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排序方式: 共有1212条查询结果,搜索用时 265 毫秒
1.
《Ceramics International》2022,48(15):21317-21326
1T phase molybdenum disulfide (1T-MoS2) has aroused extensive concern in energy storage devices such as supercapacitors due to its large interlayer spacing, high conductivity and good hydrophilicity. However, it is struggle to synthesize 1T-MoS2 with stable 1T phase with high content. Herein, Ammonium ion intercalation molybdenum disulfide (A-MoS2) with high 1T content and stable 3D microsphere structure was successfully synthesized using a facile hydrothermal method. We explained the feasibility of ammonium ion (NH4+) intercalation through density functional theory (DFT) calculations and proved the successful intercalation of NH4+ by XRD and XPS. Through XPS fitting, the 1T phase content is calculated as high as 83.1%. The as-prepared A-MoS2 presents a stable 3D microsphere structure with the interlayer spacing expanded to 0.93 nm, which provides a wide ion diffusion channel that allows ions to pass through quickly. Moreover, the high 1T content increases the hydrophilicity of MoS2, thereby improving the wettability of the electrode, which contributes to the interaction between the electrolyte and electrode. In 1 M Na2SO4, A-MoS2 electrode material displays high specific capacitance of 228 F g?1 at 5 mV s?1 and retains 127 F g?1 at 80 mV s?1, which proves the good rate capability. Furthermore, the assembled α-MnO2//A-MoS2 asymmetric supercapacitor (ASC) displayed a wide operating voltage of 2.1 V. The assembled ASC displays a high energy density of 35.8 Wh?kg?1 at a power density of 525.0 W kg?1, which indicates excellent energy storage performance. 相似文献
2.
《Journal of the European Ceramic Society》2019,39(16):5292-5297
Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF), which exhibits a high mixed oxide ionic-electronic conduction, was used for the fabrication of an oxygen separation membrane. An asymmetric structure, which was a thin and dense BSCF membrane layer supported on a porous BSCF substrate, was fabricated by the electrophoretic deposition method (EPD). Porous BSCF supports were prepared by the uniaxial pressing method using a powder mixture with BSCF and starch as the pore-forming agent (0–50 wt.%). The sintering behaviors of the porous support and the thin layer were separately characterized by dilatometry to determine the co-fired temperature at which cracking did not occur. A crack-free and thin dense membrane layer, which had about a 15 μm thickness and >95% relative density, was obtained after optimizing the processes of EPD and sintering. The dense/porous interface was well-bonded and the oxygen permeation flux was 2.5 ml (STP) min−1 cm-2 at 850 °C. 相似文献
3.
《Ceramics International》2020,46(13):21343-21350
The transition metal sulfides have gained extensive interest in energy storage devices owing to their unique features. However, the research-based on cobalt, copper and manganese sulfide composites is limited while they are considered as promising contenders for supercapacitor electrodes. The simplest and facile one-step electrodeposition technique was adopted for the direct growth of CuMnS and CoMnS on a Ni-substrate. The electrochemical properties of CuMnS and CoMnS electrodes were investigated and maximum specific capacitances of 1691 and 2290 F/g, respectively, were obtained at 10 A/g current density. Further, these electrodes are investigated with activated carbon (AC) electrode to fabricate asymmetric supercapacitor devices where CoMnS//AC exhibited superior energy density values than CuMnS//AC device. However, both the devices show a relatively uniform capacitance retention rate (~94%) after 2500 charging-discharging cycles. Furthermore, the role of capacitive- and diffusive-controlled contributions in the charge storage phenomenon of supercapacitor devices are explicitly scrutinized by employing Dunn's model. Co-electrodeposition of transition metal sulfides has great potential as electrode material for highly effective supercapacitor devices. 相似文献
4.
《International Journal of Hydrogen Energy》2020,45(4):3073-3085
In this study, a facile sonochemical strategy is used for the fabrication of CoFe2O4/MWCNTs hybrids as an electrode material for supercapacitor applications. FE-SEM image demonstrates the uniformly well-distributed MWCNTs as well as porous structures in the prepared CoFe2O4/MWCNTs hybrids, suggesting 3D network formation of conductive pathway, which can enhance the charge and mass transport properties between the electrodes and electrolytes during the faradic redox reactions. The as-fabricated CoFe2O4/MWCNTs hybrids with the MWCNTs concentration of 15 mg (CFC15) delivers maximum specific capacitance of 390 F g−1 at a current density of 1 mA cm−2, excellent rate capability (275 F g−1 at 10 mA cm−2), and outstanding cycling stability (86.9% capacitance retention after 2000 cycles at 3 mA cm−2). Furthermore, the electrochemical performance of the CFC15 is superior to those of pure CoFe2O4 and other CoFe2O4/MWCNTs hybrids (CFC5, CFC10 and CFC20), indicating well-dispersion MWCNTs and uniform porous structures. Also, as-fabricated asymmetric supercapacitor device using the CoFe2O4/MWCNTs hybrids as the positive electrode and activated carbon as the negative electrode materials shows the outstanding supercapacitive performance (high specific capacitance, superior cycling stability and good rate capability) for energy storage devices. It delivers a capacitance value of 81 F g−1 at 3 mA cm−2, ca. 92% retention of its initial capacitance value after 2000 charge-discharge cycles and excellent energy density (26.67 W h kg−1) at high power density (~319 W kg−1). 相似文献
5.
