全文获取类型
收费全文 | 11843篇 |
免费 | 1478篇 |
国内免费 | 131篇 |
专业分类
电工技术 | 69篇 |
综合类 | 370篇 |
化学工业 | 3853篇 |
金属工艺 | 94篇 |
机械仪表 | 168篇 |
建筑科学 | 70篇 |
矿业工程 | 36篇 |
能源动力 | 108篇 |
轻工业 | 7739篇 |
水利工程 | 7篇 |
石油天然气 | 468篇 |
武器工业 | 20篇 |
无线电 | 53篇 |
一般工业技术 | 340篇 |
冶金工业 | 34篇 |
原子能技术 | 11篇 |
自动化技术 | 12篇 |
出版年
2024年 | 122篇 |
2023年 | 264篇 |
2022年 | 533篇 |
2021年 | 693篇 |
2020年 | 639篇 |
2019年 | 671篇 |
2018年 | 563篇 |
2017年 | 564篇 |
2016年 | 607篇 |
2015年 | 565篇 |
2014年 | 621篇 |
2013年 | 710篇 |
2012年 | 1084篇 |
2011年 | 940篇 |
2010年 | 598篇 |
2009年 | 503篇 |
2008年 | 418篇 |
2007年 | 465篇 |
2006年 | 469篇 |
2005年 | 393篇 |
2004年 | 349篇 |
2003年 | 298篇 |
2002年 | 235篇 |
2001年 | 194篇 |
2000年 | 197篇 |
1999年 | 154篇 |
1998年 | 130篇 |
1997年 | 107篇 |
1996年 | 78篇 |
1995年 | 68篇 |
1994年 | 50篇 |
1993年 | 43篇 |
1992年 | 34篇 |
1991年 | 21篇 |
1990年 | 16篇 |
1989年 | 14篇 |
1988年 | 4篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 3篇 |
1982年 | 5篇 |
1981年 | 6篇 |
1980年 | 11篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 343 毫秒
1.
2.
3.
4.
The present study was conducted to develop subcritical water extraction (SWE) of Echinacea purpurea flowers. The influence of temperature and extraction time on quality of extracts considering total phenols content, total flavonoids content, antioxidant capacity and extraction yield, was determined. Optimized extraction parameters for maximised investigated responses were as follows: 147.56 °C and 8.43 min. The experimental values agreed with the values predicted, thus indicating the adequacy of central composite experimental design for modelling the SWE of bioactive compounds from E. purpurea. Results of the study also highlighted the potential application of E. purpurea subcritical water extracts as a source of valuable bioactive compounds. 相似文献
5.
Wan‐Xia Wu 《Polymer International》2019,68(11):1848-1855
A series of novel aliphatic poly(β‐thioether ester)s with various methylene group contents were prepared by direct lipase‐catalyzed polycondensation of the monomer with an acid‐labile β‐thiopropionate group. The polycondensation reaction using immobilized lipase B from Candida antarctica was carried out in diphenyl ether at 90 °C. Poly(β‐thioether ester)s with high molecular weights of 20 500–57 000 Da and narrow polydispersities in the range 1.40–1.48 were obtained. Thermogravimetric analysis, differential scanning calorimetry and wide‐angle X‐ray diffraction were used to investigate the thermal properties and crystal structures of these polyesters. All the poly(β‐thioether ester)s were semicrystalline polymers and thermally stable up to at least 200 °C. In vitro degradation studies showed that they can rapidly degrade under acidic conditions by the hydrolysis of the β‐thiopropionate groups, suggesting their potential as acid‐degradable polymeric materials. © 2019 Society of Chemical Industry 相似文献
6.
