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1.
不同压力下气层岩样m、n值变化的实验研究 总被引:1,自引:0,他引:1
胶结指数m和饱和度指数n变化规律的研究一直是岩石物理学家和测井解释分析家关注的问题。压力是影响m、n的重要因素,但迄今为止,仍未取得可使多数人接受的一般性结论。实验开展了低孔隙度低渗透率气层岩样在不同压力条件下的电阻率测量,在考虑孔隙度随压力变化的基础上建立了m、n参数随压力变化的关系,得出结论:某些地区的气层岩样在压力增大时即使考虑孔隙度变化,m值增大,n值减小。 相似文献
2.
When freshly etched samples of various types of copper were exposed in moderately acid, aerated chloride solutions, two phenomena were observed. First the corrosion potential and the pH of the solution decreased over a shorter time, then the potential increased over a long period (600-1500 min), following an s-shaped pattern. Increase in pH during the second stage was avoided using a pH-stat. The corrosion rate increased little or not at all over the entire period. A tentative interpretation of the short-term behaviour is presented with some reservation. The long-term development of the potential suggests phase formation or transformation following the Avrami pattern. By suitable derivations it was possible to fit the development of potentials to the Avrami equation. Subsequent examinations by Auger spectroscopy proved the presence of thin layers of Cu2O on the copper surfaces, increasing in thickness with exposure time. The dissolution kinetics can be described in terms of two parallel electrochemical reactions and a simultaneous non-electrochemical dissolution reaction. 相似文献
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5.
二元稀土镁合金Mg-La和Mg-Nd的组织和性能 总被引:6,自引:0,他引:6
系统研究了二元稀土镁合金Mg-2%La(L2)和Mg-2%Nd(N2)的铸态显微组织、拉伸性能和抗蠕变性能.通过研究发现,L2铸态组织中有大量网状的Mg-Mg17La2的共晶相析出;而N2则以Mg12Nd离异共晶析出,析出物的数量少得多.N2合金在室温或者175℃条件下,强度和塑性都优于L2合金.N2合金的抗蠕变性能在175℃、70 MPa条件下比L2低近3个数量级.通过计算两种合金的应力指数和蠕变激活能,L2合金的蠕变机制是受晶界滑动控制的,而N2合金为位错攀移机制控制. 相似文献
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7.
间歇性阵流是山区小流域发生的黏性泥石流活动的基本形式,其输沙特性表现出一定的间歇性和涨落特性,其涨落可达均值的2~4个数量级。利用Hurst指数分析了蒋家沟近50年的数千阵泥石流观测资料,发现间歇性阵流的流量、径流量、输沙量序列的Hurst指数均大于0.5,说明序列具有一定程度的长程关联性。同时,对比阵流序列与洪峰序列,发现泥石流阵流的长程关联性强于洪峰序列。另一方面,输沙量的累积百分比均满足统一的指数分布形式:P(S)=CS~(-μ)exp(-S/S_c),其中μ越大意味着序列中输沙量较小的阵次越多;S_c表示的是阵流输沙的涨落情况,即S_c越大,阵流输沙的涨落越大。 相似文献
8.
Nonisothermal crystallization of poly(N‐methyldodecano‐12‐lactam) (MPA) was investigated using DSC method at cooling rates of 2–40 K/min. With increasing cooling rate, crystallization exotherms decreased in magnitude and shifted toward lower temperatures. Subsequent heating runs (10 K/min) showed an exotherm just above Tg, which increased in magnitude with the rate of preceding cooling run, corresponding to the continuation of primary crystallization interrupted as the system crossed Tg on cooling. Kinetic evaluation by the Avrami method gave values of exponent n close to 2.0, suggesting two‐dimensional crystal growth combined with heterogeneous nucleation. The Tobin method, covering the intermediate range of relative crystallinities, provided n ? 2.20, suggesting possible partial involvement of homogeneous nucleation at later stages of nonisothermal crystallization. The crystallization rate parameter k1/n showed a linear dependency on cooling rate for both methods, the Tobin values being slightly higher. The Ozawa approach failed to provide reasonable values of the kinetic exponent m of MPA. The Augis–Bennet method was used to determine the effective activation energy of the entire nonisothermal crystallization process of MPA. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 95: 564–572, 2005 相似文献
9.
文章对分布式信息检索中通常采用的洪泛策略进行分析,发现其容易重复转发相同消息,导致产生大量冗余通信,造成网络拥塞等问题。提出采用基于路由标记的分布式信息检索策略,以减少冗余消息的产生并避免网络拥塞,最后以实例进行两种策略的对比分析,并通过理论推导证明了后者的有效性。 相似文献
10.
David?Pérez-Martínez C.?Alvarez-Salas J.?A.?Morales-Rueda J.?F.?Toro-VazquezEmail author M.?Charó-Alonso E.?Dibildox-Alvarado 《Journal of the American Oil Chemists' Society》2005,82(7):471-479
The solid fat content (SFC), Avrami index (n), crystallization rate (z), fractal dimension (D), and the pre-exponential term [log(γ)] were determined in blends of cocoa butter (CB) with canola oil or soybean oil crystallized
at temperatures (T
Cr) between 9.5 and 13.5°C. The relationship of these parameters with the elasticity (G′) and yield stress (σ*) values of the crystallized blends was investigated, considering the equilibrium melting temperature (T
M
o) and the supercooling (i.e., T
Cr
o−T
M
o) present in the blends. In general, supercooling was higher in the CB/soybean oil blend [T
M
o=65.8°C (±3.0°C)] than in the CB/canola oil blend [T
M
o=33.7°C (±4.9°C)]. Therefore, under similar T
Cr values, higher SFC and z values (P<0.05) were obtained with the CB/soybean oil blend. However, independent of T
Cr TAG followed a spherulitic crystal growth mechanism in both blends. Supercooling calculated with melting temperatures from
DSC thermograms explained the SFC and z behavior just within each blend. However, supercooling calculated with T
M
o explained both the SFC and z behavior within each blend and between the blends. Thus, independent of the blend used, SFC described the behavior of G′eq and σ* and pointed out the presence of two supercooling regions. In the lower supercooling region, G′eq and σ* decreased as SFC increased between 20 and 23%. In this region, the crystal network structures were formed by a mixture of
small β′ crystals and large β crystals. In contrast, in the higher supercooling region (24 to 27% SFC), G′eq and σ* had a direct relationship with SFC, and the crystal network structure was formed mainly by small β′ crystals. However, we
could not find a particular relationship that described the overall behavior of G′eq and σ* as a function of D and independent of the system investigated. 相似文献