6.
《International Journal of Hydrogen Energy》2020,45(11):6120-6127
In this work, a cross-linked sheet structured conducting polymer ploy(3,4-ethylenedioxythiophene) (PEDOT) decorated on Ni foam is synthesized via one-step electrodeposition using the sodium p-toluenesulfonate (STSA) as surfactant and applied for supercapacitor electrode. The surfactants play a vital role in controlling the morphologies of PEDOT leading to the electrochemical performance difference. The optimized PEDOT electrode exhibits the highest capacitance of 711.6 mF cm−2 at 3.0 mA cm−2 in the three-electrode system. An asymmetric device (PEDOT/STSA//AC) is constructed by PEDOT/STSA (the positive electrode), activated carbon (AC) (the negative electrode) as well as 1 M Na2SO4 (the electrolyte). The device has been worked in a high-voltage range of 0–1.5 V, which displays the satisfied energy density of 14.0 Wh·kg−1 at 535.5 W kg−1. Furthermore, the PEDOT/STSA//AC device presents excellent rate capability and long-time cyclic stability. 相似文献
7.
Stefan Schachner Shengli Jin Dietmar Gruber Harald Harmuth 《Ceramics International》2019,45(7):9483-9490
In service tensile and compressive stresses occur in refractory linings, these stresses lead to creep of refractories. Ordinary refractories experience creep of the primary stage and may further proceed to the secondary and tertiary creep stage. For the development of advanced material models for finite element simulations it is necessary to investigate the creep behavior in all three creep stages under tensile and compressive loads. Hence, two advanced high temperature uniaxial creep testing devices, applying a wide range of tensile and compressive loads, were used to determine the three creep stages in a reasonable time under service related loading conditions. The Norton–Bailey creep equations and an inverse identification procedure were applied for the evaluation of the experimental results. A magnesia refractory was studied at elevated temperatures and its respective creep parameters for each stage were determined. The stress dependency on the creep behavior can be seen clearly on the creep curves and the corresponding creep parameters. Furthermore, a comparative study of creep parameters and creep rates was performed between the magnesia refractory and a magnesia-chromite refractory. The results demonstrate the significant asymmetrical creep behavior in tension and compression for both materials. The creep investigation in this paper favors the requirement for consideration of the three stage creep behavior and the asymmetrical creep behavior in thermomechanical modelling activities of industrial vessels. 相似文献
8.
Most real-world vehicle nodes can be structured into an interconnected network of vehicles. Through structuring these services and vehicle device interactions into multiple types, such internet of vehicles becomes multidimensional heterogeneous overlay networks. The heterogeneousness of the overlays makes it difficult for the overlay networks to coordinate with each other to improve their performance. Therefore, it poses an interesting but critical challenge to the effective analysis of heterogeneous virtual vehicular networks. A variety of virtual vehicular networks can be easily deployed onto the native network by applying the concept of SDN (Software Defined Networking). These virtual networks reflect their heterogeneousness due to their different performance goals, and they compete for the same physical resources of the underlying network, so that a sub-optimal performance of the virtual networks may be achieved. Therefore, we propose a Deep Reinforcement Learning (DRL) approach to make the virtual networks cooperate with each other through the SDN controller. A cooperative solution based on the asymmetric Nash bargaining is proposed for co-existing virtual networks to improve their performance. Moreover, the Markov Chain model and DRL resolution are introduced to leverage the heterogeneous performance goals of virtual networks. The implementation of the approach is introduced, and simulation results confirm the performance improvement of the latency sensitive, loss-rate sensitive and throughput sensitive heterogeneous vehicular networks using our cooperative solution. 相似文献
9.
This paper is the first part of a two‐part study, and it presented numerical research of double‐diffusive natural convection within an annulus area, situated in two horizontal confocal elliptic solids charged by a Newtonian fluid. The elliptical coordinates were used to transform the physical domain into a rectangular one. To resolve the governing equations and the boundary layer conditions, a calculator code based on the finite volume approach was developed. The details of the influences of thermal Rayleigh number on heat and mass transfer were investigated. Results obtained were compared with those existing in other reasearch works. 相似文献
10.
针对两种布置形式(水平布置和对角布置)的串列双方柱,通过同步测压风洞试验,在雷诺数为Re = 8.0×104、间距比为P/B = 1.75 ~ 5.00(其中P为方柱中心间距、B为方柱边长)条件下,得到了两种布置形式串列双方柱的表面风压,重点研究了对角串列双方柱的气动力、风压分布、Strouhal数等气动性能随方柱间距的变化规律,并与水平串列双方柱进行比较。水平串列双方柱的气动力在P/B = 3.00 ~ 3.50时会发生跳跃现象,下游方柱的平均阻力由负值突变为正值,而对角下游方柱平均阻力系数则均为负值。结果表明:当P/B<3.00时,对角串列双方柱的平均和脉动气动力系数、最大平均负压强度和脉动风压系数均大于水平串列双方柱,而当P/B > 3.00时则情况相反;对角串列双方柱的Strouhal数明显小于相同间距下的水平串列双方柱,且在P/B <3.00时对角串列双方柱的升力功率谱出现了多个峰值。 相似文献