Complete oxidation of methane at low temperature over Pt and Pd catalysts for the abatement of lean-burn natural gas fuelled vehicles emissions: influence of water and sulphur containing compounds

The catalytic activity of fresh Pd and Pt catalysts supported on γ-alumina in the complete oxidation of CH₄ traces under lean-burn conditions was studied in the presence or the absence of water or H₂S. Steam-aged catalysts were also studied in order to simulate long-term ageing in real lean-burn natural gas fuelled vehicles (NGVs) exhaust conditions. Without water or H₂S added to the feed, Pd catalysts exhibit a superior catalytic activity in methane oxidation compared to Pt ones, whatever the catalysts were fresh or aged. The addition of 10 vol.% water vapour to the feed strongly affects the activity of the fresh Pd catalyst, thus being only slightly more efficient than the fresh Pt one. H₂S has a strong poisoning effect on the catalytic activity of Pd catalysts, while Pt catalysts are more resistant. The fresh H₂S-poisoned Pd/Al₂O₃ catalyst was studied by TPD in O₂/He. Poisoning species decompose above 873 K as SO₂ and O₂ in relative concentrations consistent with the decomposition of surface sulphate species. However, a treatment in O₂/He at temperatures as high as 923 K does not allow the complete regeneration of the catalytic activity of H₂S-poisoned Pd/Al₂O₃. A mechanism involving the poisoning of PdO by sulphate species is proposed. Different diffusion processes by which these sulphate species can migrate back and forth between PdO and the support, depending on the experimental conditions, are suggested.     

石油系油浆与煤系闪蒸油的焦化性能——I．热解条件的影响

通过偏光显微镜观察了石油系油浆（LH）与煤系闪蒸油（SN）焦化后所得焦块的光学结构。结果表明，在较宽条件下两种原料单独焦化均得不到取向度高的流线型结构。将两种原料以一定比例混合后先热解丙焦化所得焦块的光学结构明显好于二者混合后直接焦化所得焦块的光学结构，其中LH和SN以3：2的重量比混合后在440℃、1MPa下热解3．5h然后再在530℃、1MPa下焦化8h所得焦块为具有较高取向度的流线型结构，适合于作为针状焦的起始原料。     

Site occupations and ordering behaviour of O phase in Ti2AlNb—based intermetallics

1　ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｏｒｔｈｏｒｈｏｍｂｉｃａｌｌｏｙｓａｒｅｏｆｇｒｅａｔｔｅｃｈ ｎｏｌｏｇ ｉｃａｌｉｎｔｅｒｅｓｔｉｎｈｉｇｈｔｅｍｐｅｒａｔｕｒｅａｐｐｌｉｃａｔｉｏｎｓｓｉｎｃｅｔｈｅｙｈａｖｅａｇｏｏｄｂａｌａｎｃｅａｍｏｎｇｓｔ     

酸增殖源及其在化学增幅抗蚀剂体系中的应用

介绍了酸增殖机理、酸增殖源的种类、典型化合物在化学增幅抗蚀剂体系中的应用及对灵敏度的提高 ,提出在计算机直接制版版材研究中的应用     

Defining syntax-directed translations by tree bimorphisms

We introduce a class of tree bimorphisms that define exactly the translations performed by syntax-directed translation schemata. We also show that these “quasi-alphabetic” tree bimorphisms preserve recognizability, and that their class is closed under composition and inverses.     

南京河西地区软土场地地震动参数研究

根据南京河西地区所处的地震地质环境、地震活动环境及基岩地震动衰减规律 ,对所选取的某个典型工程软土场地 ,进行了地震危险性分析 ,给出了基岩地震动参数 ;对场地的地震动效应进行了研究 ,给出了 5 0a及10 0a超越概率水平为 6 3%、10 %和 3%的场地地震动参数。该成果对河西地区的工程抗震设计有一定的参考价值     

基于Agent的遗传算法描述与演化模型研究

Agent是指具有智能的人或其它智能物.它具有自治、反响、推测、协作、自学习和相互学习等能力,本文基于Darwin自然进化论与Mendel遗传变异理论,给出Agent的遗传算法与演化模型.这些理论的提出,进一步丰富和完善了Agent的研究内容.     

纳米酶在食源性微生物检测中的应用进展

食源性微生物污染物分布广泛存在于各种食物中,所造成的食品安全问题直接威胁着人类的健康。纳米酶是新一代人工合成酶,因其既具备纳米材料的比表面积大、活性位点多、吸附能力强等特点,又兼具天然酶的高催化性能,并且还有稳定性高、易于表面修饰、生物兼容性好等诸多优点,使得其在杀菌抗炎、环境治理、分析检测、绿色合成等领域受到越来越多的关注。利用比色,拉曼,电化学等多种传感测试手段,结合纳米酶的高催化性能,可将微弱的检测信号放大,从而实现低含量组分的现场快速测定。随着人们对纳米酶催化性能与结构之间的关系研究的深入,越来越多的功能性纳米酶被相继开发,必将带动高效快速检测技术的发展。本文综述了近年来基于纳米酶的食源性微生物的传感策略的最新进展,着重于不同类型纳米酶的检测机制以及在食源性微生物检测方面的研究现状,并探讨了其未来可能的发展方向,为基于纳米酶的食源性微生物传感设计提供理论依据,为相关技术的发展提供新思路。     

结合继电保护定期检验浅谈对状态检修的认识和看法

根据继电保护运行和维护特点，结合运城供电系统当前实际情况，分析了二次设备状态检修的各种问题并提出相应采取的措施。     

一体式活塞内模结构设计及应用

采用一体式内模代替原来的两体式内模铸造模具,简化了模具制造工艺、节约了制造成本、美化了活塞内腔。利用Magma软件模拟浇注,发现一体式内模容易出现的缺陷以及缺陷存在的位置,并提出有效的解决方法。通过在小缸径活塞上的实际应用,取得了良好的效果。