热处理对Ni-P-SiC镀层组织结构和性能影响研究

利用超声波辅助化学沉积法,在45钢基体表面制得Ni-P-SiC镀层。利用扫描电镜(SEM)、X射线衍射仪(XRD)、显微硬度计和电化学工作站研究热处理对Ni-P-Si C镀层组织结构和性能的影响规律。结果表明,Ni-P-SiC镀层的镍和SiC的平均粒径为91.7和46.8 nm。当热处理温度升高到400℃时,Ni-P-SiC镀层出现新的Ni3P和NixPy相;当热处理温度高达600℃时,Ni-P-SiC镀层中存在Ni、NiO、Ni3P、NixPy和SiC相,Ni-P-SiC3、Ni-P-SiC6、Ni-P-SiC9镀层的显微硬度分别为1170.4,1 265.1和1 313.6 HV。Ni-P-SiC镀层经400℃热处理1 h后,其耐腐蚀性能最佳。     

磁力搅拌-脉冲电沉积Ni-P-SiC镀层制备工艺研究

采用磁力搅拌-脉冲电沉积法在45钢表面制备Ni-P-SiC镀层。采用正交试验法优化Ni-P-SiC镀层的制备工艺,利用扫描电镜（SEM）和磨损试验机进行Ni-P-SiC镀层表面形貌及耐磨性能分析。结果表明,磁力搅拌-脉冲电沉积复合制备Ni-P-SiC镀层的最佳工艺为：磁力搅拌速率200 r/min,脉冲占空比2∶1,脉冲电流密度4 A/dm2,SiC粒子的质量浓度6 g/L。1号试样的磨损较严重,磨损量为5.1 mg;6号试样的磨损则较轻,磨损量为2.7 mg。     

工艺参数对磁力搅拌-化学沉积Ni-P-SiC镀层的影响

用磁力搅拌-化学沉积的方法,在45钢表面沉积Ni-P-SiC镀层。研究了SiC微粒添加量、搅拌速率以及镀液温度等对镀层硬度和表面形貌的影响,借助扫描电子显微镜(SEM)对镀层进行观察。结果表明:当SiC的质量浓度为10 g/L时,镀层显微硬度最大(615.2HV);当磁力搅拌速率为300 r/min时,镀层的显微硬度最大(632.8HV)。磁力搅拌-化学沉积Ni-P-SiC镀层的最佳工艺参数为:SiC添加的质量浓度10 g/L,搅拌速率300 r/min,温度85℃。     

沉积时间对AZ91D合金表面Ni-P-SiC复合镀层性能的影响

目的提高镁合金的耐蚀性和耐磨性。方法以AZ91D镁合金为基体,采用SiC颗粒质量浓度为3 g/L的Ni-P化学镀溶液,在其表面沉积不同时间,制备Ni-P-SiC复合镀层。通过扫描电子显微镜(SEM)、显微硬度测试、粗糙度仪、电化学腐蚀和磨损等试验来分析和评价Ni-P-SiC复合镀层的厚度、表面粗糙度、显微硬度、耐腐蚀性能和耐磨性能。结果 Ni-P-SiC复合镀层的厚度和表面粗糙度随沉积时间增加而增加,沉积时间为150 min时,镀层厚度可达53μm,表面粗糙度为2.5μm。沉积时间为120 min时,镀层的显微硬度最高,为641HV,此时复合镀层的耐蚀性和耐磨性最好,自腐蚀电位高达-0.73 V,腐蚀电流密度为0.78μA/cm~2,磨损体积最小,为1.04×10~(-3)mm~3。与AZ91D镁合金基体相比,沉积复合镀层后的样品更耐蚀,说明复合镀层有效改善了镁合金基体的耐蚀性。结论沉积时间对Ni-P-SiC复合镀层的性能有一定影响,在沉积时间为120 min时获得的复合镀层具有较好的耐蚀性和耐磨性。     