Moderate alcohol consumption is associated with increased plasma high-density lipoprotein (HDL)-cholesterol concentrations and reduced risk for cardiovascular disease. Plasma cholesteryl ester transfer activity (CETA) mediates the exchange of HDL-cholesteryl ester (CE) for the triacylglycerol (TAG) of very-low-density lipoproteins. We compared the effects of oral challenges of Alcohol, saturated fat (SAT), and (Alcohol + SAT) on plasma CETA, cholesterol, nonesterified fatty acids (NEFA), and TAG among normo-triglyceridemic (NTG) and mildly hypertriglyceridemic (HTG) volunteers having a range of plasma TAG concentrations. The major changes were (1) CETA increased more after ingestion of SAT and (Alcohol + SAT) in the HTG group versus the NTG group; (2) after all three challenges, elevation of plasma TAG concentration persisted longer in the HTG versus NTG group. Plasma cholesterol was not affected by the three dietary challenges, while Alcohol increased NEFA more in the HTG group than the NTG group. Plasma TAG best predicted plasma CETA, suggesting that intestinally derived lipoproteins are acceptors of HDL-CE. Unexpectedly, ingestion of (Alcohol + SAT) reduced the strength of the correlation between plasma TAG and CETA, that is the effects of (SAT and Alcohol) on plasma CETA are not synergistic nor additive but rather mutually suppressive. The alcohol-mediated inhibition of CE-transfer to chylomicrons maintains a higher plasma HDL-cholesterol concentration, which is athero-protective, although the suppressive metabolite underlying this correlation could be acetate, the terminal alcohol metabolite, other factors, including CETA inhibitors, are also likely important. 相似文献
7.
Purification,structural data and biological properties of polysaccharide from Prunus amygdalus gum 下载免费PDF全文
Fatma Bouaziz Mohamed Koubaa Claire Boisset Helbert Fatma Kallel Dorra Driss Imen Kacem Raoudha Ghorbel Semia Ellouz Chaabouni 《International Journal of Food Science & Technology》2015,50(3):578-584
This work demonstrates the efficiency of almond gum polysaccharides (AGPs) as bioactive compounds. AGPs were first extracted using H2O2, in the presence of NaOH, at different times and temperatures. The optimal extraction conditions were 4% H2O2 and 2 N NaOH, for 7 h at 50 °C, leading to an extraction yield of 58.2% (w/w). After a purification step, the retained AGPs were characterised using high‐performance liquid chromatography showing a molecular weight of 99.3 kDa. The monosaccharide composition of AGPs were assessed using gas chromatography–mass spectrometry. AGPs were found to be a complex heteropolysaccharide with a repeating unit mainly composed of galactose, arabinose, xylose, mannose, rhamnose, and glucuronic acid with the respective ratios: 45:26:7:10:1:11. The acidic nature of the polysaccharide is due to the presence of glucuronic acid. Total antioxidant activity, free radical‐scavenging activity and reducing power assay of AGPs were investigated. The obtained results showed high antioxidant activities of AGPs. Furthermore, beyond 60 mg mL?1, AGPs exhibited bacterial growth inhibition for five pathogenic strains: Escherichia coli, Staphylococcus aureus, Enterococcus feacalis, Pseudomonas aeruginosa and Salmonella typhimurium. 相似文献
8.
9.
High‐performance thermosets with tailored properties derived from methacrylated eugenol and epoxy‐based vinyl ester 下载免费PDF全文
Yuehong Zhang Yuzhan Li Vijay Kumar Thakur Zhenhua Gao Jiyou Gu Michael R Kessler 《Polymer International》2018,67(5):544-549
A renewable chemical, eugenol, is methacrylated to produce methacrylated eugenol (ME) employing the Steglich esterification reaction without any solvent. The resulting ME is used as a low‐viscosity co‐monomer to replace styrene in a commercial epoxy‐based vinyl ester resin (VE). The volatility and viscosity of ME and styrene are compared. The effect of ME loading and temperature on the viscosity of the VE–ME resin is investigated. Moreover, the thermomechanical properties, curing extent and thermal stability of the fully cured VE–ME thermosets are systematically examined. The results indicate that ME is a monomer with low volatility and low viscosity, and therefore the incorporation of ME monomer in VE resins allows significant reduction of viscosity. Moreover, the viscosity of the VE–ME resin can be tailored by adjusting the ME loadings and processing temperature to meet commercial liquid molding technology requirements. The glass transition temperatures of VE–ME thermosets range from 139 to 199 °C. In addition, more than 95% of the monomer is incorporated and fixed in the crosslinked network structure of VE–ME thermosets. Overall, the developed ME monomer exhibits promising potential for replacing styrene as an effective low‐viscosity co‐monomer. The VE–ME resins show great advantages for use in polymer matrices for high‐performance fiber‐reinforced composites. This work is of great significance to the vinyl ester industry by providing detailed experimental support. © 2018 Society of Chemical Industry 相似文献
10.