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1.
《Advanced Powder Technology》2022,33(6):103595
Ceria (CeO2) particles are prevalent polishing abrasive materials. Trivalent lanthanide ions are the popular category of dopants for enriched surface defects and thus improved physicochemical properties, since they are highly compatible with CeO2 lattices. Herein, a series of dendritic-like mesoporous silica (D-mSiO2)-supported samarium (Sm)-doped CeO2 nanocrystals were synthesized via a facile chemical precipitation method. The relation of the structural characteristics and chemical mechanical polishing (CMP) performances were investigated to explore the effect of Sm-doping amounts on the D-mSiO2/SmxCe1?xO2?δ (x = 0–1) composite abrasives. The involved low-modulus D-mSiO2 cores aimed to eliminate surface scratch and damage, resulting from the optimized contact behavior between abrasives and surfaces. The trivalent cerium (Ce3+) and oxygen vacancy (VO) at CeO2 surfaces were expected to be reactive sites for the material removal process over SiO2 films. The optimal oxide-CMP performances in terms of removal efficiency and surface quality were achieved by the 40% Sm-doped composite abrasives. It might be attributed to the high Ce3+ and VO concentrations and the enhancement of tribochemical reactivity between CeO2SiO2 interfaces. Furthermore, the relationship between the surface chemistry, polishing performance as well as the actual role in oxide-CMP of the D-mSiO2/SmxCe1?xO2?δ abrasives were also discussed. 相似文献
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《Journal of the European Ceramic Society》2022,42(10):4377-4387
RE disilicates are good candidates as environmental/thermal barrier coating for SiCf/SiC composite in harsh gas turbine engines. We designed (Yb1?xHox)2Si2O7 solid solutions and studied mechanical properties, thermal properties, and water vapor resistance. Powders with different compositions were synthesized by pressureless sintering, and bulk samples were prepared by Spark Plasma Sintering (SPS). Polymorphic changes with temperature and composition of the solid solutions were examined. Through doping Ho into Yb2Si2O7, water vapor corrosion resistance is significantly promoted, and thermal expansion coefficient is maintained close to that of Si-based ceramics. Compared with host disilicates, thermal conductivity of solid solutions are decreased, and mechanical properties, including Vickers hardness and fracture toughness, are increased. A two-phase domain is found at (Yb1/2Ho1/2)2Si2O7, and the γ to δ phase transition of Ho2Si2O7 is observed during SPS. Among all samples, γ-(Yb1/3Ho2/3)2Si2O7 possesses superior high temperature stability, and excellent water vapor resistance, indicating its performance as environmental/thermal barrier coating. 相似文献
4.
《Ceramics International》2022,48(3):3720-3728
In this paper, a stable lithium niobate (LN) sol was prepared using niobium pentachloride, niobium ethoxide, lithium acetate, anhydrous ethanol, and benzoylacetone (BzAcH) as a chemical modifier. The effects of different starting materials and organic solvents on the obtained gel film quality of the sols were studied and the optimization mechanism of BzAcH on the film quality was analyzed in detail. The effects of heat treatment temperature on the structure and performance of the LN thin films were also studied. X-ray diffraction (XRD) spectra showed that LN was more highly crystalline in the heat treatment temperature range of 600–800 °C. The refractive index of the LN thin films first increased and then decreased with increasing heat treatment temperature, and the LN thin film prepared at 700 °C had the largest refractive index. Light transmittance tests showed that as the heat treatment temperature increased, light transmittance decreased. Finally, it was determined that LN gel films modified with BzAcH were more highly sensitive to UV light and that after UV irradiation, it was difficult to dissolve LN gel films in organic solvent. The UV-sensitive property was utilized to realize microstructure processing of the LN thin films. The results indicated that a high-quality, non-destructive, and photoresist-free micro-fabrication method was realized. This method was used to fabricate microscale LN fine patterns with smooth sidewalls while avoiding lateral corrosion. These results are of great significance for LN thin film applications and the development of LN-based optoelectronic devices prepared by chemical methods. 相似文献
5.
