Tribological and mechanical characteristics of AA5083 alloy reinforced by hybridising heavy ceramic particles Ta2C & VC with light GNP and Al2O3 nanoparticles

In this study, AA5083 sheets were reinforced with four different hybrid nanoparticles by friction stir processing (FSP) for the development of surface nanocomposites used in advanced engineering applications. The present research focused on improving the properties and tribological behaviour of AA5083 alloy surfaces, including novel hybrid nanoparticles and the intermetallic phase formed during FSP. A tribometer tester with a constant normal load was used to examine the tribological performance of the hybrid composites. After the wear test, a surface profiler inspector was used to analyse the morphology and surface roughness of the examined materials. The Vickers micro-hardness of the base metal and the manufactured composites were measured. During FSP, a new intermetallic phase of AlV₃ was successfully formed at 300–400 °C in the hybrid nanocomposites containing VC particles. The reinforcements resulted in additional grain refining than FSP. The AA5083/Ta2C–Al₂O₃ exhibited the greatest grain refinement, a sixty-fold reduction in grain size compared to that of the base alloy. The results revealed that the hybrid nanocomposites containing VC particles demonstrated the most significant microhardness values inside the stirred zone as a result of the presence of the AlV₃ phase, which was increased by 25–30%. Moreover, the mechanical properties were significantly improved for all manufactured nanocomposites. The tensile strength was increased by 28% through the hybridisation of AA5083 using a hybrid of VC-GNPs. The dispersion of Ta₂C-GNPs and VC-GNPs in the matrix led to excellent interfacial adhesion, resulting in an enhancement in the mechanical properties. The AA5083/VC-GNPs surface composite outperformed other manufactured composites regarding wear resistance. In addition, due to GNPs soft nature, it reduced the coefficient of friction (COF) of the manufactured composites by 20–25% compared to other reinforcements.     

B4C–TiB2 composites fabricated by hot pressing TiC–B mixtures: The effect of B excess

Previous research have reported that B₄C–TiB₂ composites could be prepared by the reactive sintering of TiC–B powder mixtures. However, due to spontaneous oxidation of raw powders, using TiC–B powder mixtures with a B/TiC molar ratio of 6: 1 introduced an intermediate phase of C during the sintering process, which deteriorated the hardness of the composites. In this report, the effects of B excess on the phase composition, microstructure, and mechanical properties of B₄C–TiB₂ composites fabricated by reactive hot pressing TiC–B powder mixtures were investigated. XRD and Raman spectra confirmed that lattice expansion occurred in B-rich boron carbide and B_xC–TiB₂ (x > 4) composites were obtained. The increasing B content improved the hardness and fracture toughness but decreased the flexural strength of B_xC–TiB₂ (x > 4) composites. When the molar ratio of B/TiC increased from 6.6:1 to 7.8:1, the Vickers hardness and the fracture toughness of the composites were enhanced from 26.7 GPa and 4.53 MPa m^1/2 to 30.4 GPa and 5.78 MPa m^1/2, respectively. The improved hardness was attributed to the microstructural improvement, while the toughening mechanism was crack deflection, crack bridging and crack branching.     

Failure response of fiber-epoxy unidirectional laminate under transverse tensile/compressive loading using finite-volume micromechanics

The transverse damage initiation and extension of a unidirectional laminated composite under transverse tensile/compressive loading are evaluated by means of Representative Volume Element (RVE) presented in this paper based on an advanced homogenization model called finite-volume direct averaging micromechanics (FVDAM) theory. Fiber, fiber-matrix interface and matrix phases are considered within the RVE in determining fiber-matrix interface debonding and matrix cracking. The simulated fracture patterns are shown to be in good agreement with experimental observations.     

