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1.
《中国稀土学报(英文版)》2022,40(12):1913-1919
Transparent Er:Y2O3 ceramics with sub-micron grain size (<1 μm) were fabricated by using one-step vacuum sintering followed by hot isostatic pressing (HIPing) technique. The transmission of the undoped Y2O3 reaches 83%. The structural characteristics including the phonon energy were investigated through X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) analysis and scanning electron microscopy (SEM) measurement. The overall spectroscopic properties of transmission, fluorescence emission up to 3000 nm, lifetime, up-conversion luminescence, and refractive index were systematically studied for both 0.25 at% and 7.0 at% Er:Y2O3 ceramics with different thicknesses. The comparison of the spectra of the fluorescence emission and up-conversion luminescence under both 976 and 808 nm laser excitation was performed. The multiple high-energy-state transitional processes after the excited state absorption (ESA) processes involved in the up-conversion are discriminated between the multi-phonon non-radiative transitions and the radiative transitions according to the measured maximum phonon vibrational energy. The calculation was performed based on the Judd–Ofelt theory. 相似文献
2.
《Ceramics International》2019,45(14):16911-16917
This work presents the structural, morphological and luminescent, properties of SrGe4O9 (SGO):Er3+,Yb3+ phosphors. These phosphors were synthesized by simple combustion synthesis and subsequently annealed at 1100 °C. The XRD patterns revealed that all the SGO samples doped with Yb3+ concentrations from 2 to 10 at.% presented a trigonal pure phase (the Er3+ concentration was fixed to 1 at.%). The morphology of the SGO samples was analyzed by scanning electron microscopy and found that they are formed by microparticles with irregular shapes and average sizes in the range of 0.2 μm–3 μm. The luminescence measurements of the SGO:Er3+,Yb3+ samples showed the presence of two main emission bands at 551 nm (green) and at 662 nm (red) under excitation at 980 nm, which are associated to Er3+ transitions. For Yb concentration of 2 and 3 at.% the green band dominated, but the red band became more intense for Yb concentrations above 5 at.%. As result, the CIE coordinate changed from the green to the yellow region. The increase for the Yb content from 2 to 10 at.% also enhanced of the NIR emission of Er3+ ≈5 times and the maximum upconversion emission was observed for 8% of Yb concentration. Further, the surface of the SGO samples was analyzed by the FTIR technique in order to find OH groups which are common luminescent quenching centers, but these groups were not detected on the samples. Since the SGO samples presented tunable emission, absence of OH groups on their surface and stable crystalline structure for high Yb dopant concentrations, they could be good candidates as phosphors for solid state lighting or displays applications. 相似文献
3.
通过对Al-0.04Er-0.08Zr合金进行200°C 到450°C 范围内的热压缩测试对该合金的热变形行为进行了研究,在这个过程中利用Arrhenius-type方程进行线性拟合从而分析应力-应变曲线,之后通过透射电镜来观察研究变形组织。结果表明对于固溶态以及时效态合金来讲,在热压缩过程中动态回复是使合金软化的一个主要机制。高温以及低应变速率的热变形会诱导固溶态合金快速析出。动态析出会明显增加固溶态合金在热压缩过程中其表面的流变应力,但是却不能有效提高变形合金的硬度。动态析出还会导致应力-应变曲线拟合出现Arrhenius型偏差。 相似文献
4.
《Optical Fiber Technology》2014,20(3):235-238
A simple widely tunable wavelength spacing dual-wavelength single longitudinal mode (SLM) erbium doped fiber laser (EDFL) based on cascaded fiber Bragg gratings (FBGs) and birefringent fiber filter is proposed and demonstrated. Experimental results show that the lasing wavelength spacing is widely tunable in a range from 2 nm to 18 nm, which has potential to generate frequency tunable terahertz (THz) waves by beating the lasing dual-wavelength in a high speed photodetector. The birefringent fiber filter acts as an ultra-narrow bandpass filter and benefits the simultaneous oscillation of dual-wavelength in a single laser cavity. The output peak power of the lasing dual-wavelength is approximately equalized at room temperature, and a high optical signal-to-noise ratio (OSNR) is realized in the whole tuning range. The SLM operation of dual-wavelength fiber laser is verified by Fabry–Perot (F–P) scanning interferometer, and the clear eye diagram proves that the proposed fiber laser is effective in the application of fiber optic communication system. 相似文献
5.
