Corrosion behaviour of an industrial shot-peened and coated automotive spring steel AISI 9254

A high-strength low-alloy steel, AISI 9254 (54SiCr6), is widely used for suspension spring production in the automotive industry. In this work, industrially manufactured zinc phosphate coated helical springs are subjected to detailed microstructural and surface analysis for better understanding of corrosion evolution. The material’s free corrosion potential and anodic/cathodic behaviour were investigated in NaCl solutions and corrosion propagation mechanisms were studied using potentiostatic polarisation on cross-sectional and external surfaces. The bulk material is fully martensite with uniformly distributed MnS inclusions, while the spring surface has a 2–3?μm mechanically deformed region introduced by shot-peening and a thin zinc phosphate coating. The corrosion open circuit potential of bulk material and shot-peened spring surface was about –0.7V_SCE without significant difference, while phosphated surface is more noble (more positive potential). MnS inclusions, stimulating the anodic attack in the steel, influence corrosion propagation and pit morphology to a large extent that can have an impact on the spring performance.     

超超临界锅炉用钢Super 304H的焊接工艺

Super 304H钢是奥氏体型的超超临界锅炉用钢。通过分析Super 304H钢的焊接性能,选用NIBAS70/20-1G焊丝来焊接试板,并评定其焊接工艺。为保证焊接质量,提出坡口打磨、全程持续充氩保护、控制热输入、坡口内加丝等工艺措施来防止出现未熔合、内凹等缺陷,试验数据及工程实践均证明,选用NIBAS 70/20-1G焊丝的钨极氩弧焊工艺可保证Super 304H钢焊接接头的综合力学性能符合要求。     

Post-forming monotonic and cyclic behavior in a HSLA steel sheet after large deformations by in-plane compression

The effects of large prestrains (18–40%), produced by in-plane compression, on the asymmetry and the anisotropy of the stress response and on the fatigue life are investigated under fully reversed axial strain for a 345 MPa yield strength V–N high strength low alloy steel sheet. After prestraining, the hysteresis loops are asymmetric and the stress response is anisotropic, i.e., the response differs in directions parallel and perpendicular to that of the compressive prestrain. To understand the cyclic flow stress asymmetry, monotonic tension and compression tests were conducted in these two directions after prestraining. It is shown that the loop asymmetry is related to the Bauschinger effect after prestraining. Two cyclic stress strain curves, one corresponding to the tension side of the hysteresis loops and the other to the compression side, are defined to accurately describe the post-prestraining behavior. The amount of strengthening gained by prestraining is partially retained after cycling. Prestraining increases the fatigue life at low strain amplitudes but decreases it at high strain amplitudes.     

Friction stir welding of API X70 steel incorporating Ti-dioxide

In the present work, the microstructural evolution and hardness of HSLA X70 joined by friction stir welding were investigated. The FSW was applied to HSLA X70 with and without the addition of titanium dioxide (TiO₂) powders. To evaluate the microstructural features and hardness of different weld zones, optical microscopy and Vickers microhardness measurements were applied. The results show that the distribution of TiO₂ powders is strongly dependent on the applied friction stir processing, which in turn changed significantly the microstructure and hardness profile. In this regard, the optimum stirring action resulted in a homogeneous and fine dispersion of particles leading to the domination of an acicular ferrite phase with a hardness of 370 HV. On the other hand, the lower stirring action resulted in coarse particles as well as the development of the polygonal ferrite structure with a hardness of ～185 HV.     

Oxidation behaviour of some modern heat-resistant cast steels

The kinetics and morphological development of the oxidation of a selection of modern heat-resistant cast steels have been examined and compared with those of the traditional material, HK40. The materials examined had Cr contents of 24 to 29 weight percent (wt %), Ni contents of 30 to 46 wt %and in several cases minority additions of Nb, W, or both. One steel contained 3.3 wt % Al. Kinetics were measured gravimetrically over periods of 6 to 100 h and found to be parabolic in all cases except for the Al-containing steel, which oxidized in an irregular and irreproducible fashion. All steels formed an external scale of Cr₂O₃ with a Mn-rich spinel layer at the outer surface. Beneath this scale was a layer of alloy depleted in both Cr and Mn. Within the depleted layer inter-dendritic carbides had been destroyed, leaving either oxide near the external alloy surface or voids deeper within the alloy.     

