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排序方式: 共有1028条查询结果,搜索用时 31 毫秒
1.
M.J. Wang W.T. Wang L. Liu F. Scurti Y.D. Xia B.L. Huo X. Yang Y. Zhao 《Ceramics International》2018,44(13):15572-15578
Corrosion resistance is a crucial property to achieve successful superconducting joints of Y0.5Gd0.5Ba2Cu3O7-z (YGdBCO) coated conductors (CCs). Cu and Ag metallic layers need to be fully removed from the area of conductor to be joint to allow for a superconducting path across the joint. Therefore, when using a wet etching process to remove the metallic layers, the joint performance can be significantly influenced by the etching conditions. The effects of chemical etching with ammonia water and hydrogen peroxide mixture on crystal structure, surface microstructure and critical current (Ic) of YGdBCO CCs were systematically investigated. We found the set of etching parameters that does not affect conductor performance, leaving the Ic of the YGdBCO conductor unchanged upon etching. However, when the etching conditions are not optimal, decrease in Ic was found and the underlying reasons driving the degradation were investigated. Raman spectroscopy and XRD analysis indicated that the reduced Ic is mainly due to oxygen deficiency in the YGdBCO crystal lattice. 相似文献
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Semiconductor‐ionic materials could play an important role in advanced fuel‐to‐electricity conversion 下载免费PDF全文
Functional semiconductor‐ionic materials can be used to realize a single component or so‐called “three‐in‐one” fuel cell design. Such materials integrate the functionalities of fuel cell's anode, electrolyte, and cathode into one component. The underlying principle of a single‐component fuel cell design combines material band structures with ionic species/transport. The performance values of such devices could exceed that of traditional fuel cells. This could represent a major progress in fuel cell science and technology and lies grounds for a new direction of fuel cell R&D and commercialization. 相似文献
4.
《International Journal of Hydrogen Energy》2022,47(60):25367-25377
As a promising electrolyte material for solid oxide fuel cells (SOFCs), BaZr0.1Ce0.7Y0.1Yb0.1O3-δ (BZCYYb) often surfers from its high sintering temperature, which causes Ba evaporation and sluggish grain growth, thus reducing the electrical conductivity. In this work, densified BZCYYb electrolytes were fabricated at temperatures as low as 1400 °C using the microwave sintering technique. Comparing with the conventional sintered ones, a temperature decrease of 150 °C is achieved. The Ba evaporation is effectively suppressed, and large grain sizes of ~4 μm are obtained. The total conductivity for microwave sintered symmetric cell measured in wet air at 700 °C is 3.8 × 10?2 S cm?1, benefiting from both enhanced bulk conductivities by 1–2 times and grain boundary conductivities by 50 times. With the microwave sintered BZCYYb as electrolyte, an anode-supported cell reaches a maximum power density of 0.64 W cm?2 at 700 °C. 相似文献
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Moutusi Banerjee Abhisek Gupta Shyamal K. Saha Dipankar Chakravorty 《Small (Weinheim an der Bergstrasse, Germany)》2015,11(28):3451-3457
Attachment of Li+ ion on graphene surface to realize Li+‐ion conductor is a real challenge because of the weak interaction between the ions and the functional groups of graphene oxide; although, a large number of theoretical results are already available in the literature. To overcome this problem, graphene oxide is functionalized by 1‐aza‐15‐crown‐5, the cage‐like structure containing four oxygens that can bind Li+ ion through electrostatic interaction. Li+ migration on graphene surface has been investigated using ac relaxation mechanism. Perfect Debye‐type relaxation behavior with β (relaxation exponent) value ≈1 resulting from single ion is observed. The activation energy of Li+ migration arising due to cation‐π interaction is found to be 0.37 eV, which agrees well with recently reported theoretical value. It is believed that this study will help to design isolated ion conductors for Li+‐ion battery. 相似文献
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Matthew D. Ward Brian L. Chaloux Michelle D. Johannes Albert Epshteyn 《Advanced materials (Deerfield Beach, Fla.)》2020,32(42):2003667
High proton conductivity is reported for unhumidified ammonium borosulfate, NH4[B(SO4)2], a solid acid coordination polymer that contains 1D, hydrogen-bonded NH4+···1∞[B(SO4)4/2]− chains. NH4[B(SO4)2] is thermally stable to 320 °C and is amenable to sintering into monolithic, polycrystalline discs at 200 °C and about 300 MPa of uniaxial pressure. Impedance spectroscopy measurements reveal ionic conductivities for sintered ammonium borosulfate of 0.1 mS cm−1 at 25 °C and up to 10 mS cm−1 at 180 °C in ambient air. No superprotonic transition is observed in the temperature range of 25–180 °C. Ab initio molecular dynamics simulations show these high conductivities are aided by free rotation of the NH4+ units and significant gyrational mobility of the SO4 tetrahedra, which, in turn, provide facile pathways for proton locomotion. High conductivities, a wide operational temperature window, and tolerance to both ambient and anhydrous conditions make NH4[B(SO4)]2 an attractive candidate electrolyte for intermediate-temperature hydrogen fuel cells that may enable operation at temperatures as high as 300 °C without active humidification. 相似文献
9.
Bryan D. Paulsen Ruiheng Wu Christopher J. Takacs Hans-Georg Steinrück Joseph Strzalka Qingteng Zhang Michael F. Toney Jonathan Rivnay 《Advanced materials (Deerfield Beach, Fla.)》2020,32(40):2003404
The structure and packing of organic mixed ionic–electronic conductors have an especially significant effect on transport properties. In operating devices, this structure is not fixed but is responsive to changes in electrochemical potential, ion intercalation, and solvent swelling. Toward this end, the steady-state and transient structure of the model organic mixed conductor, poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS), is characterized using multimodal time-resolved operando techniques. Steady-state operando X-ray scattering reveals a doping-induced lamellar expansion of 1.6 Å followed by 0.4 Å relaxation at high doping levels. Time-resolved operando X-ray scattering reveals asymmetric rates of lamellar structural change during doping and dedoping that do not directly depend on potential or charging transients. Time-resolved spectroscopy establishes a link between structural transients and the complex kinetics of electronic charge carrier subpopulations, in particular the polaron–bipolaron equilibrium. These findings provide insight into the factors limiting the response time of organic mixed-conductor-based devices, and present the first real-time observation of the structural changes during doping and dedoping of a conjugated polymer system via X-ray scattering. 相似文献
10.
《低温学》2016
The data resulting from the thermal-hydraulic test of the ITER TF CICC are used to determine the flow partition and the overall effective heat transfer coefficient (hBC) between bundle and central channel in a direct way, i.e. by analysis of the heat transfer between both flow channels, based on the mass and energy balance equations and the readings of thermometers located inside the cable. In cases without a local heat source in the considered cable segment the obtained hBC values were consistent with those obtained in earlier studies by analysis of experimental data using indirect methods. It was also observed that the transverse heat transfer was strongly enhanced in a cable segment heated from outside. This phenomenon results from the mass transfer from the bundle region to the central channel. The experimental hBC data obtained for the case without a heat source in the considered segment were also compared with those calculated using various heat transfer correlations. 相似文献