Limei Song Jianhua Gao Minmin Liang Xiaojun Li Jiangtao Li Liuchang Wang 《中国稀土学报(英文版)》2019,37(3):232-236
In this work, CaF_2:Ln~(3+)(Ln:Er,Er/Yb)/Nafion composite films were prepared using Nafion as modifications and matrices by dripping method. The composite films were characterized by Fourier transform infrared spectroscopy(FT-IR), X-ray diffraction(XRD) and scanning electron microscopy(SEM). Composite films are transparent and CaF_2:Ln~(3+)(Ln:Er,Er/Yb) nanoparticles are well dispersed in Nafion films.The thicknesses of CaF_2:Er~(3+)/Nafion and CaF_2:Er~(3+),Yb~(3+)/Nafion composite film are about 77 and 73 μm,respectively. The nanoparticles in composite film possess cubic phase. CaF_2:Er~(3+),Yb~(3+)/Nafion composite film has stronger characteristic emission of Er~(3+) around 1530 nm with full width at half-maximum(FWHM) of 73 nm and longer luminescence lifetimes of 22.04 μs(25.03%) and 100.77 μs(74.97%). 相似文献
6.
《Optical Materials》2014,36(12):2400-2404
Erbium doped tellurite glasses (TeO2 + Li2O + TiO2) were prepared by conventional melt-quenching method to study the influence of the Er3+ concentration on the luminescence quantum efficiency (η) at 1.5 μm. Absorption and luminescence data were used to characterize the samples, and the η parameter was measured using the well-known thermal lens spectroscopy. For low Er3+ concentration, the measured values are around 76%, and the concentration behavior of η shows Er–Er and Er–OH− interactions, which agreed with the measured lifetime values. 相似文献
7.
《Fusion Engineering and Design》2014,89(7-8):1402-1405
Low concentration tritium permeation experiments have been performed on uncoated F82H and Er2O3-coated tubular samples in the framework of the Japan-US TITAN collaborative program. Tritium permeability of the uncoated sample with 1.2 ppm tritium showed one order of magnitude lower than that with 100% deuterium. The permeability of the sample with 40 ppm tritium was more than twice higher than that of 1.2 ppm, indicating a surface contribution at the lower tritium concentration. The Er2O3-coated sample showed two orders of magnitude lower permeability than the uncoated sample, and lower permeability than that of the coated plate sample with 100% deuterium. It was also indicated that the memory effect of ion chambers in the primary and secondary circuits was caused by absorption of tritiated water vapor that was generated by isotope exchange reactions between tritium and surface water on the coating. 相似文献
8.
Takumi Chikada Akihiro Suzuki Takayuki Terai Takeo Muroga Freimut Koch 《Fusion Engineering and Design》2013,88(6-8):640-643
Li–Pb compatibility of Er2O3 and Er2O3-Fe two-layer coatings has been explored for an understanding of corrosion behaviors and effects of the protection layer. The coatings were peeled off after static Li–Pb immersion test at 600 °C due to the degradation of adhesion between the coating–substrate interface. A loss of Er and then subsequent corrosion of Er2O3 were shown after immersion at 500 °C for 500 and 1505 h. However, the outer Fe layer played a role to decrease corrosion rate of the coatings by comparing with the results of Er2O3 single layer coatings. Deuterium permeation measurements after corrosion tests at 500 °C showed that the Er2O3 coatings kept permeation reduction factors of 102–103 after 500 h immersion, but seriously degraded after 1505 h immersion. Corrosion mechanisms suggest that corrosion protection properties will be modified by an optimization of the outer Fe layer and a control of oxygen concentration in Li–Pb. 相似文献
9.
