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1.
在水泥企业产能过剩、生产成本居高不下的情况下,水泥企业面临氮氧化物减排的巨大压力,使用的脱硝氨水用量大,且存在氨逃逸风险造成二次环境污染。分析了脱硝系统工艺流程、NO;产生的机理、氨水消耗高的原因分析、通过企业技术革新措施的应用,从而实现降低氮氧化物和节省氨水的效果。  相似文献   
2.
In this work we have investigated the effect of the solvent during the processing of SrFe12O19 platelet-based permanent magnets by cold sintering process (CSP) plus a post-thermal treatment. Several organic solvents: glacial acetic acid, oleic acid and oleylamine have been analyzed, optimizing the CSP temperatures at 190?270 °C, under pressures of 375?670 MPa and 6?50 wt% of solvent. Modifications in the morphological and structural properties are identified depending on the solvent, which impacts on the magnetic response. Independently of the solvent, the mechanical integrity of ferrite magnets obtained by CSP is improved by a post-annealing at 1100 °C for 2 h, resulting in relative densities around 92 % with an average grain size of 1 μm and a fraction of SrFe12O19 phase >91 %. HC ≥ 2.1 kOe and MS of 73 emu/g are obtained in the final sintered ceramic magnets, exhibiting the highest HC value of 2.8 kOe for the magnet sintered using glacial acetic acid.  相似文献   
3.
This study deals with the manufacturing of catalyst-coated membranes (CCMs) for newcomers in the field of coating. Although there are many studies on electrode ink composition for improving the performance of proton-exchange membrane fuel cells (PEMFCs), there are few papers dealing with electrode coating itself. Usually, it is a know-how that often remains secret and constitutes the added value of scientific teams or the business of industrialists. In this paper, we identify and clarify the role of key parameters to improve coating quality and also to correlate coating quality with fuel cell performance via polarization curves and electrochemical active surface area measurements. We found that the coating configurations can affect the performance of lab-made CCMs in PEMFCs. After the repeatability of the performance obtained by our coating method has been proved, we show that: (i) edge effects, due to mask shadowing - cannot be neglected when the active surface area is low, (ii) a heterogeneous thickness electrode produces performance lower than a homogeneous thickness electrode, and (iii) the origin and storage of platinum on carbon powders are a very important source of variability in the obtained results.  相似文献   
4.
森林大火后的残余地表余火及地下阴燃火是引起二次森林火灾的主要原因,为防止发生二次森林火灾,清理森林余火和阴燃火是必要的。细水雾作为哈龙灭火剂的最佳替代品,被广泛应用在消防领域。本文设计一种适合熄灭森林余火和阴燃火的撞击分流高压细水雾喷头,采用Fluent进行喷头流域的仿真,分析喷孔孔径、喷孔长度和喷孔喷雾锥角对喷出细水雾速度和喷雾保护半径的影响,并进行实验验证。Fluent仿真结果表明,细水雾速度受喷孔孔径和喷孔长度影响显著,并随喷孔孔径的加粗和喷孔长度减小而增大;喷雾保护半径受喷孔孔径和喷孔喷雾锥角影响显著,并随两者的增加而变大。采用Design-Expert分析出细水雾喷头最佳参数组合,将参数代入Fluent建立VOF-to-DPM(volume of fluid-to-discrete phase model,流体体积-离散相模型)细水雾喷头喷雾模型进行仿真,选用参数相近的细水雾喷头进行实验验证,实验测得喷雾保护半径与Fluent仿真结果误差为0.8%,证明优化和仿真结果合理。  相似文献   
5.
采用盐雾腐蚀试验方法,研究了模拟海洋大气环境下XCS-lode钢与30CrNi3Mo钢的腐蚀性能,通过极化曲线及电化学阻抗谱(EIS)试验研究了两种钢在腐蚀行为上的差异。结果表明:XCS-lode钢相比30CrNi3Mo钢具有更高的自腐蚀电位, XCS-lode钢腐蚀产物膜的阻抗明显大于30CrNi3Mo钢,XCS-lode钢的耐海洋大气腐蚀性能优于30CrNi3Mo钢。  相似文献   
6.
通过实验及热力学分析得出,轧制10B21钢结疤形成主要原因为钢中平均N含量为127×10-6,导致铸坯角部冷却过程中在奥氏体晶界析出细小的BN和AlN夹杂,增加了铸坯的裂纹敏感性,形成铸坯裂纹。通过提高铁水比≥920 kg/t、转炉终点C-T-P(碳-温度-磷)命中率≥85%、出钢口圆流出钢以及LF加热次数≤3次,时间≤25 min等措施可将钢中的氮含量稳定控制在≤50×10-6,有效避免10B21钢轧后盘条结疤,提高成材率,降低成本。  相似文献   
7.
