火花放电原子发射光谱类型标准化校正方式的探讨

在国内,火花放电原子发射光谱分析广泛使用类型标准化进行方法校正。在国外,标准和文献中鲜见使用此方法的相关论述。类型标准化主要采用平移校正和转动校正两种方式,哪种方式更加合理也鲜见报道。国外设备类型标准化的默认设置优先采用转动校正方式,相关国内标准对最优校正方式的规定尚不明确,此默认设置的合理性有待探讨。实验选用低合金钢20CrNi2Mo、R407标准样品和不锈钢317L、0Cr18Ni9标准样品,引用国内相关标准,以正确度临界差为评判依据,模拟类型标准化样品和待测样品“十分接近”和“接近”两种情况下平移校正和转动校正的数据正确度。经数据统计分析,平移校正分析结果均满足要求,转动校正结果在“接近”情况下部分元素不满足要求。结合相关国家标准中元素含量范围和精密度数据进行分析,通过计算允许最大偏倚量并制作曲线图方式展开分析,得出如下结论:在满足文中类型标准化控制要点前提下,分析设置更适合于采用平移校正方式。     

Surface generation mechanism of ceramic matrix composite in ultrasonic assisted wire sawing

Ceramic matrix composites (CMC) are highly required in many fields of science and engineering. However, the CMC parts always have poor surface finish. This study attempts to improve cutting performance of CMC material by combing the advantages of ultrasonic assisted cutting and diamond wire sawing. Cutting force, surface roughness, machined edge and tool wear are analyzed based on experimental results. It shows that the oscillatory movement of tool edges provides positive effect on particle ejection and residual material reduction. Ductile chip formation can be achieved due to the small tip radius of grits. Obvious decrease in cutting force, surface roughness and tool wear are obtained. Moreover, burrs, fuzzing and fracture are reduced. Meanwhile, both the surface characteristics and shape accuracy are significantly improved. These results provide a valuable basis for application of ultrasonic assisted wire sawing and understanding of CMC cutting mechanisms.     

多晶硅表面金属催化化学腐蚀法制绒研究现状

在多晶硅太阳能电池的生产过程中, 金刚线切割技术(Diamond wire sawn, DWS)具有切割速度快、精度高、原材料损耗少等优点, 受到了广泛关注。金刚线切割多晶硅表面形成的损伤层较浅, 与传统的酸腐蚀制绒技术无法匹配, 金属催化化学腐蚀法应运而生。金属催化化学腐蚀法制绒具有操作简单、结构可控且易形成高深宽比的绒面等优点, 具有广阔的应用前景。本文总结了不同类型的金属催化剂在制绒过程中的腐蚀机理及其形成的绒面结构, 深入分析和讨论了具有代表性的银、铜的单一及复合催化腐蚀过程及绒面结构和电池片性能。最后对金刚线切割多晶硅片表面的金属催化化学腐蚀法存在的问题进行了分析, 并展望了未来的研究方向。     

Experimental investigation on diamond wire sawing of Si3N4 ceramics considering the evolution of wire cutting performance

When diamond wire saw is used in machining silicon nitride ceramics (Si₃N₄ ceramics), the ultra-hardness of Si₃N₄ causes the saw wire to wear out, which leads to the saw wire cutting performance constantly changing during its life cycle, and thus the machined quality of Si₃N₄ ceramics is affected. Surface roughness and topography are important indicators of the quality of the machined surface. In this paper, the diamond wire saw cutting experiment of Si₃N₄ ceramics was carried out, the effect of the evolution of saw wire cutting performance on the surface roughness and topography of Si₃N₄ ceramics as-sawn slices was investigated based on the analysis of the changes of saw wire wear topography, breaking force, bow angle and kerf loss during the sawing process. The results show that the surface roughness along the saw wire motion direction and the workpiece feed direction tends to decrease and then increase with the evolution of the cutting performance of the saw wire, which accords well with the trend of the as-sawn slices surface morphology. The results of the study can provide experimental reference for the development of high precision diamond wire saw cutting technology for Si₃N₄ ceramics.     

基于双声表面波器件的引信加速度传感器

In view of the shortcomings of silicon micro acceleration sensor based on piezoresistive effect and capacitance principle, such as temperature drift, low resolution and poor anti-interference ability, a fuze acceleration sensor based on dual SAW devices is proposed. The sensor adopts a dual saw device structure, one is coated with a sensitive film for measurement, the other is an uncoat- ed reference channel for compensation of environmental temperature, pressure, humidity and other factors. The experimental results show that the maximum linear error is only 1.6%, the sensitivity is 54.3Hz/g, and the maximum hysteresis error is less than 1%. Compared with piezoresistive accelerometer and capacitive accelerometer, the linear error of the accelerometer is small, the sensitivi- ty is high, and it has strong anti-interference ability.     