H.H. ShenS.M. Peng X.G. LongX.S. Zhou J.H. LiuK. Sun L. YangQ.Q. Sun X.T. Zu 《Vacuum》2012,86(12):2075-2081
Erbium films were grown on single crystal Si(111) substrates by electron beam vapor deposition. The microstructures of the erbium films were systematically investigated by X-ray diffraction, scanning electron microscopy, and energy dispersive spectroscopy. Results indicate that the surface morphologies and microstructures of the erbium films with Si as substrates are susceptible to the substrate temperatures when the deposition rates are fixed. The pure erbium films with columnar grains were obtained at temperatures below 200 °C, but in the films grown at temperatures higher than 350 °C, some pinholes that are composed of erbium silicides were found. The pinholes have triangular shapes which is in accordance with the geometry of the underlying Si(111) substrate. The films grown at a substrate temperature equal or greater than 450 °C have cracks which would be formed due to the different shrinkage degree of erbium and silicon when the substrate temperature was cooled down to room temperature. The films grown at 200 °C show the (002) preferred orientation, which is consistent to the prediction by the theory of surface energy minimization. The deposition rate and deposition time are considered as factors to affect the reaction of the erbium film and the silicon substrate. 相似文献
10.
P. Nekvindova B. SvecovaJ. Cajzl A. Mackova P. Malinsky J. OswaldA. Kolistsch J. Spirkova 《Optical Materials》2012,34(4):652-659
Single crystals like lithium niobate are frequently doped with optically active rare-earth or transition-metal ions for a variety of applications in optical devices such as solid-state lasers, amplifiers or sensors. To exploit the potential of the Er:LiNbO3, one must ensure high intensity of the 1.5 μm luminescence as an inevitable prerequisite. One of the important factors influencing the luminescence properties of a lasing ion is the crystal field of the surrounding, which is inevitably determined by the crystal structure of the pertinent material. From that point it is clear that it cannot be easy to affect the resulting luminescence properties - intensity or position of the luminescence band - without changing the structure of the substrate. However, there is a possibility to utilise a potential of the ion implantation of the lasing ions, optionally accompanied with a sensitising one, that can, besides the doping, also modify the structure of the treated area od the crystal. This effect can be eventually enhanced by a post-implantation annealing that may help to recover the damaged structure and hence to improve the desired luminescence.In this paper we are going to report on our experiments with ion-implantation technique followed with subsequent annealing could be a useful way to influence the crystal field of LN. Optically active Er:LiNbO3 layers were fabricated by medium energy implantation under various experimental conditions. The Er+ ions were implanted at energies of 330 and 500 keV with fluences ranging from 1.0 × 1015 to 1.0 × 1016 ion cm−2 into LiNbO3 single-crystal cuts of both common and special orientations. The as-implanted samples were annealed in air and oxygen at two different temperatures (350 and 600 °C) for 5 h. The depth concentration profiles of the implanted erbium were measured by Rutherford Backscattering Spectroscopy (RBS) using 2 MeV He+ ions. The photoluminescence spectra of the samples were measured to determine the emission of 1.5 μm.It has been shown that the projected range Rp of the implanted erbium depends on the beam energies of implantation. The concentration of the implanted erbium corresponds well with the fluence and is similar in all of the cuts of lithium niobate used. What was different were the intensities of the 1.5 μm luminescence bands not only before and after the annealing but also in various types of the crystal cuts. The cut perpendicular to the cleavage plane 〈10-14〉 exhibited the best luminescence properties for all of the experimental conditions used. In order to study the damage introduced by the implantation process, the influence of the annealing procedure on the recovery of the host lattice was examined by RBS/channelling. The RBS/channelling method serves to determine the disorder density in the as-implanted surface layer. 相似文献