Microstructure and mechanical properties of an Al–TiC metal matrix composite obtained by reactive synthesis

A metal matrix composite has been obtained by a novel synthesis route, reacting Al₃Ti and graphite at 1000 °C for about 1 min after ball-milling and compaction. The resulting composite is made of an aluminium matrix reinforced by nanometer sized TiC particles (average diameter 70 nm). The average TiC/Al ratio is 34.6 wt.% (22.3 vol.%). The microstructure consists of an intimate mixture of two domains, an unreinforced domain made of the Al solid solution with a low TiC reinforcement content, and a reinforced domain. This composite exhibits uncommon mechanical properties with regard to previous micrometer sized Al–TiC composites and to its high reinforcement volume fraction, with a Young’s modulus of ∼110 GPa, an ultimate tensile strength of about 500 MPa and a maximum elongation of 6%.     

Effects of mean stress and fibre volume content on the fatigue-induced damage mechanisms in CFRP

The effect of the load type (tension and compression) in quasi-static and of the applied mean stress in fatigue tests on the mechanical behaviour and on the damage mechanisms in unidirectional (UD) carbon/epoxy laminates has been studied in combination with the influence of fibre volume content. Results show that the fibre volume content increases the mechanical properties in tension–tension fatigue tests for all tested angles 0°, 45° and 90°. The tensile damage mechanisms of off-axis specimens depend on the fibre volume content and change from matrix cracking and matrix–fibre debonding to fibre-pull out with an increasing amount of fibres as investigated in detail in a previous work. In tension–compression tests, higher fibre volume contents are only beneficial in fatigue tests at angles of 0° and 45°. Fatigue strengths of UD 90° specimens in tension–compression tests are not significantly improved by the fibre volume content which can be ascribed to breakage of entire fibre bundles and crushed fibres on the fracture surfaces.     

Dielectric relaxation and ionic conduction in 66%Silica/CW229-3/HW229-1 microcomposite polymer

Composites of epoxy resin with high percentage of silica fillers (66%) are designed to improve mechanical and electrical properties of transformers used in railway application. FTIR, (DRX and FE-SEM) and absorption/desorption phenomena are used to investigate the structure, the morphology and the diffusion of water in the microcomposites, respectively. Good dispersion of silica filler with size less than 10 μm was assessed by SEM, although some clustering (agglomerates) of greater than 1 μm was observed. The absorption water in the microcomposite obeys to the first Fickian law and shows saturation water of 0.6%. The calculation of the diffusion coefficient of water leads to a value of 2.9*10⁻¹² m² s⁻¹ in the studied system. Relaxation times of α-relaxation and ionic conduction relaxation processes are determined. A correlation is observed between the ionic conductivity and dielectric relaxation processes. The dc-current behavior shows a change in the conduction mechanism from electronic conduction below the T_g to ionic conduction above the T_g. Shallow traps of 0.54 eV and deep traps of 2.21 eV are determined below and above the T_g, respectively. The TSC analysis confirms the VFT behavior of the α-relaxation of the microcomposite as obtained by the dielectric spectroscopy.     

Microstructure evolution during fabrication and microstructure–property relationships in vapour-grown carbon nanofibre-reinforced aluminium matrix composites fabricated via powder metallurgy

Microstructure evolution of vapour-grown carbon nanofibre (VGCF)-reinforced aluminium matrix composites during fabrication and microstructure–property relationships of these materials were studied. Composites were fabricated using powder metallurgy, i.e. by mixing VGCFs and aluminium powder via ball-milling followed by sintering or hot extrusion. The mixing condition was selected to achieve small powder particle size and homogeneously dispersed VGCFs. Aluminium grains and VGCFs were elongated along the longitudinal direction of aluminium particles in the mixed powder. Detailed observation of the aluminium grains in the composites found grain size and morphology dominated by recrystallization. Apparently, grain growth was inhibited by VGCFs. Theoretical models considering strength increment due to grain refinement resulting from VGCF addition, load bearing of VGCFs, thermal mismatch of VGCFs and aluminium and Orowan effect were developed. Theoretical values coincided well with hardness, yield strength, and ultimate tensile strength of the composites, and thus the models could precisely explain the microstructure–property relationships.     

