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排序方式: 共有2328条查询结果,搜索用时 62 毫秒
1.
Yuelong Ma Le Zhang Tianyuan Zhou Bingheng Sun Chen Hou Shunshun Yang Jin Huang Rui Wang Farida A. Selim Zhongying Wang Ming Li Hao Chen Yun Wang 《Journal of the European Ceramic Society》2021,41(4):2834-2846
Ce:Y3Al5O12 transparent ceramics (TCs) with appropriate emission light proportion and high thermal stability are significant to construct white light emitting diode devices with excellent chromaticity parameters. In this work, strategies of controlling crystal-field splitting around Ce3+ ion and doping orange-red emitting ion, were adopted to fabricate Ce:(Y,Tb)3(Al,Mn)5O12 TCs via vacuum sintering technique. Notably, 85.4 % of the room-temperature luminescence intensity of the TC was retained at 150 °C, and the color rendering index was as high as 79.8. Furthermore, a 12 nm red shift and a 16.2 % increase of full width at half maximum were achieved owing to the synergistic effects of Tb3+ and Mn2+ ions. By combining TCs with a 460 nm blue chip, a warm white light with a low correlated color temperature of 4155 K was acquired. Meanwhile, the action mechanism of Tb3+ ion and the energy transfer between Ce3+ and Mn2+ ions were verified in prepared TCs. 相似文献
2.
Sergey Tkachev Miguel Monteiro João Santos Ernesto Placidi Mohamed Ben Hassine Pedro Marques Paulo Ferreira Pedro Alpuim Andrea Capasso 《Advanced functional materials》2021,31(33):2103287
Graphene-based materials have attracted significant attention in many technological fields, but scaling up graphene-based technologies still faces substantial challenges. High-throughput top-down methods generally require hazardous, toxic, and high-boiling-point solvents. Here, an efficient and inexpensive strategy is proposed to produce graphene dispersions by liquid-phase exfoliation (LPE) through a combination of shear-mixing (SM) and tip sonication (TS) techniques, yielding highly concentrated graphene inks compatible with spray coating. The quality of graphene flakes (e.g., lateral size and thickness) and their concentration in the dispersions are compared using different spectroscopic and microscopy techniques. Several approaches (individual SM and TS, and their combination) are tested in three solvents (N-methyl-2-pyrrolidone, dimethylformamide, and cyrene). Interestingly, the combination of SM and TS in cyrene yields high-quality graphene dispersions, overcoming the environmental issues linked to the other two solvents. Starting from the cyrene dispersion, a graphene-based ink is prepared to spray-coat flexible electrodes and assemble a touch screen prototype. The electrodes feature a low sheet resistance (290 Ω □−1) and high optical transmittance (78%), which provide the prototype with a high signal-to-noise ratio (14 dB) and multi-touch functionality (up to four simultaneous touches). These results illustrate a potential pathway toward the integration of LPE-graphene in commercial flexible electronics. 相似文献
3.
Zhongchao Fu Xiaodong Li Mu Zhang Qi Zhu Ji-Guang Li Jiao He Xing'an Wang Xudong Sun 《Journal of the American Ceramic Society》2021,104(6):2689-2701
An easy albeit quite effective deionization suspension treatment was adopted to alleviate the detrimental effects related to the hydrolysis of Y2O3 in an aqueous medium. Fabrication of highly transparent Y2O3 ceramics with a fine grain size via air pre-sintering and post–hot isostatic pressing (HIP) treatment without using any sintering additive was achieved using the treated suspensions. The hydrolysis issue of Y2O3 powder in an aqueous medium was effectively alleviated by using deionization treatment, and a well-dispersed suspension with a low concentration of dissolved Y3+ species was obtained. The dispersed suspensions were consolidated by the centrifugal casting method, and the green bodies derived from the suspension of 35.0 vol% solid loading showed an improved homogeneity with a relative density of 52.1%. Fully dense Y2O3 transparent ceramic with high transparency was obtained by pre-sintering consolidated green compacts at a low temperature of 1400°C for 16 h in air followed by a post-HIP treatment at 1550°C for 2 h under 200 MPa pressure. The sample had a fine average grain size of 690 nm. The in-line transmittance of the sample reached 83.3% and 81.8% at 1100 nm and 800 nm, respectively, very close to the theoretical values of Y2O3. 相似文献
4.
Pengyu Xu Hao Wang Wenjun Cui Qiangguo Chen Bingtian Tu Xiahan Sang Weimin Wang Zhengyi Fu 《Journal of the American Ceramic Society》2022,105(6):3735-3739
Here we report a transparent dual-phase ZnO·2.7Al2O3 ceramic. The composite is pore-free and consists of thin nanosheets with a spinel phase and a hexagonal phase, while the two phases match closely in both lattice and refractive index. Such features result in excellent optical transmittance (maximum value >80% in the visible spectrum) at comparable phase volume. This work may provide a new thought for the rational structural design of optical nanocomposites. 相似文献
5.
6.
