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1.
María P. Albano Liliana B. Garrido 《Journal of Materials Synthesis and Processing》2002,10(4):211-218
Si3N4powders coated with 6 wt% Y2O3and 4 wt% Al2O3were prepared by coprecipitation. The resulting powders were dispersed in water at different pH values and with addition of various amounts of ammonium polyacrylate (NH4PA) to produce 32 vol% slips. The influence of the amount of NH4PA solution added and pH on the rheological properties of 32 vol% coated Si3N4slips were studied. In addition, the sintered density of cast samples was determined and related to the degree of slip dispersion. The adsorption of the NH4PA on the coated particle surface was rather high and the surface became saturated near 0.86 mg/m2at pH 9.2. High NH4PA concentrations (1.7–3 wt%) were necessary to obtain well dispersed 32 vol% coated Si3N4slips at pH 9.2. The best stabilization was obtained with the addition of 2.3 wt% NH4PA; in this condition, the viscosity reached a minimum value of 35 mPa.s at 100 s–1. The slip viscosity increased with increasing pH from 9.2 to 10.2. Slips with low viscosities gave a more dense packing of cast samples and consequently higher sintered density values. 相似文献
2.
In this work, we examine the effect of small additions of cationic quaternary ammonium salts (QAS) of different molecular weight on the rheology of an industrial ceramic suspension deflocculated with sodium polyacrylate and sodium metasilicate. The observed shear thinning behaviors obey the typical power law of fluid rheology. In order to characterize the rheological behavior of these slurries, three new parameters are introduced: a low shear rate consistency index and two transient viscosities, distant from the equilibrium, after increasing and decreasing the shear rates. These parameters vary with polyacrylate molecular weight and on additions of small quantities of QAS, which we found to be useful for decreasing the slurry viscosity. 相似文献
3.
聚氨酯-聚丙烯酸酯共聚乳液的成膜和性能 总被引:4,自引:0,他引:4
通过XPS和接触角测试研究了聚氨酯-聚丙烯酸酯共聚乳液在不同基材上的成膜情况,并对共聚胶膜的耐水性和附着力进行了考察.由于该共聚乳液同时存在着亲水组分和疏水组分,所以它在不同的基材上成膜可导致其膜表面的组成成分不同,因而导致其耐水性和附着力也随基材而异。结果表明,亲水性的聚氨酯组分均富集于胶膜内部,但胶膜底层聚氨酯组分的含量却随基材的不同而不同。在憎水且表面张力较高的基材上,共聚胶膜的耐水性良好;共聚胶膜的附着力在表面张力较高的基材上也良好。 相似文献
4.
采用SBS、APP复合改性渣油,可以得到性能优良的改性沥青材料。其最佳配料和共混工艺条件为:SBS/(SBS+APP)之比0.4、外掺量20%、转速1930rPm、共混时间1.0 hr,共混温度20℃。 相似文献
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The solution behaviour of a new mesogenic side group polyacrylate in tetrahydrofuran and toluene has been investigated by static and dynamic light scattering. In the dilute regime the polymer behaves as typical polydisperse linear chains in good solvent and the dynamics is dominated by a single fast mode. Cluster formation was detected starting at a concentration around 50 g l−1. It seems to be independent of the solvent as well as of polymer molecular weight. In the semidilute regime, the behaviour of the reduced osmotic modulus leads to the conclusion that repulsion between the chains is stronger than in linear macromolecules. The appearance of larger clusters was revealed above a characteristic concentration and is slightly dependent on the polyacrylate molecular weight. The dynamics was generally characterised by a fast mode related to the cooperative diffusion and by a slow mode associated with large clusters. The existence of a network of multiconnected clusters is envisaged with increasing solution concentration. 相似文献
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9.
Guang Su Huang Xiang Ru He Jing Rong Wu Qi Ying Pan Jing Zhen Zhuo Hong 《应用聚合物科学杂志》2006,102(4):3127-3133
In this study, a kind of novel damping materials was prepared based on the blend of chlorinated butyl rubber (CIIR) and polyacrylate (PAc) synthesized by different molar ratio of butyl methacrylate and ethyl acrylate. Research results from experiments and analyses by employing DMA, TEM, and FTIR show that whether at a cocured system or noncocured system, it can be achieved to shift a loss peak of CIIR towards a higher temperature region and to keep the damping value from markedlly decreasing, which broadens the effective damping function area of CIIR to the vicinity of ambient temperature. In the former system, the thermodynamical miscibility of CIIR and PAc, to some extent, is predominated by the molecular design of PAc, while in the latter system, covulcanized networks play a more significant role in improving compatibility and abating the peak split, though the suppression effect of thermal stress on the transition of CIIR Tll transition still can not be neglected. Furthermore, transition state derived from the cocuring CIIR and PAc cannot make the phase separation completely take place, and consequently results in the deformation of phase morphology of the cocured CIIR/PAc blend. It is the influence of thermodynamics miscibility and forced compatibility in different size that makes the suppression effect of foreign PAc on CIIR Tll transition be controllable. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 3127–3133, 2006 相似文献
10.
本文研究广丙烯酸酯单体的共聚合反应以及交联型压敏胶带的制备过程,从而确定了最佳工艺条件,并测定了压敏胶带的老化,贮存期,可剥离等性能。 相似文献