Upconversion nanoparticles: Recent strategies and mechanism based applications

Upconversion nanoparticles (UCNPs) doped with lanthanides can convert near-infrared excitation into UV and visible emissions. Because of their relatively high emission efficiency, UCNPs are appealing materials for use in a variety of sectors. UCNPs are known for low auto-fluorescence, excellent chemical and thermal photo-stability, deep tissue penetration, exceptional biocompatibility, low toxicity, color purity, and ease of surface functionalization. In this review, we explain a few recent strategies to boost the efficiency and luminescence of upconversion nanoparticles and minimize quenching by fabricating them as core/shell, nanofibers, or heavily doped lanthanides. Applications of UCNPs in drug delivery, Photodynamic therapy (PDT), biosensors, bioimaging, and optogenetics are also discussed along with their mechanism of action. Our motivation for this review is to understand the working mechanism of UCNPs and their applications in various fields.     

Structural-microstructural characterization and optical properties of Eu3+,Tb3+-codoped LaPO4·nH2O and LaPO4 nanorods hydrothermally synthesized with microwaves

Rhabdophane-type Eu³⁺,Tb³⁺-codoped LaPO₄·nH₂O single-crystal nanorods with the compositions La_0.99999-xEu_xTb_0.00001PO₄·nH₂O (x?=?0–0.03), La_0.99999-yTb_yEu_0.00001PO₄·n′H₂O (y?=?0–0.010), and La_0.99999-zTb_zEu_0.000007PO₄·n′′H₂O (z?=?0–0.012) were hydrothermally synthesized with microwaves. It is shown that the Eu³⁺,Tb³⁺ codoping does not affect the thermal stability of these nanorods, which is due to the formation of substitutional solid solutions with both Eu³⁺ and Tb³⁺ replacing La³⁺ in the crystal lattice. Moreover, it is also shown that monazite-type Eu³⁺,Tb³⁺-codoped LaPO₄ single-crystal nanorods can be obtained by calcining their rhabdophane-type Eu³⁺,Tb³⁺-codoped LaPO₄·(n,n′ or n′′)H₂O counterparts at moderate temperature in air, and that they are thermally stable. It is also observed that, for the same Eu³⁺,Tb³⁺-codoping content, the monazite-type Eu³⁺,Tb³⁺-codoped LaPO₄ nanorods exhibit higher photoluminescent efficiency than the rhabdophane-type Eu³⁺,Tb³⁺-codoped LaPO₄· (n,n′ or n′′)H₂O nanorods. Moreover, it is found that the highest photoluminescence emission corresponds to the monazite-type La_0.96999Eu_0.02Tb_0.00001PO₄ nanorods for the La_0.99999-xEu_xTb_0.00001PO₄ system. However, for those compositions energy transfer from Tb³⁺ to Eu³⁺ does not occur. In addition, for an efficient energy transfer to occur, a content of at least 1?mol% Tb³⁺ is needed in all the studied materials.     

Lignin solvated in zwitterionic Good's buffers displays antibacterial synergy against Staphylococcus aureus

The volume of industrial lignin is expected to increase with the deployment of biorefineries that convert lignocellulosic biomass to renewable chemicals and fuels. Interest in using lignin for value-added biomedical applications requires understanding of its effects on mammalian and microbial cells, which has been impaired by the toxicity of the solvents used to solubilize lignin. In this study, lignin is solvated in zwitterionic Good's buffers compatible with culture media. Up to 100 mg lignin can be solvated in 1 ml of 3-morpholinopropane-1-sulfonic acid (MOPS, pH 7.2) within 60 min at room temperature, whereby MOPS acts as a chaotropic agent. The addition of MOPS-solvated lignin to cultures of Staphylococcus aureus UAMS-1 containing a subinhibitory concentration of tunicamycin reduced growth more than 99% compared to tunicamycin alone, making lignin of interest as an antibiotic adjuvant. This effect of lignin is attributed to damage to the bacterial cell membrane.     

Emerging applications of nanotechnologies to probiotics and prebiotics

Fervid interests on nanoparticles are increasing within the scientific and non-scientific communities, as they are utilised in food and non-food applications. The versatility of emerging applications of nanoparticles makes them potentially harmful to the food, healthcare and environment sectors, and thus necessitates the development of nanonutraceuticals from nutritional substances such as antioxidants, vitamins, fatty acids, fibres, probiotics and prebiotics. This review excavated state of the art on nanotechnology applications such as gold and selenium particles, nanolayers, nanobeads, nanoemulsions and nanofibers to probiotics and prebiotics for the synthesis of anticancer, antimicrobial, antioxidant and photo-reactive products among others, and finally delved into other noteworthy considerations like safety. It is concluded that available literature on the current status of nanoprobiotics and prebiotics are exhaustive, despite their huge potentials and applications.     

