
9.
张学平  崔瑞芝  桑世华 《化工学报》2021,72(9):4479-4486
采用等温溶解平衡法对两个三元体系NaBr-CaBr2-H2O和KBr-CaBr2-H2O在273.15 K下的固液相平衡关系进行了研究,测定了相关盐在水溶液中的溶解度,绘制其等温相图。结果表明,两个三元体系均为水合物型,即平衡固相中未发现任何复盐及固溶体。两个三元体系在273.15 K下的等温相图均由一个共饱点、两条等温溶解度曲线、两个平衡固相结晶区组成。三元体系NaBr-CaBr2-H2O在273.15 K的两个结晶区的平衡固相分别为NaBr·2H2O和CaBr2·6H2O,NaBr·2H2O的结晶区远大于CaBr2·6H2O。三元体系KBr-CaBr2-H2O在273.15 K的两个结晶区的平衡固相分别为KBr和CaBr2·6H2O,KBr的结晶区远大于CaBr2·6H2O。基于Pitzer模型,运用已报道的Pitzer参数对所研究的两个三元体系在273.15 K下的等温溶解度进行模拟计算,其计算结果与实验结果基本吻合。  相似文献   
10.
The applications of antiferroelectric (AFE) materials in miniaturized and integrated electronic devices are limited by their low energy density. To address the above issue, the antiferroelectricity of the reinforced material was designed to improve its AFE-ferroelectric (FE) phase transition under electric fields. In this present study, the composition of Zr4+ (0.72 Å) and Ti4+ (0.605 Å) at B-site of Pb0.97La0.02(ZrxSn0.05Ti0.95-x)O3 ceramics with orthogonal reflections are synthesized via the tape-casting method. These ceramics are modified to enhance their antiferroelectricity by reducing their tolerance factor. A recoverable energy storage density Wrec 12.1 J/cm3 was obtained for x = 0.93 under 376 kV/cm, which is superior value than reported until now in lead-based energy storage systems. Moreover, the discharge energy density can reach 10.23 J/cm3, and 90 % of which can be released within 5.66 μs. This work provides a new window and potential materials for further industrialization of pulse power capacitors.  相似文献   
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