Development and comparison of residual stress measurement on welds by various methods

Abstract

Residual stress constitutes an integral part of the total stress acting on any component in service. It is imperative to determine residual stress to estimate the life of critical engineering components, especially those that are welded. The stresses caused by non-uniform temperature distribution due to welding and the effect of these multiaxial stresses upon service performance are discussed. A controlled thermal severity test (CTS) was performed on mild steel plates bolted together, with anchor welds deposited on opposite sides. After cooling, bithermal and trithermal test welds were deposited one after the other. Varying welding stresses were deliberately introduced by using different thicknesses of both plates to change the thermal severity numbers (TSN). The main experimental technique used here to determine the magnitude and nature of residual stress is based on X-ray diffraction (XRD). It was utilised to develop and standardise other techniques. The XRD method is based on the peak shiftin the diffraction profile due to the presence of stress using a sin² ψ method. The peak shift is determined by orienting the sample at different angles ± ψ to the incident X-ray beam. The semidestructive technique of hole drilling and use of a strain gauge was also employed to determine residual stress in CTS specimens. The magnitude, nature, and direction of principal stresses were determined by relieving stresses through incremental blind hole drilling and measuring strain values at each step. The surface displacements arising due to hole drilling can also be determined by laser holography. A sandwich holography technique was developed to avoid unwanted rigid body motions of samples due to hole drilling when relieving stresses. Stress values were obtained by measuring fringe displacement between two exposures of a sandwich hologram, due to hole drilling. Results on the change in residual stress values with TSN are discussed. The residual stress values determined by XRD and sandwich holography were found to be comparable, and stress values obtained by hole drilling/strain gauge measurement were higher than these values. The reasons are discussed.     

Systematic investigation of acicular ferrite formation on laboratory scale

By increasing the amount of acicular ferrite (AF) in the microstructure, steel toughness can be improved significantly. The steel composition, cooling rate, non-metallic inclusions and austenite grain size have a strong influence on the formation of AF. The present paper describes and compares two approaches to study AF formation in a titanium-deoxidised high-strength low-alloyed steel and its influencing factors on laboratory scale: route A simulates the formation of AF after heat treatment; route B simulates the formation directly after solidification of the melt. The formation of AF is essentially influenced by the former processing, which also changes the optimum cooling parameters substantially. (Ti,Mn)_xO_y and (Ti,Al,Mn)_xO_yS_z are the predominant active inclusion types in the investigated steel.     

Improving the Interfacial Microstructure Evolution of Ti/Stainless Steel GTA Welding Joint by Employing Cu Filler Metal

In the present work, Cu alloys as filler metals were applied to improve interfacial microstructural evolution during the process of gas tungsten arc (GTA) welding of TA15 titanium alloy with 18-8 stainless steel (SS). Results indicated that the interfacial brittle microstructure evolution of Ti/SS GTA welding joint was improved by adopting Cu alloy as the filler metal. Microstructure in the reaction zone (RZ) is composed of massive precipitations including brittle phosphide (Ti₃P), Ti₂Cu₃ and Ti(Cu, Fe) intermetallic compounds (IMCs), while the fusion zone (FZ) near SS is mainly composed of Cu-rich clumps and α-Fe+(Fe, Cr)₃P skeleton eutectic microstructure. Ti₂Cu₃ precipitations provided substrate for the heterogeneous nucleation of Ti₃P whose regular tetragonal and irregular morphologies are attributed to the proposed two kinds of forming mechanism. During the reaction of P with Ti₂Cu₃, the dropping of residual Ti₂Cu₃ contributed to the formation of macroporous in the middle of irregular Ti₃P precipitations. The dispersive distribution of massive brittle precipitations in the RZ leads to the fluctuant distribution of microhardness, which is up to about 700HV_0.5.     

Effect of direct quenching on the microstructure and mechanical properties of the lean-chemistry HSLA-100 steel plates

The influence of direct quenching on structure-property behavior of lean chemistry HSLA-100 steels was studied. Two laboratory heats, one containing Cu and Nb (C:0.052, Mn:0.99, Cu:1.08, Nb:0.043, Cr:0.57, Ni:1.76, Mo:0.55 pct) and the other containing Cu, Nb and B (C:0.04, Mn:1.02, Cu:1.06, Nb:0.036, Cr:0.87, Ni:1.32, Mo:0.41, B:0.002 percent) were hot-rolled into 25 and 12.5 mm thick plates by varying finish-rolling temperatures. The plates were heat-treated by conventional reheat quenching and tempering (RQT), as well as by direct quenching and tempering (DQT) techniques. In general, direct-quench and tempered plates of Nb-Cu heat exhibited good strength (yield strength ∼ 900 MPa) and low-temperature impact toughness (average: 74 J at −85 °C); the Charpy V-notch impact energies were marginally lower than conventional HSLA-100 steel. In Nb-Cu-B heat, impact toughness at low-temperature was inferior owing to boron segregation at grain boundaries. Transmission electron microscopy (TEM) and scanning auger microprobe (SAM) analysis confirmed existence of borocarbides at grain boundaries in this steel. In general, for both the steels, the mechanical properties of the direct-quench and tempered plates were found to be superior to reheat quench and tempered plates. A detailed transmission electron microscopy study revealed presence of fine Cu and Nb (C, N) precipitates in these steels. It was also observed that smaller martensite inter-lath spacing, finer grains and precipitates in direct-quench and tempered plates compared to the reheat quench and tempered plates resulted in their superior strength and good impact toughness.