Innovative conductive polymer composite coating for aircrafts lightning strike protection

A new kind of high electrical conductive epoxy coating with low filler rate was investigated for lightning strike protection (LSP) of carbon fiber reinforced polymer (CFRP). The coating without CFRP substrate was firstly studied. The influence of silver submicronic wires (AgSWs) with a high aspect ratio on the electrical behavior is observed; that is, the electrical resistivity evolution, the current density value, and the electrical conduction mechanisms as function of temperature. The preponderant electrical conduction mechanism is an Ohmic behavior. The higher level of conductivity obtained is 5.5 × 10⁵ S m⁻¹ for 9% vol of AgSWs. Lightning strike tests were carried out on an epoxy/AgSWs coating filled with 8% in volume (74 gsm) and deposited on a CFRP. The ultrasonic testing after lightning strike on coated CFRP shows no structural delamination and demonstrates the interest of this new route for an efficient LSP. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 137, 48700.     

Graphene standardization: The lesson from the East

How do scientific ideas become market products? There is probably no single pathway for such transformation. And yet, there are certain similarities in the way how advanced materials evolve from laboratory studies to being used in technology. Common steps in such progress are the enhancement of useful properties, development of the production methods, creation of industrially-relevant modification of the material itself and its fabrication process. The reason in the emergent similarities in the pathway to market is the established relation between materials supplier and the final product manufacturers. A dramatic role in such relations is played by industrial standards. The later can help, but also, if incorrectly developed, can stumble the final product development. We will study the process of commercialisation of graphene, its transformation to commodity and the emerging graphene standardisation efforts.     

Numerical investigation of the flow in a kitchen hood system

This study presents the results obtained when Computational Fluid Dynamics is applied to calculating the flow in a domestic kitchen hood at operating conditions. Special emphasis has been placed on parametric modeling of the geometry to permit the rapid modification of fundamental parameters, such as the number of blades and the twisting angle. The governing equations (mass, momentum, energy and turbulence) have been solved using the commercial code, fluent. The predicted characteristic curves of the hood ventilator based on the dimensionless flow and load coefficients have been built, and they are shown to be in good agreement with the experimental data. Finally, the hood model has been incorporated into a full-scale kitchen to predict airflow conditions in this space.     

Preparation and Application of Perovskite Catalysts for Diesel Soot Emissions Control: An Overview

The diesel engines are energy efficient (1), but their particulate matter (soot) emissions are still a matter of concern even though major advances in their control are being made. For soot abatement, catalytic diesel particulate filter (DPF) technique is widely employed to trap and burn the soot. Many types of catalysts have been investigated for the soot combustion i.e. platinum group metal (PGM) based, perovskite-type oxides, spinel-type oxides, rare earth metal oxides, and mixed transient metal oxides etc. The cost of PGM catalysts is high and their availability is questionable. Further they are susceptible to poisoning and have low thermal stability. On the other hand perovskite catalysts show potential as effective soot oxidation catalyst for the DPF because of their low cost, high thermal stability and tailoring flexibility. Many papers related to soot oxidation over perovskite catalysts have been published but no review paper appears in the literature that is dedicated to soot oxidation. Thus, this article provides a summary of published information regarding pure and substituted perovskite catalyst, preparation methods, properties, and their application for diesel soot emission control.     

Effects of type of multimedia strategy on learning of Chinese characters for non-native novices

The purpose of this study was to examine the effects of multimedia strategies for instructional techniques and practice on non-native novices' Chinese character learning performance and cognitive load. Two types of multimedia instructional presentations – radical-highlighted and stroke-pronunciation – and two types of practice – visual cue and voice cue – were implemented. Participants were 81 non-native novices randomly assigned to one of the four experimental groups, namely radical-highlighted visual-cue, radical-highlighted voice-cue, stroke-pronunciation visual-cue and stroke-pronunciation voice-cue. An Internet-based e-learning course on the basis of Chinese characters was implemented and delivered as experimental instruction using a Moodle platform. The results show that, for non-native novices, the stroke-pronunciation (SP) strategy of showing strokes with pronunciations is better than the radical-highlighted (RH) strategy, enabling the novices to achieve better performance in identifying Chinese radicals. The significant two-way interactions suggest that (1) the SP presentation should be delivered with the voice-cue (VoC) practice to elicit better performance in writing and in identifying characters and strokes, and (2) the RH presentation should be delivered with visual-cue (ViC) practice to elicit better performance in character writing. Furthermore, participants showed similar levels of perceived cognitive load toward the stroke-based task and the radical-based task. However, when the SP presentation was delivered with the VoC practice, participants revealed lower perceived cognitive load toward the writing task.     

Enhanced Degradation of Azoxystrobin in Grapes and Model Systems by Ozone Fumigation during Storage

This study was conducted to investigate the natural decline in the residues of the world’s most widely used fungicide, azoxystrobin, in model systems and grapes stored in cold rooms and to determine if ozone fumigation during storage has a contribution to the degradation process. The level of the fungicide gradually decreased both in model systems and grapes with the reduction rates of 53 ± 2 and 29 ± 1%, respectively, at the end of storage. Addition of ozone (1.0 ppm) to the storage atmosphere was found to have a significant influence on fungicide degradation both in model systems and grapes and about 90% reduction rates were recorded. This is the first report demonstrating the accelerated degradation of azoxystrobin by the use of ozone gas treatment.