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排序方式: 共有806条查询结果,搜索用时 15 毫秒
1.
Polyacrylate gels containing Ag+ and TiO2 nanoparticles are shown to swell under UV light and shrink under visible light in water. In work reported by Tetsu Tatsuma and co‐workers on p. 1249, the TiO2 absorbs UV light and reduces the Ag+, whereas the deposited Ag absorbs visible light and dissolves itself. These redox reactions change the interactions between the polymer chains and eventually the volume of the gel, as shown on the cover. 相似文献
2.
Zinc sulphide thin film electroluminescent devices doped with Mn or Tb have been produced on p-type Si substrates using a process in which doped zinc oxide films are deposited by a sol-gel drain coating method from a solution of zinc acetate containing a manganese or terbium dopant. The films are then converted to ZnS by heating them in an atmosphere containing hydrogen sulphide which replaces the oxygyn with sulphur. The composition, crystalline structure and optical properties of films have shown that complete conversion from the oxide to the sulphide takes place. The luminescent characteristics of the devices so produced have been measured as a function of the doping concentrations, film thickness, insulator thickness and driving voltage and frequency. It has been found that yellow or green luminescence can be obtained using Mn or Tb doping respectively. 相似文献
3.
ElectrochemicalInvestigationontheFormationofDyFeAloyinMoltenChloridesLiuGuankun(刘冠昆),TongYexiang(童叶翔),HongHuichan(洪惠婵),Yang... 相似文献
4.
A thin film of poly(l-serine) was prepared via electropolymerization for the determination of trace levels of estradiol. In pH 5.0 phosphate buffer,
l-serine was oxidized during the cyclic potential sweeps between −0.60 and 2.0 V, forming a thin film at the electrode surface.
The electrochemical behavior of estradiol was investigated. The oxidation peak potential of estradiol shifts negatively at
the poly(l-serine) film-coated glassy carbon electrode (GCE) compared with that at the bare GCE. Otherwise, the oxidation peak current
greatly increases at the poly(l-serine) film-modified GCE. These phenomena suggest that the poly(l-serine) film exhibits catalytic activity towards the electrochemical oxidation of estradiol. Based on this, a sensitive,
rapid and simple electrochemical method was proposed for the determination of estradiol. The limit of detection is evaluated
to be 2.0 × 10−8 mol L−1. Finally, this method was successfully used to determine estradiol in blood serum. 相似文献
5.
ElectrochemicalStudyonFormationofDy-NiAlloyinMoltenChloridesTongYexiang;LiuGuankun;YangQiqin;HongHuichan,(童叶翔)(刘冠昆)(杨绮琴)(洪惠婵)... 相似文献
6.
Xin Shen Rui Zhang Shuhao Wang Xiang Chen Chuan Zhao Elena Kuzmina Elena Karaseva Vladimir Kolosnitsyn Qiang Zhang 《中国化学工程学报》2021,37(9):137-143
Lithium (Li) metal anodes promise an ultrahigh theoretical energy density and low redox potential,thus being the critical energy material for next-generation batteries.Unfortunately,the formation of Li den-drites in Li metal anodes remarkably hinders the practical applications of Li metal anodes.Herein,the dynamic evolution of discrete Li dendrites and aggregated Li dendrites with increasing current densities is visualized by in-situ optical microscopy in conjunction with ex-situ scanning electron microscopy.As revealed by the phase field simulations,the formation of aggregated Li dendrites under high current den-sity is attributed to the locally concentrated electric field rather than the depletion of Li ions.More specif-ically,the locally concentrated electric field stems from the spatial inhomogeneity on the Li metal surface and will be further enhanced with increasing current densities.Adjusting the above two factors with the help of the constructed phase field model is able to regulate the electrodeposited morphology from aggregated Li dendrites to discrete Li dendrites,and ultimately columnar Li morphology.The methodol-ogy and mechanistic understanding established herein give a significant step toward the practical appli-cations of Li metal anodes. 相似文献
7.
1,12-bis(1,2,4-triazolyl)dodecane (dTC12) is an excellent corrosion inhibitor for carbon steel in deaerated 1 M HCl solution. In this work electrochemical and analytical techniques were used to study the inhibition of corrosion on carbon steel in acidic medium. The carbon steel corrosion inhibition of dTC12 was attributed to the synergistic effect between chloride anion and quaternary ammonium ion. The protective efficiency of the film was higher than 90%, indicating that corrosion of carbon steel in 1 M HCl is reduced by dTC12.The effect of dissolved oxygen on the inhibition efficiency was also investigated. The results show that the inhibition efficiency increases in early stage and decreases for a long immersion time. 相似文献
8.
In the process of Li+ intercalation-deintercalation, electron removal is accompanied simultaneously. Oxygen was found to compensate electron removal both in theoretical calculations and practical experiments. Chlorine addition to LiNi0.7Co0.3O2 was expected to exchange electrons in that Cl− was easier to lose electrons than O2−. LiNi0.7Co0.3O2−xClx was identified as a pure hexagonal lattice of α-NaFeO2 type by X-ray diffraction. X-ray photoelectron spectroscopy was used to analyze the influence of chlorine substitution on the oxidation state of transition-metal ions. Charge-discharge experiments and cyclic voltammetry confirmed that chlorine addition was an effective way to improve reversible capacity and structural stability in cycles. 相似文献
9.
Hua Zhao 《Chemical Engineering Communications》2006,193(12):1660-1677
Over the past decade, ionic liquids (ILs) have become one of the fastest growing “green” media for chemists and engineers due to their superb physicochemical properties. The applications of these remarkable salts in reactions and extraction processes have been extensively investigated and reviewed. This review, however, highlights recent advances of ILs as versatile “green” engineering liquids in a variety of industrial applications including heat transfer fluids, azeotrope-breaking liquids, lubricants, electrolytes, liquid crystals, supported IL membranes, plasticizers, and more. This review is not intended to be comprehensive, but rather to discuss the potentials of ILs for diverse industrial applications. 相似文献
10.
The electrodiffusion technique was performed in order to investigate the shear rate on a scraped surface heat exchanger. Microelectrodes were placed inside: the walls of the outer cylinder; the inlet and outlet bowls; the rotor and the blades. Highly viscous Newtonian fluid (Emkarox HV45 solutions) and non-Newtonian model fluid (aqueous solutions of CMC) were used. The electrodiffusion method allowed us to measure wall shear rates. Maximum shear rate was observed at the scraping surface and caused by blades scraping, high shear rate was also measured on the leading edge of the blades. In the other parts of the exchanger, shear rate remained low but the development of Taylor vortices completely modified the scraped surface heat exchangers behaviour inside the surface of the bowls. A dimensionless representation of the friction factor was established for the inner and outer wall surface of the exchanger. 相似文献