不同压力下气层岩样m、n值变化的实验研究

胶结指数m和饱和度指数n变化规律的研究一直是岩石物理学家和测井解释分析家关注的问题。压力是影响m、n的重要因素,但迄今为止,仍未取得可使多数人接受的一般性结论。实验开展了低孔隙度低渗透率气层岩样在不同压力条件下的电阻率测量,在考虑孔隙度随压力变化的基础上建立了m、n参数随压力变化的关系,得出结论:某些地区的气层岩样在压力增大时即使考虑孔隙度变化,m值增大,n值减小。     

The initial behaviour of freshly etched copper in moderately acid, aerated chloride solutions

When freshly etched samples of various types of copper were exposed in moderately acid, aerated chloride solutions, two phenomena were observed. First the corrosion potential and the pH of the solution decreased over a shorter time, then the potential increased over a long period (600-1500 min), following an s-shaped pattern. Increase in pH during the second stage was avoided using a pH-stat. The corrosion rate increased little or not at all over the entire period. A tentative interpretation of the short-term behaviour is presented with some reservation. The long-term development of the potential suggests phase formation or transformation following the Avrami pattern. By suitable derivations it was possible to fit the development of potentials to the Avrami equation. Subsequent examinations by Auger spectroscopy proved the presence of thin layers of Cu₂O on the copper surfaces, increasing in thickness with exposure time. The dissolution kinetics can be described in terms of two parallel electrochemical reactions and a simultaneous non-electrochemical dissolution reaction.     

用测井资料预测储层的润湿性

岩心电性及润湿性实验测量结果表明，润湿性对阿尔奇饱和度指数n有很大影响。通过引入相对润湿指数，发现阿尔奇饱和度指数n的对数与相润湿指数之间存在很好的线性关系，为利用饱和度指数预测储层的润湿性提供了依据。同时使用电磁波传播测井和微球形聚焦电阻率测井求出饱和度指数随地层深度的变化曲线，预测储层的润湿性。现场井资料处理结果表明，该方法能快速直观显示不同深度处储层润湿性的变化。     

非晶态Pd—Cu—Si合金的晶化动力学研究

本文应用DSC研究了非晶态Pd-Cu-Si合金的晶化过程动力学.根据Kissinger峰移法和Arrhenius方程分别计算了晶化激活能,发现等温晶化动力学在0.15相似文献   

二元稀土镁合金Mg-La和Mg-Nd的组织和性能

系统研究了二元稀土镁合金Mg-2%La(L2)和Mg-2%Nd(N2)的铸态显微组织、拉伸性能和抗蠕变性能.通过研究发现,L2铸态组织中有大量网状的Mg-Mg17La2的共晶相析出;而N2则以Mg12Nd离异共晶析出,析出物的数量少得多.N2合金在室温或者175℃条件下,强度和塑性都优于L2合金.N2合金的抗蠕变性能在175℃、70 MPa条件下比L2低近3个数量级.通过计算两种合金的应力指数和蠕变激活能,L2合金的蠕变机制是受晶界滑动控制的,而N2合金为位错攀移机制控制.     

合成镁白云石中CaO和MgO晶粒生长动力学

应用ＴＰ速率等式和线性截距法研究了经１５００℃至１７００℃烧成的两个合成镁白云石体系中ＣａＯ和ＭｇＯ的晶粒生长，采用回归分析和最小二乘法求得ＣａＯ和ＭｇＯ晶粒的生长指数和晶位生长活化能。结果表明，体系中ＭｇＯ晶粒的生长速率总比ＣａＯ的要大，而加入少量ＣｅＯ２添加剂的合成镁白云石中ＣａＯ和ＭｇＯ晶粒生长速率比无添加剂的要快。     

云南蒋家沟黏性泥石流输沙的涨落特征

间歇性阵流是山区小流域发生的黏性泥石流活动的基本形式,其输沙特性表现出一定的间歇性和涨落特性,其涨落可达均值的2~4个数量级。利用Hurst指数分析了蒋家沟近50年的数千阵泥石流观测资料,发现间歇性阵流的流量、径流量、输沙量序列的Hurst指数均大于0.5,说明序列具有一定程度的长程关联性。同时,对比阵流序列与洪峰序列,发现泥石流阵流的长程关联性强于洪峰序列。另一方面,输沙量的累积百分比均满足统一的指数分布形式:P(S)=CS~(-μ)exp(-S/S_c),其中μ越大意味着序列中输沙量较小的阵次越多;S_c表示的是阵流输沙的涨落情况,即S_c越大,阵流输沙的涨落越大。     

Crystallization behavior of poly(N‐methyldodecano‐12‐lactam). IV. Nonisothermal crystallization

Nonisothermal crystallization of poly(N‐methyldodecano‐12‐lactam) (MPA) was investigated using DSC method at cooling rates of 2–40 K/min. With increasing cooling rate, crystallization exotherms decreased in magnitude and shifted toward lower temperatures. Subsequent heating runs (10 K/min) showed an exotherm just above T_g, which increased in magnitude with the rate of preceding cooling run, corresponding to the continuation of primary crystallization interrupted as the system crossed T_g on cooling. Kinetic evaluation by the Avrami method gave values of exponent n close to 2.0, suggesting two‐dimensional crystal growth combined with heterogeneous nucleation. The Tobin method, covering the intermediate range of relative crystallinities, provided n ? 2.20, suggesting possible partial involvement of homogeneous nucleation at later stages of nonisothermal crystallization. The crystallization rate parameter k^1/n showed a linear dependency on cooling rate for both methods, the Tobin values being slightly higher. The Ozawa approach failed to provide reasonable values of the kinetic exponent m of MPA. The Augis–Bennet method was used to determine the effective activation energy of the entire nonisothermal crystallization process of MPA. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 95: 564–572, 2005     

基于路由标记的分布式信息检索

文章对分布式信息检索中通常采用的洪泛策略进行分析,发现其容易重复转发相同消息,导致产生大量冗余通信,造成网络拥塞等问题。提出采用基于路由标记的分布式信息检索策略,以减少冗余消息的产生并避免网络拥塞,最后以实例进行两种策略的对比分析,并通过理论推导证明了后者的有效性。     

Novel nitrogen‐containing epoxy resin. II. Cure kinetics by differential scanning calorimetry

The isothermal and nonisothermal cure behaviors of a novel nitrogen‐containing epoxy resin (XT resin) were studied by differential scanning calorimetry (DSC). Various kinetic parameters and details of cure process were obtained based on the Avrami theory. The results indicated that Avrami method is suitable for calculating the kinetic parameters up to the gel point at least. The apparent activation energy (E_a) for isothermal cure process was in agreement with that for nonisothermal cure process. E_a value in the early stage (78.5–81.0 KJ mol^?1) was about three times than that in the later stage (23.3–26.5 KJ mol^?1). The kinetic results from Avrami theory may present a combined effect of all factors, and which is helpful to understand the cure technique for XT–DDS system. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3483–3489, 2006