D999系列新功能树脂分离铂铼的研究

考察D999系列新功能树脂分离铂和铼的性能.试验表明,D999树脂在中弱酸性介质中能有效吸附铂铼,而在3mol/L以上的强酸性介质中基本不吸附铼,尚可吸附铂,铂和铼的分离因数达100以上.也可以先在适度酸性介质同时吸附铂和铼,然后采用不同的淋洗剂分步淋洗铂与铼.     

Synthesis and luminescence properties of a novel red Sr3Bi（PO4）3：Sm^3＋ phosphor

A series of Sr3Bi1-x(PO4)3: xSm3+phosphors were prepared by solid state method at 1250 °C for 4 h. X-ray diffraction (XRD) indi-cated that the sample was of a pure phase of Sr3Bi(PO4)3. The main excitation peaks were located at 343 (6H5/2→4H9/2), 360 (6H5/2→4D3/2), 373 (6H5/2→6P7/2), 400 (6H5/2→4F7/2), 414 (6H5/2→6P5/2) and 467 nm (6H5/2→4I13/2). The main emission were located at 563 (4G5/2→6H5/2), 599 (4G5/2→6H7/2), 646 (4G5/2→6H9/2) and 708 nm (4G5/2→6H11/2). The intensest emission was excited by 400 nm. We studied the effect of differ-ent doping concentrations of Sm3+ activator on the luminescence properties and found that the luminescent intensity first increased with Sm3+ concentration increasing, and then decreased. The luminescent intensity had the best value when x=0.04. The chromaticity coordinates of the sample Sr3Bi0.96(PO4)3:0.04Sm3+ were (x=0.57, y=0.36), and the lifetime was 2.12 ms.     

用AI-9吸附剂从盐湖卤水中吸附锂的试验研究

研究了用AI-9吸附剂从盐湖卤水中吸附锂,考察了卤水温度、卤水中锂离子质量浓度、接触时间、进液方式对锂吸附率的影响以及吸附剂的破碎情况。试验结果表明:在卤水温度20℃、卤水中锂离子质量浓度较高(350mg/L)条件下,吸附接触10min,卤水以上进液方式运行,吸附剂的工作容量和工作效率都较高,且破碎率较低,可以满足从盐湖卤水中提取锂的工业生产要求。     

Eu^2＋在KCaPO4中的发光及晶体学格位

采用高温固相法制备了KCaPO4：Eu^2＋蓝绿色荧光粉,研究了材料的发光特性。在400 nm近紫外光激发下,材料呈非对称的单峰发射,主峰位于487 nm。监测487 nm发射峰,对应的激发光谱覆盖300-450 nm,说明材料能够很好的吸收紫外-近紫外光,发射蓝绿色光。利用van Uitert公式计算了Eu^2＋取代...     

KCaPO4:Tb3+绿色荧光粉的发光特性

采用高温固相法合成了KCaPO4:Tb3+绿色荧光粉,并研究了材料的发光性质.KCaPO4:Tb什材料呈多峰发射,发射峰为437、490、545、587和623nm,分别对应Tb3+的5D3→F4和5D4→FJ=615,4,3跃迁发射,主峰为545nm;监测545nm发射峰,所得激发光谱由4f7 5d1宽带吸收(200...     

AZ91D镁合金铸态组织三维重构

通过连续切片技术获得AZ91D镁合金两块区域各80张金相照片,对所得图片进行去除污渍、二次化、旋转对齐等初步处理后,分别使用ImageJ和Mimics软件重构其三维组织,了解其组织结构特点。从重构后的AZ91D镁合金三维组织形貌可以看出,初生相α-Mg含量较高,其他相含量相对较低,测量结果与试验基本符合。     

有机电致发光器件各层厚度对色坐标的影响

采用真空蒸镀法制备了不同厚度的双层有机电致发光器件,器件结构为ITO/NPB/Alq3/Al。测得不同厚度的有机电致发光器件的色坐标,发现随有机层厚度值的增加,发光器件的色坐标x值增大,y值减小。为解释此现象,从光传输角度出发利用光传输矩阵理论分析了光从激发到射出器件的光耦合输出过程,建立了光输出模型并得出色坐标变化的原因是厚度变化引起相位的变化,从而影响了传输矩阵,这样透射率会随传输矩阵的改变而改变,色坐标的计算又与透射率有关,最终使色坐标发生改变。     

Fabrication and luminescent properties of red phosphor M3BO6:Eu3+（M=La,Y）

A series of red phosphors M3BO6:Eu3+(M=La,Y) were synthesized at 1150 oC by conventional solid state reaction method and their luminescent properties were investigated.Structural characterization of the luminescent materials was carried out with X-ray powder diffraction(XRD) analysis.Photoluminescence measurements indicated that the La3BO6:Eu3+ phosphor exhibited bright red emission centered at about 612 nm 626 nm under UV excited.La3BO6:Eu3+ phosphor had better luminescent intensity than Y3BO6:Eu3+ phosphors under the same excitation and measuring conditions.It was shown that the 0.08 mol.% Eu3+ ions in La3BO6:Eu3+ phosphors was optimal.The color parameter indicated that La3BO6:Eu3+ phosphor was a preferable red phosphor for white LED.     

硫脲用量对燃烧法制备的Y_2O_2S:Sm~(3+)发光性能的影响(英文)

利用硫脲作为燃料(fuel,F),以Sm(NO3)3·6H2O,Y(NO3)3·6H2O为氧化剂(oxidizer,O),通过燃烧法制备了白光发光二极管用Y2O2S:Sm3+红色荧光粉,并研究了其发光性能以及硫脲用量等反应条件对发光性能的影响.X射线衍射结果表明:当燃料与氧化剂的摩尔比[n(F)/n(O)]为2.0～4.0时,通过燃烧法可合成纯相Y2O2S.n(F)/n(O)的值对样品的反应速度和反应温度有很大的影响.扫描电镜结果表明:当n(F)/n(O)为3.0时,可以得到粒度和发光强度较好的Y2O2S:Sm3+荧光粉.测量了Sm3+离子摩尔分数为3%时的激发光谱和发射光谱.样品的激发光谱由1个宽带和一系列的尖峰组成,其中位于412nm和468nm处的激发峰最强.发射光谱由3个发射带组成,其中发射主峰分别位于570nm,606nm和658nm.这表明Y2O2S:Sm3+可被波长为412nm的紫光和468nm的蓝光有效的激发并发出红光.