《Ceramics International》2022,48(6):8155-8168
In the present study, the effect of oxy-acetylene flame angle on the erosion resistance of SiC/ZrB2–SiC/ZrB2 multilayer coatings with the gradient structure was investigated. To this aim, first, the SiC inner layer was applied by the reactive melt infiltration (RMI) technique; then ZrB2 and ZrB2–SiC layers with 10, 20 and 30%wt. SiC were applied on graphite by the plasma spraying technique. To prevent the oxidation of ZrB2 and SiC particles, the plasma spraying process was performed by a solid protective shield. To evaluate the performance of the coatings in erosive environments, the samples were exposed to oxy-acetylene flame at the angles of 30°, 60° and 90° for 360 s; the destruction mechanism of SiC/ZrB2–SiC/ZrB2 multilayer coatings appeared to be controlled mechanically and chemically. The results of the erosion test showed that at the low flame angles of about 30°, due to the shear forces of oxy-acetylene flame, mechanical erosion overcame the chemical one. With increasing the flame angle, due to raising the surface temperature, chemical erosion overcame the mechanical one; so, most chemical destruction occurred at the flame angle of 90°. Also, the results of the erosion test showed that the total chemical and mechanical destruction at the angle of 60° was greater than that in other angles. Also, among the coatings tested, SiC/ZrB2- 20% wt. SiC/ZrB2 coatings had the best erosion resistance; so, the weight changes under the oxy-acetylene flame at the angles of 30° and 60°, respectively, were about ?0.038%. and ?0.355%; meanwhile, at the angle of 90°, it was about +4.3%. 相似文献
6.
研究了3种微通道板基底羟基化的方法,测量了羟基化处理后微通道板基底表面水接触角及通道端面的形貌变化,分析了各种方法中微通道板基底的亲水性和腐蚀情况。实验结果表明:氨水双氧水溶液对基体表面的亲水性能提升不大,NaOH溶液对基体有腐蚀作用,经食人鱼溶液处理的基体表面亲水性明显提高且无腐蚀作用。研究了微通道板在食人鱼溶液中的浸泡时间和浸泡温度对表面亲水性的影响。结果表明:随着浸泡温度的增加,微通道板表面水接触角先减小后增大,当温度为80℃时达到极小值,浸泡时间对微通道板表面的亲水性影响不大。最终确定了微通道板表面羟基化工艺:浸泡温度为80℃,静置时间为20~60 min。 相似文献
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用块状渣土置换软弱地基和回填低洼谷地等是处置工程渣土的有效途径。为了分析饱和块状混合回填土地基的固结性状,运用混合物理论建立了其一维固结模型。首先,假定块状土固相和充填土固相之间满足等应变条件,获得了饱和块状混合回填土中各相应变与块状土孔隙变形和充填土孔隙变形的关系式。其次,在小应变条件下,根据自由能势函数方程建立了饱和块状混合回填土的一维线弹性本构方程,再结合达西定律和应力平衡方程获得了一维固结控制方程。再次,利用分离变量法得到一维固结解析解,通过退化本文模型与已有模型进行对比,验证了本文模型的正确性。最后,基于所得解析解,分析了充填土孔隙渗透系数、块状土孔隙渗透系数以及流体交换参数等因素对饱和块状混合回填土地基固结性状的影响。分析结果表明:充填土孔隙渗透系数对饱和块状混合回填土地基整体固结性状起主导作用;在固结初期,块状土超孔压会有一定程度的上升,且3个参数具有相似的作用机理。 相似文献
9.
《Geotextiles and Geomembranes》2022,50(1):55-68
A series of large scale direct shear experiments is used to investigate the effect of the geomembrane (GMB) surface roughness, geotextile (GTX) properties, and GTX ageing, on the GMB-GTX interface shear behaviour. Interfaces involving smooth, coextruded textured, and structured surface GMBs underlying four different nonwoven needle-punched staple fibres (GTXs) with mass per unit areas between 200 and 2400 g/m2, and a geocomposite drain (GCD) are examined at normal stresses between 250 and 1000 kPa. The results showed that the interlocking between the GMB and GTX increased with increasing the GMB asperity height and/or decreasing the mass per unit area of the GTX. For the interfaces that involved GTXs preaged prior to the shear box experiments for up to 2 years at 85 °C, it was found that the 2400 g/m2 heat bonded two-layered GTX exhibited internal shear failure at low shear displacements. However, all the highly aged single layered GTXs showed an increase in the peak interface friction angles with the increase in their ageing. For these single layered GTX, the results suggest that assessing the interface friction angles using unaged GTXs for the stability analysis is conservative as long as the GTX remains intact in the field. 相似文献