不同相组成铸态Mg-xLi-1Al合金的阻尼性能(英文)

采用真空熔炼法制备三种不同相态的Mg-xLi-1Al三元合金,并使用光学显微镜、X射线衍射分析及动态力学分析仪研究其显微组织及阻尼性能。结果表明:由于锂含量的增加,合金的相结构发生转变且出现新的阻尼机制,其中BCC结构的出现使阻尼性能显著提高,同时弹性模量的减小也使临界应变振幅值降低。两相共存状态的合金随温度变化表现出较高的阻尼现象,并在低温与高温区均出现两个较为明显的峰值,其中低温区的P1峰是位错阻尼峰,高温区的P2峰是晶界阻尼峰。     

球磨工艺参数对MgNi非晶合金形成及性能的影响

通过机械合金化法制备了MgNi非晶合金,利用X射线衍射分析了非晶相的形成情况,并对其储氢性能和电化学性能进行了测试.对球磨工艺参数与合金微观结构及性能之间关系进行分析,结果表明,球磨机转速对MgNi非晶相的形成效率具有十分重要的影响,随着转速的增加,MgNi非晶相的形成时间大大缩短.随着球磨时间的延长,MgNi非晶相的形成趋于完全,粉末的粒径逐渐减小,粒度分布也较为均匀,但形成完全非晶后继续球磨过长时间会降低Mg-Ni合金的吸放氢性能和电化学性能.     

轧制对Mg-3Cu-1Mn合金温度阻尼峰的影响(英文)

经过变形量4.7%的单道次室温轧制变形,Mg-3Cu-1Mn合金的一次温度—阻尼谱出现了3个明显的阻尼峰;在二次温度—阻尼谱中,3个阻尼峰均发生变化,特别是第3阻尼峰P3受到抑制,变得非常不明显。对各阻尼峰峰温处淬火样品进行金相、XRD、EBSD等实验,研究轧制对Mg-3Cu-1Mn合金温度—阻尼峰的影响。结果表明:在一次温度—阻尼谱中的P3峰处出现织构增强、孪晶急剧消失的现象;轧制变形后,3个温度—阻尼峰依次为位错阻尼峰、晶界阻尼峰和孪晶引发的再结晶阻尼峰;另外,随着拉伸孪晶的消失,室温轧制态Mg-3Cu-1Mn合金的应变阻尼性能大幅度恢复,高应变下接近均匀化退火态Mg-3Cu-1Mn的应变阻尼性能。这说明拉伸孪晶对Mg-3Cu-1Mn合金应变阻尼性能有不利的影响。     

深过冷Ni-P共晶合金凝固组织的形成和转变

采用玻璃熔覆法使Ni—P共晶合金实现了深过冷。随着过冷度的增加，其凝固组织发生了一系列的变化：晶粒逐渐细化，凝固组织从规则棒状共晶向异常粒状共晶组织转化，最后得到显微结构细小的胞状共晶团组织。利用单相枝晶状共晶的熔断模型，解释了过冷熔体形成异常粒状共晶团的形成原因。熔体在深过冷条件下形成的胞状共晶组织则可以固／液界面稳定性理论来描述。     

Formation and crystallization of bulk Pd_(82)Si_(18) amorphous alloys

1　INTRODUCTIONMetallicglassisregardedasastatethatisofdis orderunlikecrystalalloyswith periodicatomstruc ture.Soitshowsexcellentcapabilitiesofsoftmag netism ,mechanics ,corrosionresistance ,etc .How ever ,mostofamorphousalloyswereproducedbyus ingrapidsolidificationmethodssuchassplatquench ing ,meltspinning ,andsoon ,withcharacteristiccoolingratesof 10 4 10 6 K/s .Becauseamorphousal loysarepreparedwithsilk ,powderandribbon ,itisgreatlylimitedinengineeringapplication .Recently ,severalbulk…     

预退火时间对Pd40Cu30Ni10P20玻璃转变及晶化的影响

采用示差扫描量热(DSC)分析方法,测定了大块非晶合金Pd40Cu30Ni10P20经523 K((Tg-100 K)＜7＜Tg)不同时间(0～64 h)预退火后的玻璃转变温度7g、玻璃转变峰温度TM、起始晶化温度Tx、晶化峰的峰温Tp、晶化焓以及在玻璃转变过程中的比热容增量,并根据Kissinger公式计算了晶化的表观活化能.同时,测量了不同时间预退火后样品的显微硬度.结果表明:在玻璃转变温度以下的预退火处理使Pd40Cu30Ni10P20大块非晶合金的微观原子组态发生变化,从而影响了其随后的玻璃转变行为,但对晶化的影响不大.其显微硬度随预退火时间的延长而逐步增加后趋于稳定.并利用结构弛豫理论分析了预退火对玻璃转变、晶化和显微硬度的影响.     

热处理对AZ61镁合金力学性能和阻尼性能的影响

能的影响规律.     

Ti和Si在Zr_(55)Cu_(30)Al_(10)Ni_5大块金属玻璃中的原子扩散行为

采用二次离子质谱仪(SIMS)研究了Ti和Si原子在Zr55Cu30Al10Ni5大块金属玻璃(BMG)中的扩散行为,发现在玻璃转变温度Tg上下,其扩散系数的温度关系均分别符合同一Arrhenius关系式,表明玻璃转变并未引起扩散机制的变化。而且小原子Si比大原子Ti的扩散系数高约0.5～1个数量级,但其扩散激活能Q却相差不多,这是由于Si原子虽然原子半径较小,但它作为非金属元素与基材中的金属原子结合力较强,从而使得扩散激活能也较大。     

Influence of impurities on microstructure and mechanical properties of ZK60 magnesium alloy

The influence of impurity content on the microstructure and mechanical properties of ZK60 magnesium alloys was investigated by optical microscopy, scanning electron microscopy and tensile test. ZK60 alloys were prepared by changing holding time of alloy melt during semi-continuous casting in order to control the content of impurity elements. The alloy with lower purity content is found to have less second precipitates and larger grain size in the as-cast state. However, in the as-extruded state, reducing impurities brings about a decrease in grain size and an increase in yield strength from 244 MPa to 268 MPa, while the elongations in the as-extruded alloys with different contents of impurities are almost the same. After T5 treatment, impurity content is found to have more obvious effect on the yield strength of ZK60 alloy. The yield strength of ZK60-45 alloys with low impurity content is increased up to 295 MPa after T5 treatment.     

Influence of impurities on damping properties of ZK60 magnesium alloy

The influence of impurities on damping capacities of ZK60 magnesium alloys in the as-cast, as-extruded and T4-treated states was investigated by dynamically mechanical analyzer at room temperature. Granato and Lucke dislocation pinning model was employed to explain damping properties of the alloys. It is found that reducing impurity content can decrease the amount of second-phase particles, increase grain size and improve damping capacity of the as-cast alloy slightly. The as-extruded alloy with lower impurity content is found to possess obviously higher damping capacity in the relatively high strain region than that with higher impurity concentration, which appears to originate mainly from different dislocation characteristics. The variation tendency of damping property with change of impurity content after solution-treatment is also similar to that in the as-extruded and as-cast states. Meanwhile, the purification of the alloy results in an evident improvement in tensile yield strength in the as-extruded state.