利用MELCOR程序对小型船用堆稳压器喷雾除气过程及停堆过程进行建模,进而模拟核动力装置从功率运行至降功率除气,以及除气结束后停堆消除稳压器气腔的全部物理过程。通过对反应堆关键运行参数变化趋势的仿真分析,验证了模拟的物理过程的合理性。结合建立的除气及停堆仿真模型,计算分析了包壳破损状态下,稳压器喷雾除气、停堆过程对稳压器内惰性气体含量的影响,评估了稳压器高点放气和喷雾除气对放射性物质的去除作用。研究结果能为小型堆包壳破损状态下放射性安全管理策略提供指导和帮助。  相似文献   
8.
以植物乳杆菌(Lactobacillus plantarum)、凝结芽孢杆菌(Bacillus coagulans)混菌对大枣进行液态发酵,通过单因素试验研究喷雾干燥进口温度、雾化流量、蠕动泵转速和脱脂乳粉添加量对益生菌发酵枣粉出粉率、感官评定、含水量、堆积密度及活菌数的影响,确定喷雾干燥进口温度、雾化流量、蠕动泵转速和脱脂乳粉添加量4个因素为自变量,感官评分为响应值进行响应面优化。结果表明,喷雾干燥制备益生菌发酵枣粉的最优参数为喷雾干燥进口温度150 ℃,雾化流量473 L/h,蠕动泵速20%,脂乳粉添加量2.5%。在此优化条件下,益生菌发酵枣粉出粉率为39.15%、感官评分为95.6分、含水量3.82%、堆积密度为0.251 g/mL、活菌数为1.78×109 CFU/g。  相似文献   
9.
《Ceramics International》2022,48(13):18238-18245
Zinc oxide nanorods, ZnO NRs, were synthesized on a clean glass and coated with graphene oxide (GO) using spray coating method to enhance the photocatalytic activity in wastewater treatment. The ZnO NRs were synthesized using the solution process synthesis that was optimized using Taguchi method. Several synthesis parameters have been optimized and studied to determine the best synthesis parameter to grow ZnO NRs for the photodegradation of organic contaminants. Field emission scanning electron microscopy (FESEM) with EDX, X-ray diffraction (XRD), Raman, ultraviolet visible near-infrared (UV-VIS-NIR), and photoluminescence (PL) spectroscopies were used to investigate the structural and optical properties of the produced nanorods. FESEM images revealed the vertical growth of ZnO NRs as well as layers of GO covering the ZnO NRs' top surface. The Raman study demonstrates the combination peak of GO and ZnO, hence proving the GO layer's successful coating. After the GO coating, decrease in the bandgap of the synthesized photocatalyst was detected by PL and UV–Vis absorption measurements. Under UVC exposure with treatment time of 6 h, the degradation of MB with ZnO NRs/GO photocatalyst reached a degradation percentage of 97.86%, which is greater than the degradation percentage achieved using pristine ZnO NRs, which is 93.28%. The results validated that the coating of GO enhances the photocatalytic activity of the host material, ZnO NRs.  相似文献   
10.
Cold Sintering was applied to densify a Potassium-Sodium Niobate solid solution composition, 0.5KNbO3-0.5NaNbO3 (KNN); the process uses a transient chemical sintering aid, moderate pressure (400 MPa), and temperatures between 230–300 °C to obtain ceramics of ~92 to 96 % theoretical density. Typically, sintering temperatures between ~1000?1050 °C are required to density KNN using conventional methods. In this paper, the densification was investigated during heating, particularly the shrinkage in the first 60 min of the cold sintering process. The low-field dielectric and electrical properties of the resulting ceramics were found to be comparable to conventionally sintered KNN. Electric fields up to 80 kV/cm could be applied, however the ceramics showed pinched hysteresis loops, even after poling over a wide range of temperatures and electric fields. A Rayleigh analysis was used to investigate domain dynamics and high reversible permittivity. The irreversible behavior was an order of magnitude lower than in conventionally sintered KNN, likely associated with defect pinning of ferroelectric domains. A Transmission Electron Microscopy (TEM) study revealed a high density of line defects in most grains; dislocations in the grains limit poling and domain wall movement, thus suppressing both the piezoelectric properties and the hysteresis. Furthermore, TEM observations indicated crystalline grain boundaries that were faceted with terrace kink ledges. These observations point to the importance of the initial powder optimization and grain boundary diffusion when using cold sintering to prepare ceramics that are intended to show bulk cooperative properties such as ferroelectricity. The impact of limited high temperature homogenization of bulk diffusional processes is discussed.  相似文献   
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