Hierarchical electromagnetic absorption in micro-waveguide stuffed with magnetic media for resin-based composites of graphene nanosheets and manganese oxides

Waveguide configurations of hierarchical system are proposed as new microstructures for composites in absorbing enhancement. Supercritical fluid (SCF) one-pot exfoliation of layered graphite and manganese oxide mixing materials is developed to obtain a hierarchical system, containing graphene nanosheets (GNS) and exfoliated manganese oxides (EMO) in different sizes. Composites with GNS–EMO embedded in epoxy resin matrix are produced for a design of dielectric and magnetic loss integrated absorber. Volume fraction of GNS–EMO in composites is given for an optimal quantity of resin epoxy in fixation and formation. The effect of mixing ratios between electric and magnetic components is provided for the design of dielectric and magnetic loss integrated absorbers. Frequency shifting phenomena are revealed in the component adjusting course. Excluding the offsetting sizes, reflection loss of composites is enhanced as thickness increases. Synergistic effect of electric and magnetic coordinated materials demonstrates the superiority of micro-waveguide structures in GNS–EMO composite absorber.     

Non-keyhole Friction Stir Welding for 6061-T6 Aluminum Alloy

A novel non-keyhole friction stir welding technique was proposed to weld the butt joint of 6061-T6 aluminum alloy with the thickness of 6 mm. A sound joint was obtained by this technique, simultaneously eliminating the flash, shoulder mark and keyhole defects. The sleeve directly affected zone (SDAZ) and the sleeve indirectly affected zone (SIAZ) were divided into the joint according to the plunging position of the hollow sleeve. The lack of root penetration defect was avoided when the plunging depth of the hollow sleeve was only 4.2 mm, because the hollow part inside the sleeve improved the material flow below the sleeve. An S-shaped line was left at the SIAZ, and the height of it had the minimum value of 1.47 mm at 20 mm/min. Whether the failure location of the joint was in SIAZ/SDAZ or the heat-affected zone (HAZ) depended on the height and bonding strength of the S-shaped line. The joint fracture location changed from the SIAZ/SDAZ at 35 mm/min to the HAZ at 20 and 30 mm/min. The maximum tensile strength of 224.3 MPa was obtained at 30 mm/min which was 73.7% of that of the base material. The fracture surface morphology exhibited the typical ductile fracture.     

Ablation behavior of (TiZrHfNbTa)C high-entropy ceramics with the addition of SiC secondary under an oxyacetylene flame

The ablation behavior of high-entropy ceramics (HECs) was investigated in this study using an oxyacetylene flame at 2000 °C. Spark plasma sintering was used to construct a dense HEC (TiZrHfNbTa)C with a 20 vol% of SiC addition (HEC-20SiC). The densification of HEC-20SiC can be improved to a certain extent by adding SiC particles, increasing the hardness of HEC-20SiC to up to 24.6 GPa, and the crack deflection observed through the addition of SiC particles were considered to be the strengthening and toughening mechanisms. After ablation, Hf₆Ta₂O₁₇, Ti_5.1Ta_4.9O₂₀, Nb₂Zr₆O₁₇, TaZr_2.75O₈, and SiO₂ can be detected on an ablated surface and HEC-20SiC possesses the minimum mass ablation rate (?1.9 mg s^?1) and line ablation rate (2.1 μm s^?1) among the comparative ceramics. On the one hand, the SiC phase forms gaseous CO, CO₂, and SiO as well as viscous SiO₂ during ablation and some part of the heat can be dissipated by the evaporation of gaseous CO, CO₂, and SiO; further, pore defects can be healed by viscous SiO₂, thus inhibiting the diffusion of reactive oxygen species. On the other hand, the HEC phase with a lattice-distortion caused by single-phase solid-solution can effectively inhibit the invasion of reactive oxygen species and the outward migration of metal atoms. The invasion rate of reactive oxygen is considered to be the main step during HEC-20SiC ablation, and it is believed that higher principal component HECs can improve ablation performance even further.