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以浸渍法模拟碱金属中毒NH3-SCR催化剂过程,制备不同Na含量(质量分数)的铜基小孔分子筛Cu/SSZ-13和Cu/SAPO-34,对比研究了二者的碱金属中毒机理。结果表明,外引Na离子均可严重影响两种催化剂的NH3-SCR催化活性,造成催化剂的晶相结构坍塌,酸性量减少,活性物种减少。不同的是,Na引入量较低(<1.82%)时,Cu/SAPO-34比Cu/SSZ-13具有更强的Na离子耐受性,而当Na含量高于3.48%时,Cu/SAPO-34几乎完全丧失NH3-SCR催化活性。通过催化剂的结构表征(BET、XRD和SEM)和酸性位表征(DRIFTS、NH3-TPD和H2-TPR),研究表明随着Na中毒程度的加深,Cu/SSZ-13的结构破坏是渐变式的,而Cu/SAPO-34的结构破坏是突变式的;Na中毒的机理研究表明,酸性位的减少是Cu/SSZ-13的SCR活性下降的主导原因,结构坍塌是Cu/SAPO-34的SCR活性下降的主导原因。 相似文献
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In the purification process of automobile exhaust,existing water plays an important role as an oxidant,which converts CO and hydrocarbons(HCs) by the water-gas shift(WGS) and the steam reforming(SR) reactions,respectively,especially at high temperatures.Meanwhile it is major component of the exhaust which can affect significantly the thermal stability of the three-way catalyst.Activity experiments were carried out close to the real operation conditions(GHSV,concentration,etc.) with a Pd/Ce0.67Zr0.33O2 catal... 相似文献
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NeNOx催化剂研究进展 总被引:1,自引:0,他引:1
氮氧化物的脱除是治理空气污染的一大难题。选择性催化还原、非选择性催化还原及催化分解是目前研究较多的脱除氮氧化物的方法。本文介绍了这3类催化剂的研究历史、现状及应用前景。 相似文献
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采用浸渍法制备负载金属Pd(其中金属Pd含量0.6g/L)活性组分的金属蜂窝载体催化剂,应用于甲烷部分氧化制合成气。实验表明,焙烧温度为950℃的催化剂较600℃的催化剂甲烷转化率、CO和H2的选择性更高,焙烧温度为950℃的催化剂在反应温度800℃,GHSV=1×105ml/g·h条件下,甲烷转化率为91%,CO和H2的选择性分别达到90%和89%。用SEM与XPS对催化剂进行表征,结果表明,950℃焙烧催化剂并没有出现明显的烧结现象,且可能由于更多零价Pd的出现,使得该催化剂的性能更好。由于金属蜂窝载体优良的导热性,对950℃焙烧温度制备的金属蜂窝催化剂,催化剂床层的飞温点温度小于880℃,可以解决其它类型催化剂在甲烷部分氧化反应中出现的飞温问题,具有一定的工业化意义。 相似文献
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Catalytic Activity of Ceria-Zirconia Nanostructured Materials Prepared via Reversed Microemulsion Method 总被引:1,自引:1,他引:1
CeO2-ZrO2mixed oxides have a number of i mpor-tant catalytic applications[1].They are extensively em-ployed in current automotive three-way catalysts(TWCs)as the oxygen storage promoters,i.e.materi-als that regulate the oxygen partial pressure throughtheC… 相似文献
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Ceria-zirconia-alumina (CZA) solid solution was prepared by sol-gel method in the present study. 0.5 wt.% Pd supported on CZA was prepared by incipient wetness impregnation. The steam effects for CO and C3H8 oxidation, three-way catalytic activity and stoichiometric window property were studied. The light-off temperature of the CO oxidation reaction shifted to a lower temperature due to the water-gas shift (WGS) reactions. The oxidation of C3H8 was enhanced due to the steam reforming (SR) reactions. The steam promoted the C3H8 oxidation and NO reduction in three-way catalytic reaction. The amplitude of stoichiometric window was amplified by the addition of water to the feed stream. 相似文献
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用草酸盐共沉淀法 ,结合不同干燥条件 ,得到了氧空位较多的纳米晶 La Co O3钙钛矿。用正电子湮没寿命谱研究了氧空位较多的纳米晶 La Co O3催化剂的界面结构。结果表明 :纳米晶 La Co O3的聚集体微结构主要由两部分组成——含有氧空位的结晶晶粒以及晶界表面 ,基本上不存在由多个晶粒围成的大孔穴。不同的干燥条件可制备得到不同晶粒度和不同大小氧空位的 La Co O3钙钛矿 相似文献