Rufei Chen Wenyan Duan Gong Wang Bingshan Liu Yantong Zhao Shan Li 《Journal of the European Ceramic Society》2021,41(11):5495-5504
Wave-transmitting materials are a kind of multi-functional materials that protect the normal operation of communication and guidance systems of spacecraft in harsh environments. In this paper, we fabricate a broadband microwave transparent Si3N4-SiO2 composite ceramic with excellent performance through digital light processing (DLP) 3D printing technology. The influences of sintering temperature on the weight increase rate, density, dimensional shrinkage, phase composition, microstructure, bending strength and dielectric properties of Si3N4-SiO2 ceramic were all systematically studied. The strength of Si3N4-SiO2 ceramic sintered at 1350 ℃ was 77 ± 5 MPa. The relative permittivity of the ceramic is within the range of less than 4, and the loss tangent can be below 0.003. The 3D printed Si3N4-SiO2 ceramic material exhibited excellent wave-transparent performance. 相似文献
7.
Liangkai Liu Qihua Zhu Qiangqiang Zhu Benxue Jiang Minghui Feng Long Zhang 《Ceramics International》2019,45(5):5339-5345
Y2O3 ceramic is a promising optical material for mid-infrared (IR) windows and domes. Improvements in the mechanical and thermal performance of this material have become urgent if it is to perform adequately under extreme conditions. Herein, Y2O3 nanopowders were produced through the nitrate pyrogenation method. The final Y2O3 transparent ceramics were fabricated with a hybrid sintering method combining low temperature presintering and a subsequent hot isostatic pressing (HIP) treatment. The synthesis of nanopowders and the fabrication of the final ceramic products were investigated in detail. The Y2O3 ceramic sample that was presintered at 1350?°C provided the optimum microstructure for HIP treatment and resulted in an average grain size of 0.5?µm. Owing to the reduced grain size, the flexure strength and Vickers hardness of the sample were improved to 180?MPa and 8.4?GPa, respectively. Furthermore, the achieved pure Y2O3 ceramic demonstrated an excellent thermal conductivity at high temperature. 相似文献
8.
In this article, isocyanate was adopted to modify Y2O3 powder for the purpose of preparing transparent Y2O3 ceramics via gel casting. The modification could enhance the hydration resistance of Y2O3 powder through the steric hindrance effect. The coating mechanism can be proved by the infrared spectrum of the surface-modified Y2O3 powder. Modification could not only prevent Y2O3 particles from reacting with water, but also prevents agglomeration between particles. The viscosity of the slurry with a solid content of 52.7 vol% is only 0.48 Pa·s at the shear rate of 100 s−1, which is suitable for preparing high-density compacts by gel casting. The transmittance of the sample (1840°C × 8 h, 1 mm thickness) at 1100 nm reaches 75%. The microstructure of the sintered body is dense with the average grain size of 6.5 μm without obvious impurities nor pores. Five mol% ZrO2-doped Y2O3 transparent ceramic fairing with the diameter of 5 cm without defects was successfully fabricated by gel casting (52.7 vol% solid volume) and vacuum sintering (1840°C × 8 h). 相似文献
9.
Yongqiang Zhang Zhiwei Zhou Weiwei Li Yu Yang Bingchu Mei Zaichun Sun 《Journal of the American Ceramic Society》2022,105(4):2932-2944
Nd3+ doped strontium fluorophosphate (S-FAP), with chemical formula Sr5(PO4)3F, nanopowders were prepared using the co-precipitation method. The prepared powders had no impurity phase with a grain size of about 30 nm and the doping limit of Nd3+ ions in strontium fluorophosphate is about 9 at.%. The morphology and particle size were determined by the doping concentration of Nd3+. Anisotropic Nd: S-FAP transparent ceramics with different Nd3+ doping concentrations were fabricated successfully by the simple hot-pressing method. The grain size of prepared S-FAP transparent ceramics decreased first and then increased with the increase of Nd3+ concentration. The 2 at.% Nd: S-FAP ceramic presented the highest optical transmittance at all wavelengths range. The characteristic transitions from the ground state to the excited states of Nd3+ ions were observed from the absorption spectra, and the absorption cross-section was calculated at 3.71 × 10–20 cm2. The influence of Nd3+ ion concentration on luminescence intensity and fluorescence lifetime was studied under 796 nm excitation. The strong emission of 4F3/2→4I9/2 transition in Nd: S-FAP was calculated by Judd–Ofelt (J-O) theory. 相似文献
10.
Qiang Liu Xinyu Mao Xiaoying Li Penghui Chen Xin Liu Ziyu Liu Danyang Zhu Haohong Chen Tengfei Xie Jiang Li 《Journal of the American Ceramic Society》2021,104(10):4927-4931
0.5 at.% Cr:ZnGa2O4 precursor was synthesized by the co-precipitation method with nitrates as raw materials, using ammonium carbonate as the precipitant. Low-agglomerated Cr:ZnGa2O4 powders with an average particle size of 43 nm were obtained by calcining the precursor at 900℃ for 4 h. Using the powders as starting materials, 0.5 at.% Cr:ZnGa2O4 ceramics with an average grain size of about 515 nm were prepared by presintering at 1150℃ for 5 h in air and HIP post-treatment at 1100℃ for 3 h under 200 MPa Ar. The in-line transmittance of 0.5 at.% Cr:ZnGa2O4 ceramics with a thickness of 1.3 mm reaches 59.5% at the wavelength of 700 nm. The Cr:ZnGa2O4 ceramics can be effectively excited by visible light and produce persistent luminescence at 700 nm. For Cr:ZnGa2O4 transparent ceramics, the brightness of afterglow was larger than 0.32 mcd/m2 after 30 min, which is far superior to that of Cr:ZnGa2O4 persistent luminescence powders. 相似文献