Risk of slaughterhouse workers developing work-related musculoskeletal disorders in different organizational working conditions

Job rotation is defined as workers rotating between tasks with different exposure levels and occupational demands. The aim of the present study was to analyze the risk factors for the development of upper-limb work-related musculoskeletal disorders (UL-WMSDs) in poultry slaughterhouse workers as well as compare the score of the OCRA Checklist in different organizational working conditions. In this cross-sectional study, 118 workers were involved, 68 women (32.3 ± 10.7 years) and 50 men (29.5 ± 10.5 years). Three organizational configurations (“without job rotation”, “with job rotation – tasks >1h” and “with job rotation - tasks <1h”) were evaluated using the OCRA Checklist method, totaling 36 tasks and 28 job rotation schemes composed of 2–3 tasks. The OCRA score of the right upper limbs (17.8 ± 3.2) was significantly higher (p = 0.046) relative to the left upper limbs (16.4 ± 3.6). The median score was significantly lower in the “with job rotation - tasks <1h” condition (18.6) when compared to the “job rotation – tasks >1h” (19.4) (p < 0.001) and the “without job rotation” (19.0) (p = 0.038) conditions. However, there was no significant difference between the condition “with job rotation - tasks >1h” and “without job rotation” (p = 0.155). Thus, job rotations with intervals <1h reduced the risk of developing UL-WMSDs. Job rotations with <1 h intervals in poultry slaughterhouses are recommended along with further studies to verify the effectiveness of rotations with more than two tasks, involving mild or non-repetitive tasks.     

高强不锈钢绞线网与ECC黏结-滑移关系模型

高强不锈钢绞线网与ECC的黏结是二者协同工作的基础，且黏结 滑移关系模型是其黏结性能的综合反映，故通过对17组51个高强不锈钢绞网增强ECC薄板试件进行单边拉拔试验，研究横向钢绞线间距、纵向钢绞线直径和相对锚固长度等因素对钢绞线网在ECC中黏结性能的影响规律。试验结果表明，横向钢绞线的设置可使黏结破坏由脆性破坏转变为延性破坏；高强不锈钢绞线网与ECC的黏结滑移曲线可分为5个阶段，分别为上升段、微降段、延性强化段、下降段和残余段。基于试验结果，对钢绞线网在ECC中的黏结破坏特征和黏结 滑移机理进行分析，在相关黏结-滑移关系模型的基础上，提出钢绞线网与ECC的黏结 滑移关系模型，并进行模型参数分析。所提模型及模型参数计算公式与试验结果吻合良好，能较好地反映钢绞线网与ECC的界面黏结滑移特征。     

退火温度对0Cr25Al5热轧态盘条钢组织及性能的影响

采用显微组织分析和分子动力学模拟等方法研究了退火温度对0Cr25Al5热轧态盘条钢组织及性能的影响。结果发现,晶粒尺寸随温度的升高逐渐增加并趋于稳定,但是断后伸长率和断面收缩率在950 ℃突然大幅度下降。试样组织形貌在800 ℃和950 ℃退火温度下的OM及SEM分析结果未见明显差别。于是使用分子动力学模拟对0Cr25Al5钢三元体系的自由能进行了计算,发现随着B2结构的FeAl或者DO3结构的Fe₃Al有序相尺寸的增大,系统自由能先减小后增大,其最小值随着退火温度的升高向有序相颗粒尺寸减小的方向移动。在1273 K的高温下仍然会保留60 nm左右大小的有序相颗粒。因此,推测0Cr25Al5钢在大于950 ℃的温度范围内韧性下降是由于60 nm左右的B2结构的FeAl或者DO3结构的Fe₃Al有序相造成,与晶粒尺寸无关。因此,针对该钢种应进行低温退火促使基体组织回复以消除缺陷,从而抑制Fe、Al等基体原子的扩散。     

Experimental study on the behavior of eccentrically loaded circular footing model resting on reinforced sand

In this study, an experimental investigation has been conducted on a circular footing model subjected to eccentric load resting on the geonet-reinforced sand. To this end, five series of tests were carried out in order to evaluate the effect of reinforcement dimension and eccentricity on the bearing capacity, settlement, and rotation of the footing. Results show that the bearing capacity ratio (BCR) is in direct relationship with eccentricity and the impact of soil reinforcement at low settlements is much more significant in the case of eccentric loading. Additionally, the bearing capacity interaction diagram and variation in the position of rotation line at different load levels for reinforced and unreinforced conditions are presented.     

基于非对称磁镀材料线圈的无线输电系统

煤矿井下有线供电有很多弊端，急需将无线输电技术及系统应用于煤矿井下，但是目前常规对称线圈结构难以满足矿井的特殊需求。基于非对称磁镀材料线圈的磁耦合谐振式无线输电系统并分析其传输效率，针对无线输电系统实际应用中常有的发射端线圈与接收端线圈尺寸有较大差异且位置有水平偏移的问题，进行了分析与研究。提出在常规两线圈结构间加入与发射线圈同轴共面的中继线圈，同时采用五层结构的磁镀导线代替铜导线进行线圈绕制，并建立了系统模型。进行了无线输电系统的互感分析及与常规两线圈系统的比对，对磁镀导线结构相较于普通铜线减少能量损耗的优势进行了分析及仿真。对加入特定位置线圈且使用磁镀导线的无线输电系统及原始两线圈系统进行了构建过程中各阶段的系统模拟仿真及室内实验。认为提出的加入特定位置线圈及采用磁镀导线的方法对非对称的磁耦合无线输电系统的传输效率有明显积极作用，构建的基于磁镀导线且加入特定位置线圈的非对称磁耦合无线输电系统即使结构不对称，仍能保持很高的传输效率，相较于常规两线圈系统而言，传输效率得到显著提升。