Tribological properties of electroless Ni-P-SiC composite coatings in rolling/sliding contact under boundary lubrication

Ni-P-SiC composite coatings were prepared under a given bath composition and operation parameters of electroless plating. The tribological properties of the Ni-P-SiC composite coatings after annealing at 400℃ for 1 h were tested in rolling/sliding contact under boundary lubrication condition using a two-roller tribometer. The measurement contained friction coefficient, contact surface temperature, contact electrical resistance, and wear rate of the Ni-P-SiC composite coatings under various slide to roll ratios, loads, and rolling speeds. For the simultaneous examination of the effect of the chosen parameters on the tribological properties of the Ni-P-SiC composite coatings, an orthogonal regression experimental design method was used.     

Characterisations of low phosphorus electroless Ni and composite electroless Ni-P-SiC coatings on A356 aluminium alloy

A low phosphorus electroless nickel coating of Ni-2.5?wt-%P alloy and a composite coating of Ni-5?wt-%P-SiC were prepared on A356 aluminium alloy substrates using two types of electroless bath solutions, an alkaline bath for low phosphorus and acidic for composite plating. The coatings morphologies have been characterised using optical and scanning electron microscopy. In addition, X-ray diffraction, microhardness, reciprocating wear testing and adhesion tests have been conducted to characterise structure and mechanical properties of the resulting coatings. The results obtained revealed that a crack-free and homogeneous coating could be produced using an optimum bath formulation. The maximum thickness of the composite coatings was 50?µm, the thickness of coatings tested. The composite coating was more resistant to wear in comparison to the low phosphorus nickel one, but had lower adhesion.     

Ni-P-SiC和Ni60JH涂层耐冲刷腐蚀性能的对比

为解决材料在液固两相流环境中的冲刷腐蚀问题,分别采用酸性化学镀镍工艺和超音速火焰喷涂技术在Q235钢基体上制备了Ni-P-SiC涂层和Ni60JH涂层,并采用冲刷腐蚀试验机研究了2种涂层在酸性浆料中的耐冲刷腐蚀性能.结果表明,在冲刷角度和温度一定的条件下,随冲蚀速度增加,2种涂层的损伤明显加剧,耐蚀性好的Ni-P-Si...     

化学镀Ni-P-SiC复合镀层的研究进展

综述了近年来国内外在Ni-P-SiC复合镀方面的研究进展,重点论述了SiC微粒的预处理、分散方式、SiC浓度、pH值、温度等工艺参数对镀速、复合镀层中粒子分布及含量的影响,讨论了复合镀层的硬度、耐磨性和耐蚀性能,最后指出了Ni-P-SiC复合镀应用中存在的问题和未来发展的方向.     

化学沉积Ni—P合金层及Ni—P—SiC复合层的研究

本文通过对化学沉积Ni-P合金和Ni-P-SiC复合镀层的研究,找到了制取适宜的磷含量和SiC含量的工艺方法。介绍了所得沉积层具有较高硬度和优良的耐磨性,并列举了应用于工业生产的实例,预期这项技术具有较广阔的应用前景。     

Ni-P 和 Ni-P-SiC 化学镀层的结构和性能

首先研究了热处理温度对Ｎｉ－Ｐ,Ｎｉ－Ｐ－ＳｉＣ化学镀层结构和硬度的影响,然后系统研究了ＳｉＣ颗粒粒度及浓度对Ｎｉ－Ｐ－ＳｉＣ镀层显微硬度的影响。用ＸＲＤ测定了镀层结构,用金相显微镜观察了镀层组织。结果表明,加入ＳｉＣ能增加Ｎｉ－Ｐ镀层的显微硬度。两种镀层经４００℃热处理后显微硬度均达到最大值。４００℃热处理后,Ｎｉ－Ｐ－ＳｉＣ镀层硬度随ＳｉＣ浓度增加而单调增加,随ＳｉＣ粒径的变化有一最大值。